IIT-JEE 1980
Paper was held on Fri, Apr 11, 1980 9:00 AM
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Chemistry

1
Element X is strongly electropositive and element Y is strongly electronegative. Both are univalent. The compound formed would be
2
The modern atomic unit is based on the mass of ______.
3
The total no of electron present in 18 ml of water is ______.
4
M is molecular weight of KMnO4. The equivalent wight of KMnO4 when it is converted into K2MnO4 is
5
A hydrocarbon contains 10.5 g of carbon per gram of hydrogen. 1 litre of the hydrocarbon at 127oC and 1 atmosphere weighs 2.8 g. Find the molecular formula.
6
A mixture contains NaCl and unknown chloride MCl.

(i) 1g of this is dissolved in water. Excess of acidified AgNO3 solution is added to it. 2.567 g of white ppt is formed.

(ii) 1 g of original mixture is heated to 300oC. Some vapours come out which are absorbed in acidified AgNO3 solution, 1.341 g of white precipitate was obtained.

Find the molecular weight of unknown chloride.
7
Find
(i) The total number of neutrons and
(ii) The total mass of neutron in 7 mg of 14C
(Assume that mass of neutron = mass of hydrogen atom)
8

(a) 1 litre of a mixture of CO and CO2 is taken. This mixture is passed through a tube containing red hot charcoal. The volume now becomes 1.6 litre. The volumes are measured under the same conditions. Find the composition of the mixture by volume.

(b) A compound contains 28 percent of nitrogen and 72 percent of metal by weight. 3 atoms of metal combine with 2 atoms of N. Find the atomic weight of metal.

9
(i). A sample of MnSO4.4H2O is strongly heated in air. The residue is Mn3O4.

(ii). The residue is dissolved in 100 ml of 0.1N FeSO4 containing dilute H2SO4.

(iii). The solution reacts completely with 50 ml of KMnO4 solution.

(iv). 25 ml of the KMnO4 solution used in step (iii) requires 30 ml of 0.1 N FeSO4 solution for complete reaction.

Find the amount of MnSO4.4H2O present in the sample.
10
(a) One litre of a sample of hard water contains 1 mg of CaCl2 and 1 mg of MgCl2. Find the total hardness in terms of parts of CaCO3 per 106 parts of water by weight.

(b) A sample of hard water contains 20 mg of Ca++ ions per litre. How many milli-equivalent of Na2CO3 would be required to soften 1 litre of the sample?

(c) 1 gm of Mg is burnt in a closed vessel which contains 0.5gm of O2.
      (i) Which reactant is left in excess?
      (ii) Find the weight of the excess reactants.
      (iii) How many milliliters of 0.5N H2SO4 will dissolve the residue in the vessel?
11
Which of the following compounds are covalent?
12
The total number of electrons that take part in forming the bond in N2 is
13
Which of the following is soluble in water?
14
Anhydrous MgCl2 is obtained by hydrated salt with ______.
15
Calcium is obtained by
16
HCL is added to the following oxides. Which one would give H2O2?
17

Explain the following in not more than two sentenses.

A solution of FeCl3 in water gives a brown precipitate on standing.

18

Compound A is a light green crystalline solid. It gives the following tests :

(i) It dissolves in dilute sulphuric acid. No gas is produced.

(ii) A drop of KMnO4 is added to the above solution. The pink colour disappears.

(iii) Compound A is heated strongly. Gases B and C, with pungent smell, come out. A brown residue D is left behind.

(iv) The gas mixture (B and C) is passed into a dichromate solution. The solution turns green.

(v) The green solution from step (iv) gives a white precipitate E with a solution of barium nitrate.

(vi) Residue D from step (iii) is heated on charcoal in a reducing flame. It gives a magnetic substance E.

Name the compounds A, B, C, D and E.

Mathematics

1
The probability that an event $$A$$ happens in one trial of an experiment is $$0.4.$$ Three independent trials of the experiment are performed. The probability that the event $$A$$ happens at least once is
2
Two events $$A$$ and $$B$$ have probabilities $$0.25$$ and $$0.50$$ respectively. The probability that both $$A$$ and $$B$$ occur simultaneously is $$0.14$$. Then the probability that neither $$A$$ nor $$B$$ occurs is
3
The equation $$\,2{\cos ^2}{x \over 2}{\sin ^2}x = {x^2} + {x^{ - 2}};\,0 < x \le {\pi \over 2}$$ has
4
$$ABC$$ is a triangle with $$AB=AC$$. $$D$$ is any point on the side $$BC$$. $$E$$ and $$F$$ are points on the side $$AB$$ and $$AC$$, respectively, such that $$DE$$ is parallel to $$AC$$, and $$DF$$ is parallel to $$AB$$. Prove that $$$DF + FA + AE + ED = AB + AC$$$
5
Given $$A = {\sin ^2}\theta + {\cos ^4}\theta $$ then for all real values of $$\theta $$
6
The smallest positive integer n for which $${\left( {{{1 + i} \over {1 - i}}} \right)^n} = 1$$ is
7
Find the real values of x and y for which the following equation is satisfied $$\,{{(1 + i)x - 2i} \over {3 + i}} + {{(2 + 3i)y + i} \over {3 - i}} = i$$
8
Given $$\alpha + \beta - \gamma = \pi ,$$ prove that
$$\,{\sin ^2}\alpha + {\sin ^2}\beta - {\sin ^2}\gamma = 2\sin \alpha {\mkern 1mu} \sin \beta {\mkern 1mu} \cos y$$
9
Given $$A = \left\{ {x:{\pi \over 6} \le x \le {\pi \over 3}} \right\}$$ and
$$f\left( x \right) = \cos x - x\left( {1 + x} \right);$$ find $$f\left( A \right).$$
10
For all $$\theta $$ in $$\left[ {0,\,\pi /2} \right]$$ show that, $$\cos \left( {\sin \theta } \right) \ge \,\sin \,\left( {\cos \theta } \right).$$
11
Let $$y = \sqrt {{{\left( {x + 1} \right)\left( {x - 3} \right)} \over {\left( {x - 2} \right)}}} $$

Find all the real values of $$x,$$ for which $$y$$ takes real values.

12
Given $${n^4} < {10^n}$$ for a fixed positive integer $$n \ge 2,$$ prove that $${\left( {n + 1} \right)^4} < {10^{n + 1}}.$$
13
For what values of $$m,$$ does the system of equations $$$\matrix{ {3x + my = m} \cr {2x - 5y = 20} \cr } $$$

has solution satisfying the conditions $$x > 0,\,y > 0.$$

14
Find the solution set of the system $$$\matrix{ {x + 2y + z = 1;} \cr {2x - 3y - w = 2;} \cr {x \ge 0;\,y \ge 0;\,z \ge 0;\,w \ge 0.} \cr } $$$
15
Both the roots of the equation (x - b) (x - c) + (x - a) (x - c) + (x - a) (x - b) = 0 are always
16
The least value of the expression $$2\,\,{\log _{10}}\,x\, - \,{\log _x}(0.01)$$ for x > 1, is
17
If $$\,({x^2} + px + 1)\,$$ is a factor of $$(a{x^3} + bx + c)$$, then
18
The interior angles of a polygon are in arithmetic progression. The smallest angle is $${120^ \circ }$$, and the common difference is $${5^ \circ }$$, Find the number of sides of the polygon.
19
The point $$\,\left( {4,\,1} \right)$$ undergoes the following three transformations successively.
Reflection about the line $$y=x$$.
Translation through a distance 2 units along the positive direction of x-axis.
Rotation through an angle $$p/4$$ about the origin in the counter clockwise direction.
Then the final position of the point is given by the coordinates.
20
A straight line $$L$$ is perpendicular to the line $$5x - y = 1.$$ The area of the triangle formed by the line $$L$$ and the coordinate axes is $$5$$. Find the equation of the Line $$L$$.
21
A square is inscribed in the circle $${x^2} + {y^2} - 2x + 4y + 3 = 0$$. Its sides are parallel to the coordinate axes. The one vertex of the square is
22
Two circles $${x^2} + {y^2} = 6$$ and $${x^2} + {y^2} - 6x + 8 = 0$$ are given. Then the equation of the circle through their points of intersection and the point (1, 1) is
23
Given $$y = {{5x} \over {3\sqrt {{{\left( {1 - x} \right)}^2}} }} + {\cos ^2}\left( {2x + 1} \right)$$; Find $${{dy} \over {dx}}$$.
24
$$ABC$$ is a triangle, $$P$$ is a point on $$AB$$, and $$Q$$ is point on $$AC$$ such that $$\angle AQP = \angle ABC$$. Complete the relation $$${{area\,\,of\,\,\Delta APQ} \over {area\,\,of\,\,\Delta ABC}} = {{\left( {...} \right)} \over {A{C^2}}}$$$
25
$$ABC$$ is a triangle with $$\angle B$$ greater than $$\angle C.\,D$$ and $$E$$ are points on $$BC$$ such that $$AD$$ is perpendicular to $$BC$$ and $$AE$$ is the bisector of angle $$A$$. Complete the relation $$$\angle DAE = {1 \over 2}\left[ {\left( {} \right) - \angle C} \right]$$$
26
In a $$\Delta ABC,\,\angle A = {90^ \circ }$$ and $$AD$$ is an altitude. Complete the relation $${{BD} \over {BA}} = {{AB} \over {\left( {....} \right)}}$$.
27
$$ABC$$ is a triangle. $$D$$ is the middle point of $$BC$$. If $$AD$$ is perpendicular to $$AC$$, then prove that $$$\cos A\,\cos C = {{2\left( {{c^2} - {a^2}} \right)} \over {3ac}}$$$
28
(i) $$PQ$$ is a vertical tower. $$P$$ is the foot and $$Q$$ is the top of the tower. $$A, B, C$$ are three points in the horizontal plane through $$P$$. The angles of elevation of $$Q$$ from $$A$$, $$B$$, $$C$$ are equal, and each is equal to $$\theta $$. The sides of the triangle $$ABC$$ are $$a, b, c$$; and the area of the triangle $$ABC$$ is $$\Delta $$. Show that the height of the tower is $${{abc\tan \theta } \over {4\Delta }}$$.

(ii) $$AB$$ is vertical pole. The end $$A$$ is on the level ground. $$C$$ is the middle point of $$AB$$. $$P$$ is a point on the level ground. The portion $$CB$$ subtends an angle $$\beta $$ at $$P$$. If $$AP = n\,AB,$$ then show that tan$$\beta $$ $$ = {n \over {2{n^2} + 1}}$$

Physics

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