JEE Advanced 2022 Paper 2 Online
Paper was held on Sun, Aug 28, 2022 9:00 AM
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Chemistry

1

Concentration of $\mathrm{H}_{2} \mathrm{SO}_{4}$ and $\mathrm{Na}_{2} \mathrm{SO}_{4}$ in a solution is $1 \mathrm{M}$ and $1.8 \times 10^{-2} \mathrm{M}$, respectively. Molar solubility of $\mathrm{PbSO}_{4}$ in the same solution is $\mathrm{X} \times 10^{-\mathrm{Y}} \mathrm{M}$ (expressed in scientific notation). The value of $Y$ is ________.

[Given: Solubility product of $\mathrm{PbSO}_{4}\left(K_{s p}\right)=1.6 \times 10^{-8}$. For $\mathrm{H}_{2} \mathrm{SO}_{4}, K_{a l}$ is very large and $\left.K_{a 2}=1.2 \times 10^{-2}\right]$

2
An aqueous solution is prepared by dissolving $0.1 \mathrm{~mol}$ of an ionic salt in $1.8 \mathrm{~kg}$ of water at $35^{\circ} \mathrm{C}$. The salt remains $90 \%$ dissociated in the solution. The vapour pressure of the solution is $59.724 \mathrm{~mm}$ of Hg. Vapor pressure of water at $35{ }^{\circ} \mathrm{C}$ is $60.000 \mathrm{~mm}$ of $\mathrm{Hg}$. The number of ions present per formula unit of the ionic salt is _________.
3
Consider the strong electrolytes $Z_{m} X_{n}, U_{m} Y_{p}$ and $V_{m} X_{n}$. Limiting molar conductivity ( $\Lambda^{0}$ ) of $\mathrm{U}_{\mathrm{m}} \mathrm{Y}_{\mathrm{p}}$ and $\mathrm{V}_{\mathrm{m}} \mathrm{X}_{\mathrm{n}}$ are 250 and $440 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}$, respectively. The value of $(\mathrm{m}+\mathrm{n}+\mathrm{p})$ is

Given:

Ion $\mathrm{Z}^{\mathrm{n}+}$ $\mathrm{U}^{\mathrm{p}+}$ $\mathrm{V}^{\mathrm{n}+}$ $\mathrm{X}^{\mathrm{m}-}$ $\mathrm{Y}^{\mathrm{m}-}$
$\lambda^{0}\left(\mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}\right)$ $50.0$ $25.0$ $100.0$ $80.0$ $100.0$

$\lambda^{0}$ is the limiting molar conductivity of ions

The plot of molar conductivity ( $\Lambda$ ) of $\mathrm{Z}_{\mathrm{m}} \mathrm{X}_{\mathrm{n}} v s\, \mathrm{c}^{1 / 2}$ is given below.

JEE Advanced 2022 Paper 2 Online Chemistry - Electrochemistry Question 6 English
4
The reaction of $\mathrm{Xe}$ and $\mathrm{O}_{2}{F}_{2}$ gives a $\mathrm{Xe}$ compound $\mathbf{P}$. The number of moles of $\mathrm{HF}$ produced by the complete hydrolysis of $1 \mathrm{~mol}$ of $\mathbf{P}$ is __________.
5
Thermal decomposition of $\mathrm{AgNO}_{3}$ produces two paramagnetic gases. The total number of electrons present in the antibonding molecular orbitals of the gas that has the higher number of unpaired electrons is ____________.
6
The number of isomeric tetraenes (NOT containing $s p$-hybridized carbon atoms) that can be formed from the following reaction sequence is ___________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 5 English
7
The number of $-\mathrm{CH}_{2}-$ (methylene) groups in the product formed from the following reaction sequence is _________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 4 English
8
The total number of chiral molecules formed from one molecule of $\mathbf{P}$ on complete ozonolysis $\left(\mathrm{O}_{3}, \mathrm{Zn} / \mathrm{H}_{2} \mathrm{O}\right)$ is _________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 3 English
9
To check the principle of multiple proportions, a series of pure binary compounds $\left(\mathrm{P}_{\mathrm{m}} \mathrm{Q}_{\mathrm{n}}\right)$ were analyzed and their composition is tabulated below. The correct option(s) is(are)

Compound Weight % of $\mathrm{P}$ Weight % of $\mathrm{Q}$
1 50 50
2 44.4 55.6
3 40 60
10
The correct option(s) about entropy (S) is(are)

$[\mathrm{R}=$ gas constant, $\mathrm{F}=$ Faraday constant, $\mathrm{T}=$ Temperature $]$
11
The compound(s) which react(s) with $\mathrm{NH}_{3}$ to give boron nitride (BN) is(are)
12
The correct option(s) related to the extraction of iron from its ore in the blast furnace operating in the temperature range $900-1500 \mathrm{~K}$ is(are)
13
Considering the following reaction sequence, the correct statement(s) is(are)

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 2 English
14
Among the following, the correct statement(s) about polymers is(are)
15
Atom $\mathrm{X}$ occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to
16
The reaction of $\mathrm{HClO}_{3}$ with $\mathrm{HCl}$ gives a paramagnetic gas, which upon reaction with $\mathrm{O}_{3}$ produces
17
The reaction of $\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}$ and $\mathrm{NaCl}$ in water produces a precipitate that dissolves upon the addition of $\mathrm{HCl}$ of appropriate concentration. The dissolution of the precipitate is due to the formation of
18
Treatment of D-glucose with aqueous $\mathrm{NaOH}$ results in a mixture of monosaccharides, which are

Mathematics

1
Let $\alpha$ and $\beta$ be real numbers such that $-\frac{\pi}{4}<\beta<0<\alpha<\frac{\pi}{4}$.

If $\sin (\alpha+\beta)=\frac{1}{3}$ and $\cos (\alpha-\beta)=\frac{2}{3}$, then the greatest integer less than or equal to

$$ \left(\frac{\sin \alpha}{\cos \beta}+\frac{\cos \beta}{\sin \alpha}+\frac{\cos \alpha}{\sin \beta}+\frac{\sin \beta}{\cos \alpha}\right)^{2} $$ is
2
If $y(x)$ is the solution of the differential equation

$$ x d y-\left(y^{2}-4 y\right) d x=0 \text { for } x > 0, y(1)=2, $$

and the slope of the curve $y=y(x)$ is never zero, then the value of $10 y(\sqrt{2})$ is
3
The greatest integer less than or equal to

$$ \int_{1}^{2} \log _{2}\left(x^{3}+1\right) d x+\int_{1}^{\log _{2} 9}\left(2^{x}-1\right)^{\frac{1}{3}} d x $$

is ___________.
4
The product of all positive real values of $x$ satisfying the equation

$$ x^{\left(16\left(\log _{5} x\right)^{3}-68 \log _{5} x\right)}=5^{-16} $$

is __________.
5
If

$$ \beta=\lim \limits_{x \to 0} \frac{e^{x^{3}}-\left(1-x^{3}\right)^{\frac{1}{3}}+\left(\left(1-x^{2}\right)^{\frac{1}{2}}-1\right) \sin x}{x \sin ^{2} x}, $$

then the value of $6 \beta$ is ___________.
6
Let $\beta$ be a real number. Consider the matrix

$$ A=\left(\begin{array}{ccc} \beta & 0 & 1 \\ 2 & 1 & -2 \\ 3 & 1 & -2 \end{array}\right) $$

If $A^{7}-(\beta-1) A^{6}-\beta A^{5}$ is a singular matrix, then the value of $9 \beta$ is _________.
7
Consider the hyperbola

$$ \frac{x^{2}}{100}-\frac{y^{2}}{64}=1 $$

with foci at $S$ and $S_{1}$, where $S$ lies on the positive $x$-axis. Let $P$ be a point on the hyperbola, in the first quadrant. Let $\angle S P S_{1}=\alpha$, with $\alpha<\frac{\pi}{2}$. The straight line passing through the point $S$ and having the same slope as that of the tangent at $P$ to the hyperbola, intersects the straight line $S_{1} P$ at $P_{1}$. Let $\delta$ be the distance of $P$ from the straight line $S P_{1}$, and $\beta=S_{1} P$. Then the greatest integer less than or equal to $\frac{\beta \delta}{9} \sin \frac{\alpha}{2}$ is ________.
8
Consider the functions $f, g: \mathbb{R} \rightarrow \mathbb{R}$ defined by

$$ f(x)=x^{2}+\frac{5}{12} \quad \text { and } \quad g(x)= \begin{cases}2\left(1-\frac{4|x|}{3}\right), & |x| \leq \frac{3}{4} \\ 0, & |x|>\frac{3}{4}\end{cases} $$

If $\alpha$ is the area of the region

$$ \left\{(x, y) \in \mathbb{R} \times \mathbb{R}:|x| \leq \frac{3}{4}, 0 \leq y \leq \min \{f(x), g(x)\}\right\}, $$

then the value of $9 \alpha$ is
9
Let $P Q R S$ be a quadrilateral in a plane, where

$Q R=1, \angle P Q R=\angle Q R S=70^{\circ}, \angle P Q S=15^{\circ}$ and $\angle P R S=40^{\circ}$.

If $\angle R P S=\theta^{\circ}, P Q=\alpha$ and $P S=\beta$, then the interval(s) that contain(s) the value of

$4 \alpha \beta \sin \theta^{\circ}$ is/are
10
Let

$$ \alpha=\sum\limits_{k = 1}^\infty {{{\sin }^{2k}}\left( {{\pi \over 6}} \right)} $$

Let $g:[0,1] \rightarrow \mathbb{R}$ be the function defined by

$$ g(x)=2^{\alpha x}+2^{\alpha(1-x)} . $$

Then, which of the following statements is/are TRUE ?
11
Let $\bar{z}$ denote the complex conjugate of a complex number $z$. If $z$ is a non-zero complex number for which both real and imaginary parts of $$ (\bar{z})^{2}+\frac{1}{z^{2}} $$ are integers, then which of the following is/are possible value(s) of $|z|$ ?
12
Let $G$ be a circle of radius $R>0$. Let $G_{1}, G_{2}, \ldots, G_{n}$ be $n$ circles of equal radius $r>0$. Suppose each of the $n$ circles $G_{1}, G_{2}, \ldots, G_{n}$ touches the circle $G$ externally. Also, for $i=1,2, \ldots, n-1$, the circle $G_{i}$ touches $G_{i+1}$ externally, and $G_{n}$ touches $G_{1}$ externally. Then, which of the following statements is/are TRUE?
13
Let $\hat{\imath}, \hat{\jmath}$ and $\hat{k}$ be the unit vectors along the three positive coordinate axes. Let

$$ \begin{aligned} & \vec{a}=3 \hat{\imath}+\hat{\jmath}-\hat{k} \text {, } \\ & \vec{b}=\hat{\imath}+b_{2} \hat{\jmath}+b_{3} \hat{k}, \quad b_{2}, b_{3} \in \mathbb{R} \text {, } \\ & \vec{c}=c_{1} \hat{\imath}+c_{2} \hat{\jmath}+c_{3} \hat{k}, \quad c_{1}, c_{2}, c_{3} \in \mathbb{R} \end{aligned} $$

be three vectors such that $b_{2} b_{3}>0, \vec{a} \cdot \vec{b}=0$ and

$$ \left(\begin{array}{ccc} 0 & -c_{3} & c_{2} \\ c_{3} & 0 & -c_{1} \\ -c_{2} & c_{1} & 0 \end{array}\right)\left(\begin{array}{l} 1 \\ b_{2} \\ b_{3} \end{array}\right)=\left(\begin{array}{r} 3-c_{1} \\ 1-c_{2} \\ -1-c_{3} \end{array}\right) . $$

Then, which of the following is/are TRUE?
14
For $x \in \mathbb{R}$, let the function $y(x)$ be the solution of the differential equation

$$ \frac{d y}{d x}+12 y=\cos \left(\frac{\pi}{12} x\right), \quad y(0)=0 $$

Then, which of the following statements is/are TRUE ?
15
Consider 4 boxes, where each box contains 3 red balls and 2 blue balls. Assume that all 20 balls are distinct. In how many different ways can 10 balls be chosen from these 4 boxes so that from each box at least one red ball and one blue ball are chosen ?
16
If $M=\left(\begin{array}{rr}\frac{5}{2} & \frac{3}{2} \\ -\frac{3}{2} & -\frac{1}{2}\end{array}\right)$, then which of the

following matrices is equal to $M^{2022} ?$
17
Suppose that

Box-I contains 8 red, 3 blue and 5 green balls,

Box-II contains 24 red, 9 blue and 15 green balls,

Box-III contains 1 blue, 12 green and 3 yellow balls,

Box-IV contains 10 green, 16 orange and 6 white balls.

A ball is chosen randomly from Box-I; call this ball $b$. If $b$ is red then a ball is chosen randomly from Box-II, if $b$ is blue then a ball is chosen randomly from Box-III, and if $b$ is green then a ball is chosen randomly from Box-IV. The conditional probability of the event 'one of the chosen balls is white' given that the event 'at least one of the chosen balls is green' has happened, is equal to

18
For positive integer $n$, define

$$ f(n)=n+\frac{16+5 n-3 n^{2}}{4 n+3 n^{2}}+\frac{32+n-3 n^{2}}{8 n+3 n^{2}}+\frac{48-3 n-3 n^{2}}{12 n+3 n^{2}}+\cdots+\frac{25 n-7 n^{2}}{7 n^{2}} . $$

Then, the value of $$\mathop {\lim }\limits_{n \to \infty } f\left( n \right)$$ is equal to :

Physics

1
A particle of mass $1 \mathrm{~kg}$ is subjected to a force which depends on the position as $\vec{F}=$ $-k(x \hat{\imath}+y \hat{\jmath}) \mathrm{kg}\, \mathrm{m} \mathrm{s}^{-2}$ with $k=1 \mathrm{~kg} \mathrm{~s}^{-2}$. At time $t=0$, the particle's position $\vec{r}=$ $\left(\frac{1}{\sqrt{2}} \hat{\imath}+\sqrt{2} \hat{\jmath}\right) m$ and its velocity $\vec{v}=\left(-\sqrt{2} \hat{\imath}+\sqrt{2} \hat{\jmath}+\frac{2}{\pi} \hat{k}\right) m s^{-1}$. Let $v_{x}$ and $v_{y}$ denote the $x$ and the $y$ components of the particle's velocity, respectively. Ignore gravity. When $z=0.5 \mathrm{~m}$, the value of $\left(x v_{y}-y v_{x}\right)$ is __________ $m^{2} s^{-1}$.
2
In a radioactive decay chain reaction, ${ }_{90}^{230} \mathrm{Th}$ nucleus decays into ${ }_{84}^{214} \mathrm{Po}$ nucleus. The ratio of the number of $\alpha$ to number of $\beta^{-}$particles emitted in this process is ________.
3

Two resistances $R_{1}=X \Omega$ and $R_{2}=1 \Omega$ are connected to a wire $A B$ of uniform resistivity, as shown in the figure. The radius of the wire varies linearly along its axis from $0.2 \mathrm{~mm}$ at $A$ to $1 \mathrm{~mm}$ at $B$. A galvanometer $(\mathrm{G})$ connected to the center of the wire, $50 \mathrm{~cm}$ from each end along its axis, shows zero deflection when $A$ and $B$ are connected to a battery. The value of $X$ is ____________.

JEE Advanced 2022 Paper 2 Online Physics - Current Electricity Question 5 English

4

In a particular system of units, a physical quantity can be expressed in terms of the electric charge $e$, electron mass $m_{e}$, Planck's constant $h$, and Coulomb's constant $k=\frac{1}{4 \pi \epsilon_{0}}$, where $\epsilon_{0}$ is the permittivity of vacuum. In terms of these physical constants, the dimension of the magnetic field is $[B]=[e]^{\alpha}\left[m_{e}\right]^{\beta}[h]^{\gamma}[k]^{\delta}$. The value of $\alpha+\beta+\gamma+\delta$ is _______.

5

Consider a configuration of $n$ identical units, each consisting of three layers. The first layer is a column of air of height $h=\frac{1}{3} \mathrm{~cm}$, and the second and third layers are of equal thickness $d=$ $\frac{\sqrt{3}-1}{2} \mathrm{~cm}$, and refractive indices $\mu_{1}=\sqrt{\frac{3}{2}}$ and $\mu_{2}=\sqrt{3}$, respectively. A light source 0 is placed on the top of the first unit, as shown in the figure. A ray of light from 0 is incident on the second layer of the first unit at an angle of $\theta=60^{\circ}$ to the normal. For a specific value of $n$, the ray of light emerges from the bottom of the configuration at a distance $l=\frac{8}{\sqrt{3}} \mathrm{~cm}$, as shown in the figure. The value of $n$ is ________.

JEE Advanced 2022 Paper 2 Online Physics - Geometrical Optics Question 16 English

6

A charge $q$ is surrounded by a closed surface consisting of an inverted cone of height $h$ and base radius $R$, and a hemisphere of radius $R$ as shown in the figure. The electric flux through the conical surface is $\frac{n q}{6 \epsilon_{0}}$ (in SI units). The value of $n$ is _______.

JEE Advanced 2022 Paper 2 Online Physics - Electrostatics Question 20 English

7

On a frictionless horizontal plane, a bob of mass $m=0.1 \mathrm{~kg}$ is attached to a spring with natural length $l_{0}=0.1 \mathrm{~m}$. The spring constant is $k_{1}=0.009 \,\mathrm{Nm}^{-1}$ when the length of the spring $l>l_{0}$ and is $k_{2}=0.016 \,\mathrm{Nm}^{-1}$ when $l < l_{0}$. Initially the bob is released from $l=$ $0.15 \mathrm{~m}$. Assume that Hooke's law remains valid throughout the motion. If the time period of the full oscillation is $T=(n \pi) s$, then the integer closest to $n$ is __________.

8

An object and a concave mirror of focal length $f=10 \mathrm{~cm}$ both move along the principal axis of the mirror with constant speeds. The object moves with speed $V_{0}=15 \mathrm{~cm} \mathrm{~s}^{-1}$ towards the mirror with respect to a laboratory frame. The distance between the object and the mirror at a given moment is denoted by $u$. When $u=30 \mathrm{~cm}$, the speed of the mirror $V_{m}$ is such that the image is instantaneously at rest with respect to the laboratory frame, and the object forms a real image. The magnitude of $V_{m}$ is _________ $\mathrm{cm} \,\mathrm{s}^{-1}$.

JEE Advanced 2022 Paper 2 Online Physics - Geometrical Optics Question 15 English

9

In the figure, the inner (shaded) region $A$ represents a sphere of radius $r_{A}=1$, within which the electrostatic charge density varies with the radial distance $r$ from the center as $\rho_{A}=k r$, where $k$ is positive. In the spherical shell $B$ of outer radius $r_{B}$, the electrostatic charge density varies as $\rho_{B}=$ $\frac{2 k}{r}$. Assume that dimensions are taken care of. All physical quantities are in their SI units.

JEE Advanced 2022 Paper 2 Online Physics - Electrostatics Question 19 English

Which of the following statement(s) is(are) correct?

10
In Circuit-1 and Circuit- 2 shown in the figures, $R_{1}=1 \,\Omega, R_{2}=2 \,\Omega$ and $R_{3}=3 \,\Omega$.

$P_{1}$ and $P_{2}$ are the power dissipations in Circuit-1 and Circuit-2 when the switches $\mathrm{S}_{1}$ and $\mathrm{S}_{2}$ are in open conditions, respectively.

$Q_{1}$ and $Q_{2}$ are the power dissipations in Circuit-1 and Circuit-2 when the switches $\mathrm{S}_{1}$ and $\mathrm{S}_{2}$ are in closed conditions, respectively.

JEE Advanced 2022 Paper 2 Online Physics - Current Electricity Question 4 English
Which of the following statement(s) is(are) correct?
11
A bubble has surface tension $S$. The ideal gas inside the bubble has ratio of specific heats $\gamma=$ $\frac{5}{3}$. The bubble is exposed to the atmosphere and it always retains its spherical shape. When the atmospheric pressure is $P_{a 1}$, the radius of the bubble is found to be $r_{1}$ and the temperature of the enclosed gas is $T_{1}$. When the atmospheric pressure is $P_{a 2}$, the radius of the bubble and the temperature of the enclosed gas are $r_{2}$ and $T_{2}$, respectively.

Which of the following statement(s) is(are) correct?
12
A disk of radius $\mathrm{R}$ with uniform positive charge density $\sigma$ is placed on the $x y$ plane with its center at the origin. The Coulomb potential along the $z$-axis is

$$ V(z)=\frac{\sigma}{2 \epsilon_{0}}\left(\sqrt{R^{2}+z^{2}}-z\right) . $$

A particle of positive charge $q$ is placed initially at rest at a point on the $z$ axis with $z=z_{0}$ and $z_{0}>0$. In addition to the Coulomb force, the particle experiences a vertical force $\vec{F}=-c \hat{k}$ with $c>0$. Let $\beta=\frac{2 c \epsilon_{0}}{q \sigma}$.

Which of the following statement(s) is(are) correct?
13

A double slit setup is shown in the figure. One of the slits is in medium 2 of refractive index $n_{2}$. The other slit is at the interface of this medium with another medium 1 of refractive index $n_{1}\left(\neq n_{2}\right)$. The line joining the slits is perpendicular to the interface and the distance between the slits is $d$. The slit widths are much smaller than $d$. A monochromatic parallel beam of light is incident on the slits from medium 1. A detector is placed in medium 2 at a large distance from the slits, and at an angle $\theta$ from the line joining them, so that $\theta$ equals the angle of refraction of the beam. Consider two approximately parallel rays from the slits received by the detector.

JEE Advanced 2022 Paper 2 Online Physics - Wave Optics Question 7 English

Which of the following statement(s) is(are) correct?

14

In the given $P-V$ diagram, a monoatomic gas $\left(\gamma=\frac{5}{3}\right)$ is first compressed adiabatically from state $A$ to state $B$. Then it expands isothermally from state $B$ to state $C$. [Given: $\left(\frac{1}{3}\right)^{0.6} \simeq 0.5, \ln 2 \simeq 0.7$ ].

JEE Advanced 2022 Paper 2 Online Physics - Heat and Thermodynamics Question 18 English

Which of the following statement(s) is(are) correct?

15

A flat surface of a thin uniform disk $A$ of radius $R$ is glued to a horizontal table. Another thin uniform disk $B$ of mass $M$ and with the same radius $R$ rolls without slipping on the circumference of $A$, as shown in the figure. A flat surface of $B$ also lies on the plane of the table. The center of mass of $B$ has fixed angular speed $\omega$ about the vertical axis passing through the center of $A$. The angular momentum of $B$ is $n M \omega R^{2}$ with respect to the center of $A$. Which of the following is the value of $n$ ?

JEE Advanced 2022 Paper 2 Online Physics - Rotational Motion Question 18 English

16

When light of a given wavelength is incident on a metallic surface, the minimum potential needed to stop the emitted photoelectrons is $6.0 \mathrm{~V}$. This potential drops to $0.6 \mathrm{~V}$ if another source with wavelength four times that of the first one and intensity half of the first one is used. What are the wavelength of the first source and the work function of the metal, respectively? [Take $\frac{h c}{e}=1.24 \times$ $10^{-6} \mathrm{JmC}^{-1}$.]

17

Area of the cross-section of a wire is measured using a screw gauge. The pitch of the main scale is $0.5 \mathrm{~mm}$. The circular scale has 100 divisions and for one full rotation of the circular scale, the main scale shifts by two divisions. The measured readings are listed below.

Measurement condition Main scale reading Circular scale reading
Two arms of gauge touching
each other without wire
0 division 4 divisions
Attempt-1: With wire 4 divisions 20 divisions
Attempt-2: With wire 4 divisions 16 divisions

What are the diameter and cross-sectional area of the wire measured using the screw gauge?

18

Which one of the following options represents the magnetic field $\vec{B}$ at $\mathrm{O}$ due to the current flowing in the given wire segments lying on the $x y$ plane?

JEE Advanced 2022 Paper 2 Online Physics - Magnetism Question 10 English

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