Chemistry
The state S1 is :
Energy of the state S1 in units of the hydrogen atom ground state energy is:
The orbital angular momentum quantum number of the state S2 is
O, Cl, F, N, P, Sn, Tl, Na, Ti
The total number of diprotic acids among the following is:
H3PO4, H2SO4, H3PO3, H2CO3, H2S2O7, H3BO3, H3PO2, H2CrO4 and H2SO3
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In the reaction,
The structure of the product T is :
One mole of an ideal gas is taken from $\mathbf{a}$ to $\mathbf{b}$ along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is $W_{\text {s }}$ and that dotted line path is $W_{\mathrm{d}}$, then the integer closest to the ratio $W_{\mathrm{d}} / W_{\mathrm{s}}$ is
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Column I | Column II |
---|---|
(A) ![]() |
(P) Racemic mixture |
(B) ![]() |
(Q) Addition reaction |
(C) ![]() |
(R) Substitution reaction |
(D) ![]() |
(S) Coupling reaction |
All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in Column II.
Column I | Column II |
---|---|
(A) (CH3)2SiCl2 | (P) Hydrogen halide formation |
(B) XeF4 | (Q) Redox reaction |
(C) Cl2 | (R) Reacts with glass |
(D) VCl5 | (S) Polymerisation |
(T) O2 formation |
Mathematics
$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$ Column-$$I$$
(A)$$\,\,\,\,$$ A line from the origin meets the lines $$\,{{x - 2} \over 1} = {{y - 1} \over { - 2}} = {{z + 1} \over 1}$$
and $${{x - {8 \over 3}} \over 2} = {{y + 3} \over { - 1}} = {{z - 1} \over 1}$$ at $$P$$ and $$Q$$ respectively. If length $$PQ=d,$$ then $${d^2}$$ is
(B)$$\,\,\,\,$$ The values of $$x$$ satisfying $${\tan ^{ - 1}}\left( {x + 3} \right) - {\tan ^{ - 1}}\left( {x - 3} \right) = {\sin ^{ - 1}}\left( {{3 \over 5}} \right)$$ are
(C)$$\,\,\,\,$$ Non-zero vectors $$\overrightarrow a ,\overrightarrow b $$ and $$\overrightarrow c \,\,$$ satisfy $$\overrightarrow a \,.\,\overrightarrow b \, = 0.$$
$$\left( {\overrightarrow b - \overrightarrow a } \right).\left( {\overrightarrow b + \overrightarrow c } \right) = 0$$ and $$2\left| {\overrightarrow b + \overrightarrow c } \right| = \left| {\overrightarrow b - \overrightarrow a } \right|.$$
If $$\overrightarrow a = \mu \overrightarrow b + 4\overrightarrow c \,\,,$$ then the possible values of $$\mu $$ are
(D)$$\,\,\,\,$$ Let $$f$$ be the function on $$\left[ { - \pi ,\pi } \right]$$ given by $$f(0)=9$$
and $$f\left( x \right) = \sin \left( {{{9x} \over 2}} \right)/\sin \left( {{x \over 2}} \right)$$ for $$x \ne 0$$
The value of $${2 \over \pi }\int_{ - \pi }^\pi {f\left( x \right)dx} $$ is
$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$Column-$$II$$
(p)$$\,\,\,\,$$ $$-4$$
(q)$$\,\,\,\,$$ $$0$$
(r)$$\,\,\,\,$$ $$4$$
(s)$$\,\,\,\,$$ $$5$$
(t)$$\,\,\,\,$$ $$6$$
[Note : Here z takes value in the complex plane and Im z and Re z denotes, respectively, the imaginary part and the real part of z.]
Column I
(A) The set of points z satisfying $$\left| {z - i} \right|\left. {z\,} \right\|\,\, = \left| {z + i} \right|\left. {\,z} \right\|$$ is contained in or equal to
(B) The set of points z satisfying $$\left| {z + 4} \right| + \,\left| {z - 4} \right| = 10$$ is contained in or equal to
(C) If $$\left| w \right|$$= 2, then the set of points $$z = w - {1 \over w}$$ is contained in or equal to
(D) If $$\left| w \right|$$ = 1, then the set of points $$z = w + {1 \over w}$$ is contained in or equal to.
Column II
(p) an ellipse with eccentricity $${4 \over 5}$$
(q) the set of points z satisfying Im z = 0
(r) the set of points z satisfying $$\left| {{\rm{Im }}\,{\rm{z }}} \right| \le 1$$
(s) the set of points z satisfying $$\,\left| {{\mathop{\rm Re}\nolimits} \,\,z} \right| < 2$$
(t) the set of points z satisfying $$\left| {\,z} \right| \le 3$$
[Note :[k] denotes the largest integer less than or equal to k ]
Then $$\sum\limits_{r = 1}^{10} {{A_r}\left( {{B_{10}}{B_r} - {C_{10}}{A_r}} \right)} $$ is equal to
Tangents are drawn from the point $$P(3, 4)$$ to the ellipse $${{{x^2}} \over 9} + {{{y^2}} \over 4} = 1$$ touching the ellipse at points $$A$$ and $$B$$.
The coordinates of $$A$$ and $$B$$ are
Tangents are drawn from the point $$P(3, 4)$$ to the ellipse $${{{x^2}} \over 9} + {{{y^2}} \over 4} = 1$$ touching the ellipse at points $$A$$ and $$B$$.
The equation of the locus of the point whose distances from the point $$P$$ and the line $$AB$$ are equal, is
The orthocentre of the triangle $$PAB$$ is
such that $$f'\left( x \right) = 2010\left( {x - 2009} \right){\left( {x - 2010} \right)^2}{\left( {x - 2011} \right)^3}{\left( {x - 2012} \right)^4}$$ for all $$x \in $$$$R$$
If $$g$$ is a function defined on $$R$$ with values in the interval $$\left( {0,\infty } \right)$$ such that
$$$f\left( x \right) = ln\,\left( {g\left( x \right)} \right),\,\,for\,\,all\,\,x \in R$$$
then the number of points in $$R$$ at which $$g$$ has a local maximum is ___________.
$${e^{ - x}}f\left( x \right) = 2 + \int\limits_0^x {\sqrt {{t^4} + 1} \,\,dt,} $$ for all $$x \in \left( { - 1,1} \right)$$,
and let $${f^{ - 1}}$$ be the inverse function of $$f$$. Then $$\left( {{f^{ - 1}}} \right)'\left( 2 \right)$$ is equal to
Let $k$ be a positive real number and let
$$ \begin{aligned} A & =\left[\begin{array}{ccc} 2 k-1 & 2 \sqrt{k} & 2 \sqrt{k} \\ 2 \sqrt{k} & 1 & -2 k \\ -2 \sqrt{k} & 2 k & -1 \end{array}\right] \text { and } \\\\ \mathbf{B} & =\left[\begin{array}{ccc} 0 & 2 k-1 & \sqrt{k} \\ 1-2 k & 0 & 2 \sqrt{k} \\ -\sqrt{k} & -2 \sqrt{k} & 0 \end{array}\right] . \end{aligned} $$
If $\operatorname{det}(\operatorname{adj} A)+\operatorname{det}(\operatorname{adj} B)=10^6$, then $[k]$
is equal to _________.
[ Note : adj M denotes the adjoint of a square matrix M and $[k]$ denotes the largest integer less than or equal to $k$ ].
Consider the polynomial
$$f\left( x \right) = 1 + 2x + 3{x^2} + 4{x^3}.$$
Let $$s$$ be the sum of all distinct real roots of $$f(x)$$ and let $$t = \left| s \right|.$$
The real numbers lies in the interval
Consider the polynomial
$$f\left( x \right) = 1 + 2x + 3{x^2} + 4{x^3}.$$
Let $$s$$ be the sum of all distinct real roots of $$f(x)$$ and let $$t = \left| s \right|.$$
The area bounded by the curve $$y=f(x)$$ and the lines $$x=0,$$ $$y=0$$ and $$x=t,$$ lies in the interval
Consider the polynomial
$$f\left( x \right) = 1 + 2x + 3{x^2} + 4{x^3}.$$
Let $$s$$ be the sum of all distinct real roots of $$f(x)$$ and let $$t = \left| s \right|.$$
The function$$f'(x)$$ is
$$\overrightarrow {AB} = 2\widehat i + 10\widehat j + 11\widehat k$$ and $$\,\overrightarrow {AD} = -\widehat i + 2\widehat j + 2\widehat k$$
The side $$AD$$ is rotated by an acute angle $$\alpha $$ in the plane of the parallelogram so that $$AD$$ becomes $$AD'.$$ If $$AD'$$ makes a right angle with the side $$AB,$$ then the cosine of the angle $$\alpha $$ is given by
Physics
If the radius of the opening of the dropper is $$r$$, the vertical force due to the surface tension on the drop of radius R (assuming $$r$$ << R) is
If r = 5 $$ \times $$ 10−4 m, $$\rho $$ = 103 kg m−3 , g = 10 m/s2 , T = 0.11 Nm−1 , the radius of the drop when it detaches from the dropper is approximately
After the drop detaches, its surface energy is
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A block of mass 2 kg is free to move along the x-axis. It is at rest and from t = 0 onwards, it is subjected to a time-dependent force F(t) in the x-direction. The force F(t) varies with t as shown in the figure. The kinetic energy of the block after 4.5 s is
A biconvex lens of focal length 15 cm is in front of a plane mirror. The distance between the lens and the mirror is 10 cm. A small object is kept at a distance of 30 cm from the lens. The final image is
A large glass slab ($$\mu$$ = 5/3) of thickness 8 cm is placed over a point source of light on a plane surface. It is seen that light emerges out of the top surface of the slab from a circular area of radius R cm. What is the value of R?
Image of an object approaching a convex mirror of radius of curvature 20 m along its optical axis is observed to move from $${{25} \over 3}$$ m to $${{50} \over 7}$$ m in 30 s. What is the speed of the object in km per hour?
To determine the half-life of a radioactive element, a student plots a graph of $$\ln \left| {{{dN(t)} \over {dt}}} \right|$$ versus t. Here, $${{dN(t)} \over {dt}}$$ is the rate of radioactive decay at time t. If the number of radioactive nuclei of this element decreases by a factor of p after 4.16 years, the value of p is __________.
At time t = 0, a battery of 10 V is connected across points A and B in the given circuit. If the capacitors have no charge initially, at what time (in seconds) does the voltage across them becomes 4 V? (Take ln5 = 1.6, ln3 = 1.1)
A diatomic molecule has moment of inertia I. By Bohr's quantization condition, its rotational energy in the nth level (n = 0 is not allowed) is
It is found that the excitation frequency from ground to the first excited state of rotation for the CO molecule is close to $${4 \over \pi } \times {10^{11}}$$ Hz. Then, the moment of inertia of CO molecule about its centre of mass is close to (Take h = 2$$\pi$$ $$\times$$ 10$$-$$34 J-s)
In a CO molecule, the distance between C (mass = 12 amu) and O (mass = 16 amu), where 1 amu $$ = {5 \over 3} \times {10^{ - 27}}$$ kg, is close to :
Two transparent media of refractive indices $\mu_1$ and $\mu_3$ have a solid lens shaped transparent material of refractive index $\mu_2$ between them as shown in figures in Column II. A ray traversing these media is also shown in the figures. In Column I different relationships between $\mu_1, \mu_2$ and $\mu_3$ are given. Match them to the ray diagram shown in Column II :
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You are given many resistances, capacitors and inductors. These are connected to a variable DC voltage source (the first two circuits) or an AC voltage source of 50 Hz frequency (the next three circuits) in different ways as shown in Column II. When a current I (steady state for DC or rms for AC) flows through the circuit, the corresponding voltage $V_1$ and $V_2$ (indicated in circuits) are related as shown in Column I. Match the two :
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