The correct molecular orbital diagram for $\mathrm{F}_2$ molecule in the ground state is :

Consider the following statements related to colloids.

(I) Lyophobic colloids are not formed by simple mixing of dispersed phase and dispersion medium.

(II) For emulsions, both the dispersed phase and the dispersion medium are liquid.

(III) Micelles are produced by dissolving a surfactant in any solvent at any temperature.

(IV) Tyndall effect can be observed from a colloidal solution with dispersed phase having the same refractive index as that of the dispersion medium.

The option with the correct set of statements is :

In the following reactions, $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ are the major products.




The correct statement about $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ is :

A disaccharide $\mathbf{X}$ cannot be oxidised by bromine water. The acid hydrolysis of $\mathbf{X}$ leads to a laevorotatory solution. The disaccharide $\mathbf{X}$ is :

The complex(es), which can exhibit the type of isomerism shown by $\left[\operatorname{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Br}_2\right]$, is(are) :

[en $=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2$ ]

Atoms of metals $\mathrm{x}, \mathrm{y}$, and $\mathrm{z}$ form face-centred cubic (fcc) unit cell of edge length $\mathrm{L}_{\mathrm{x}}$, body-centred cubic (bcc) unit cell of edge length $\mathrm{L}_y$, and simple cubic unit cell of edge length $\mathrm{L}_z$, respectively.

If $\mathrm{r}_{\mathrm{z}}=\frac{\sqrt{3}}{2} r_{\mathrm{y}} ; \mathrm{r}_{\mathrm{y}}=\frac{8}{\sqrt{3}} \mathrm{r}_{\mathrm{x}} ; M_{\mathrm{z}}=\frac{3}{2} M_{\mathrm{y}}$ and $M_{\mathrm{z}}=3 M_{\mathrm{x}}$, then the correct statement(s) is(are) :

[Given: $M_x, M_y$, and $M_z$ are molar masses of metals $x, y$, and $z$, respectively.
$\mathrm{r}_{\mathrm{x}}, \mathrm{r}_{\mathrm{y}}$, and $\mathrm{r}_{\mathrm{z}}$ are atomic radii of metals $\mathrm{x}, \mathrm{y}$, and $\mathrm{z}$, respectively.]

In the following reactions, $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ are the major products.



The correct statement(s) about $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ is(are) :

$\mathrm{H}_2 \mathrm{S}$ (5 moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is $\mathbf{x}$, and the number of moles of electrons involved is $\mathbf{y}$. The value of $(\mathbf{x}+\mathbf{y})$ is ________.

Among $\left[\mathrm{I}_3\right]^{+},\left[\mathrm{SiO}_4\right]^{4-}, \mathrm{SO}_2 \mathrm{Cl}_2, \mathrm{XeF}_2, \mathrm{SF}_4, \mathrm{ClF}_3, \mathrm{Ni}(\mathrm{CO})_4, \mathrm{XeO}_2 \mathrm{~F}_2,\left[\mathrm{PtCl}_4\right]^{2-}, \mathrm{XeF}_4$, and $\mathrm{SOCl}_2$, the total number of species having $s p^3$ hybridised central atom is ________.

Consider the following molecules: $\mathrm{Br}_3 \mathrm{O}_8, \mathrm{~F}_2 \mathrm{O}, \mathrm{H}_2 \mathrm{S}_4 \mathrm{O}_6, \mathrm{H}_2 \mathrm{S}_5 \mathrm{O}_6$, and $\mathrm{C}_3 \mathrm{O}_2$. Count the number of atoms existing in their zero oxidation state in each molecule.

Their sum is _______.

For $\mathrm{He}^{+}$, a transition takes place from the orbit of radius $105.8 \mathrm{pm}$ to the orbit of radius $26.45 \mathrm{pm}$. The wavelength (in nm) of the emitted photon during the transition is _______.

[Use :

Bohr radius, $\mathrm{a}=52.9 \mathrm{pm}$

Rydberg constant, $R_{\mathrm{H}}=2.2 \times 10^{-18} \mathrm{~J}$

Planck's constant, $\mathrm{h}=6.6 \times 10^{-34} \mathrm{~J} \mathrm{~s}$

Speed of light, $\mathrm{c}=3 \times 10^8 \mathrm{~m} \mathrm{~s}^{-1}$ ]

$50 \mathrm{~mL}$ of 0.2 molal urea solution (density $=1.012 \mathrm{~g} \mathrm{~mL}^{-1}$ at $300 \mathrm{~K}$ ) is mixed with $250 \mathrm{~mL}$ of a solution containing $0.06 \mathrm{~g}$ of urea. Both the solutions were prepared in the same solvent. The osmotic pressure (in Torr) of the resulting solution at $300 \mathrm{~K}$ is _______.

[Use: Molar mass of urea $=60 \mathrm{~g} \mathrm{~mol}^{-1}$; gas constant, $\mathrm{R}=62$ L Torr $\mathrm{K}^{-1} \mathrm{~mol}^{-1}$;

Assume, $\Delta_{\text {mix }} \mathrm{H}=0, \Delta_{\text {mix }} \mathrm{V}=0$ ]

The reaction of 4-methyloct-1-ene $(\mathbf{P}, 2.52 \mathrm{~g})$ with $\mathrm{HBr}$ in the presence of $\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CO}\right)_2 \mathrm{O}_2$ gives two isomeric bromides in a $9: 1$ ratio, with a combined yield of $50 \%$. Of these, the entire amount of the primary alkyl bromide was reacted with an appropriate amount of diethylamine followed by treatment with aq. $\mathrm{K}_2 \mathrm{CO}_3$ to give a non-ionic product $\mathbf{S}$ in $100 \%$ yield.

The mass (in mg) of $\mathbf{S}$ obtained is ________.

[Use molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) : $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{Br}=80$ ]

The value of entropy change, $S_\beta-S_\alpha$ (in $\mathrm{J} \mathrm{mol}^{-1} \mathrm{~K}^{-1}$ ), at $300 \mathrm{~K}$ is _______.

[Use : $\ln 2=0.69$

Given : $S_\beta-S_\alpha=0$ at $0 \mathrm{~K}$ ]

$$ \text { The value of enthalpy change, } \mathrm{H}_\beta-\mathrm{H}_\alpha \text { (in } \mathrm{J} \mathrm{mol}^{-1} \text { ), at } 300 \mathrm{~K} \text { is } $$ ________.

The number of heteroatoms present in one molecule of $\mathbf{R}$ is _________.

[Use : Molar mass (in $\left.\mathrm{g} \mathrm{mol}^{-1}\right)$ : $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]

The total number of carbon atoms and heteroatoms present in one molecule of $\mathbf{S}$ is _________.

[Use : Molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ): $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]

Let $f:[1, \infty) \rightarrow \mathbb{R}$ be a differentiable function such that $f(1)=\frac{1}{3}$ and $3 \int\limits_1^x f(t) d t=x f(x)-\frac{x^3}{3}, x \in[1, \infty)$. Let $e$ denote the base of the natural logarithm. Then the value of $f(e)$ is :

Consider an experiment of tossing a coin repeatedly until the outcomes of two consecutive tosses are same. If the probability of a random toss resulting in head is $\frac{1}{3}$, then the probability that the experiment stops with head is :

For any $y \in \mathbb{R}$, let $\cot ^{-1}(y) \in(0, \pi)$ and $\tan ^{-1}(y) \in\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)$. Then the sum of all the solutions of the equation

$\tan ^{-1}\left(\frac{6 y}{9-y^2}\right)+\cot ^{-1}\left(\frac{9-y^2}{6 y}\right)=\frac{2 \pi}{3}$ for $0<|y|<3$, is equal to :

Let the position vectors of the points $P, Q, R$ and $S$ be $\vec{a}=\hat{i}+2 \hat{j}-5 \hat{k}, \vec{b}=3 \hat{i}+6 \hat{j}+3 \hat{k}$, $\vec{c}=\frac{17}{5} \hat{i}+\frac{16}{5} \hat{j}+7 \hat{k}$ and $\vec{d}=2 \hat{i}+\hat{j}+\hat{k}$, respectively. Then which of the following statements is true?

Let $M=\left(a_{i j}\right), i, j \in\{1,2,3\}$, be the $3 \times 3$ matrix such that $a_{i j}=1$ if $j+1$ is divisible by $i$, otherwise $a_{i j}=0$. Then which of the following statements is(are) true?

Let $f:(0,1) \rightarrow \mathbb{R}$ be the function defined as $f(x)=[4 x]\left(x-\frac{1}{4}\right)^2\left(x-\frac{1}{2}\right)$, where $[x]$ denotes the greatest integer less than or equal to $x$. Then which of the following statements is(are) true?

Let $S$ be the set of all twice differentiable functions $f$ from $\mathbb{R}$ to $\mathbb{R}$ such that $\frac{d^2 f}{d x^2}(x)>0$ for all $x \in(-1,1)$. For $f \in S$, let $X_f$ be the number of points $x \in(-1,1)$ for which $f(x)=x$. Then which of the following statements is(are) true?

For $x \in \mathbb{R}$, let $\tan ^{-1}(x) \in\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)$. Then the minimum value of the function $f: \mathbb{R} \rightarrow \mathbb{R}$ defined by $f(x)=\int\limits_0^{x \tan ^{-1} x} \frac{e^{(t-\cos t)}}{1+t^{2023}} d t$ is :

For $x \in \mathbb{R}$, let $y(x)$ be a solution of the differential equation

$\left(x^2-5\right) \frac{d y}{d x}-2 x y=-2 x\left(x^2-5\right)^2$ such that $y(2)=7$.

Then the maximum value of the function $y(x)$ is :

Let $X$ be the set of all five digit numbers formed using 1,2,2,2,4,4,0. For example, 22240 is in $X$ while 02244 and 44422 are not in $X$. Suppose that each element of $X$ has an equal chance of being chosen. Let $p$ be the conditional probability that an element chosen at random is a multiple of 20 given that it is a multiple of 5 . Then the value of $38 p$ is equal to :

Let $A_1, A_2, A_3, \ldots, A_8$ be the vertices of a regular octagon that lie on a circle of radius 2 . Let $P$ be a point on the circle and let $P A_i$ denote the distance between the points $P$ and $A_i$ for $i=1,2, \ldots, 8$. If $P$ varies over the circle, then the maximum value of the product $P A_1 \times P A_2 \times \cdots \cdots \times P A_8$, is :

Let $R=\left\{\left(\begin{array}{lll}a & 3 & b \\ c & 2 & d \\ 0 & 5 & 0\end{array}\right): a, b, c, d \in\{0,3,5,7,11,13,17,19\}\right\}$.

Then the number of invertible matrices in $R$ is :

Let $C_1$ be the circle of radius 1 with center at the origin. Let $C_2$ be the circle of radius $r$ with center at the point $A=(4,1)$, where $1 < r < 3$. Two distinct common tangents $P Q$ and $S T$ of $C_1$ and $C_2$ are drawn. The tangent $P Q$ touches $C_1$ at $P$ and $C_2$ at $Q$. The tangent $S T$ touches $C_1$ at $S$ and $C_2$ at $T$. Mid points of the line segments $P Q$ and $S T$ are joined to form a line which meets the $x$-axis at a point $B$. If $A B=\sqrt{5}$, then the value of $r^2$ is :

$$ \text { Let } a \text { be the area of the triangle } A B C \text {. Then the value of }(64 a)^2 \text { is } $$ :

$$ \text { Then the inradius of the triangle } A B C \text { is } $$ :

Let $p_i$ be the probability that a randomly chosen point has $i$ many friends, $i=0,1,2,3,4$. Let $X$ be a random variable such that for $i=0,1,2,3,4$, the probability $P(X=i)=p_i$. Then the value of $7 E(X)$ is :

Two distinct points are chosen randomly out of the points $A_1, A_2, \ldots, A_{49}$. Let $p$ be the probability that they are friends. Then the value of $7 p$ is :

An electric dipole is formed by two charges $+q$ and $-q$ located in $x y$-plane at $(0,2) \mathrm{mm}$ and $(0,-2) \mathrm{mm}$, respectively, as shown in the figure. The electric potential at point $P(100,100) \mathrm{mm}$ due to the dipole is $V_0$. The charges $+q$ and $-q$ are then moved to the points $(-1,2) \mathrm{mm}$ and $(1,-2) \mathrm{mm}$, respectively. What is the value of electric potential at $P$ due to the new dipole?

Young's modulus of elasticity $Y$ is expressed in terms of three derived quantities, namely, the gravitational constant $G$, Planck's constant $h$ and the speed of light $c$, as $Y=c^\alpha h^\beta G^\gamma$. Which of the following is the correct option?

A particle of mass $m$ is moving in the $x y$-plane such that its velocity at a point $(x, y)$ is given as $\overrightarrow{\mathrm{v}}=\alpha(y \hat{x}+2 x \hat{y})$, where $\alpha$ is a non-zero constant. What is the force $\vec{F}$ acting on the particle?

An ideal gas is in thermodynamic equilibrium. The number of degrees of freedom of a molecule of the gas is $n$. The internal energy of one mole of the gas is $U_n$ and the speed of sound in the gas is $\mathrm{v}_n$. At a fixed temperature and pressure, which of the following is the correct option?

A monochromatic light wave is incident normally on a glass slab of thickness $d$, as shown in the figure. The refractive index of the slab increases linearly from $n_1$ to $n_2$ over the height $h$. Which of the following statement(s) is(are) true about the light wave emerging out of the slab?

An annular disk of mass $M$, inner radius $a$ and outer radius $b$ is placed on a horizontal surface with coefficient of friction $\mu$, as shown in the figure. At some time, an impulse $J_0 \hat{x}$ is applied at a height $h$ above the center of the disk. If $h=h_m$ then the disk rolls without slipping along the $x$-axis. Which of the following statement(s) is(are) correct?

The electric field associated with an electromagnetic wave propagating in a dielectric medium is given by $\vec{E}=30(2 \hat{x}+\hat{y}) \sin \left[2 \pi\left(5 \times 10^{14} t-\frac{10^7}{3} z\right)\right] \mathrm{Vm}^{-1}$. Which of the following option(s) is(are) correct?

[Given: The speed of light in vacuum, $c=3 \times 10^8 \mathrm{~m} \mathrm{~s}^{-1}$ ]

A thin circular coin of mass $5 \mathrm{gm}$ and radius $4 / 3 \mathrm{~cm}$ is initially in a horizontal $x y$-plane. The coin is tossed vertically up ( $+z$ direction) by applying an impulse of $\sqrt{\frac{\pi}{2}} \times 10^{-2} \mathrm{~N}$-s at a distance $2 / 3 \mathrm{~cm}$ from its center. The coin spins about its diameter and moves along the $+z$ direction. By the time the coin reaches back to its initial position, it completes $n$ rotations. The value of $n$ is ________.

[Given: The acceleration due to gravity $g=10 \mathrm{~m} \mathrm{~s}^{-2}$ ]

A rectangular conducting loop of length $4 \mathrm{~cm}$ and width $2 \mathrm{~cm}$ is in the $x y$-plane, as shown in the figure. It is being moved away from a thin and long conducting wire along the direction $\frac{\sqrt{3}}{2} \hat{x}+\frac{1}{2} \hat{y}$ with a constant speed $\mathrm{v}$. The wire is carrying a steady current $I=10 \mathrm{~A}$ in the positive $x$-direction. A current of $10 \mu \mathrm{A}$ flows through the loop when it is at a distance $d=4 \mathrm{~cm}$ from the wire. If the resistance of the loop is $0.1 \Omega$, then the value of $\mathrm{v}$ is ________ $\mathrm{m} \mathrm{s}^{-1}$.

[Given: The permeability of free space $\mu_0=4 \pi \times 10^{-7} \mathrm{~N} \mathrm{~A}^{-2}$ ]

A string of length $1 \mathrm{~m}$ and mass $2 \times 10^{-5} \mathrm{~kg}$ is under tension $T$. When the string vibrates, two successive harmonics are found to occur at frequencies $750 \mathrm{~Hz}$ and $1000 \mathrm{~Hz}$. The value of tension $T$ is ________ Newton.

An incompressible liquid is kept in a container having a weightless piston with a hole. A capillary tube of inner radius $0.1 \mathrm{~mm}$ is dipped vertically into the liquid through the airtight piston hole, as shown in the figure. The air in the container is isothermally compressed from its original volume $V_0$ to $\frac{100}{101} V_0$ with the movable piston. Considering air as an ideal gas, the height $(h)$ of the liquid column in the capillary above the liquid level in $\mathrm{cm}$ is _______.

[Given: Surface tension of the liquid is $0.075 \mathrm{~N} \mathrm{~m}^{-1}$, atmospheric pressure is $10^5 \mathrm{~N} \mathrm{~m}^{-2}$, acceleration due to gravity $(\mathrm{g})$ is $10 \mathrm{~m} \mathrm{~s}^{-2}$, density of the liquid is $10^3 \mathrm{~kg} \mathrm{~m}^{-3}$ and contact angle of capillary surface with the liquid is zero]

In a radioactive decay process, the activity is defined as $A=-\frac{d N}{d t}$, where $N(t)$ is the number of radioactive nuclei at time $t$. Two radioactive sources, $S_1$ and $S_2$ have same activity at time $t=0$. At a later time, the activities of $S_1$ and $S_2$ are $A_1$ and $A_2$, respectively. When $S_1$ and $S_2$ have just completed their $3^{\text {rd }}$ and $7^{\text {th }}$ half-lives, respectively, the ratio $A_1 / A_2$ is _________.

One mole of an ideal gas undergoes two different cyclic processes I and II, as shown in the $P-V$ diagrams below. In cycle I, processes $a, b, c$ and $d$ are isobaric, isothermal, isobaric and isochoric, respectively. In cycle II, processes $a^{\prime}, b^{\prime}, c^{\prime}$ and $d^{\prime}$ are isothermal, isochoric, isobaric and isochoric, respectively. The total work done during cycle $\mathrm{I}$ is $W_I$ and that during cycle II is $W_{I I}$. The ratio $W_I / W_{I I}$ is ________.

When only $S_2$ is emitting sound and it is at $Q$, the frequency of sound measured by the detector in $\mathrm{Hz}$ is _________.

Consider both sources emitting sound. When $S_2$ is at $R$ and $S_1$ approaches the detector with a speed $4 \mathrm{~m} \mathrm{~s}^{-1}$, the beat frequency measured by the detector is _________ $\mathrm{Hz}$.

Considering the air flow to be streamline, the steady mass flow rate of air exiting the chimney is _________ $\mathrm{gm} \mathrm{s}^{-1}$.

When the chimney is closed using a cap at the top, a pressure difference $\Delta P$ develops between the top and the bottom surfaces of the cap. If the changes in the temperature and density of the hot air, due to the stoppage of air flow, are negligible then the value of $\Delta P$ is __________ $\mathrm{N} \mathrm{m}^{-2}$.