IIT-JEE 1990
Paper was held on Wed, Apr 11, 1990 9:00 AM
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Chemistry

1
Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g/ml
2
The oxidation number of phosphorus in Ba(H2PO2) is :
3
A mixture of H2C2O4 (oxalic acid) and NaHC2O4 weighing 2.02 g was dissolved in water and solution made upto one litre. Ten millilitres of the solution required 3.0 ml. of 0.1 N sodium hydroxide solution for complete neutralization. In another experiment, 10.0 ml. of the same solution, in hot dilute sulphuric acid medium. require 4.0 ml. of 0.1 N potassium permanganate solution for complete reaction. Calculate the amount of H2C2O4 and NaHC2O4 in the mixture.
4
A solid mixture (5.0 g) consisting of lead nitrate and sodium nitrate was headed below 600oC until the weight of the residue was constant. If the loss in weight 28.0 percent, find the amount of lead nitrate and sodium nitrate in the mixture.
5
According to Bohr's theory, the electronic energy of hydrogen atom in the nth Bohr's orbit is given by $${E_n} = {{ - 21.6 \times {{10}^{ - 19}}} \over {{n^2}}}J$$. Calculate the longest wavelength of light (in Å) that will be needed to remove an electron from the third Bohr orbit of the He+ ion.
6
Amongst the following elements (whose electronic configuration are given below), the one having the highest ionization energy is:
7
The shape of [CH3]+ is _____.
8
The presence of polar bonds in a poly-atomic molecule suggests that the molecule has non-zero dipole moment.
9
When zeolite, which is hydrated sodium aluminium silicate is treated with hard water the sodium ions are exchanged with
10
The freezing point of equimolal aqueous solutions will be highest for
11
The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile non-electrolyte solid weighing 2.175 g is added to 39.0 g of benzene. The vapour pressure of the solution is 600 mm Hg. What is the molecular weight of the solid substance?
12

Give the IUPAC name of the following compound :

IIT-JEE 1990 Chemistry - Basics of Organic Chemistry Question 14 English

Mathematics

1
Prove that for any positive integer $$k$$,
$${{\sin 2kx} \over {\sin x}} = 2\left[ {\cos x + \cos 3x + ......... + \cos \left( {2k - 1} \right)x} \right]$$
Hence prove that $$\int\limits_0^{\pi /2} {\sin 2kx\,\cot \,x\,dx = {\pi \over 2}} $$
2
Show that $$\int\limits_0^{\pi /2} {f\left( {\sin 2x} \right)\sin x\,dx = \sqrt 2 } \int\limits_0^{\pi /4} {f\left( {\cos 2x} \right)\cos x\,dx} $$
3
Compute the area of the region bounded by the curves $$\,y = ex\,\ln x$$ and $$y = {{\ln x} \over {ex}}$$ where $$ln$$ $$e=1.$$
4
Let $$A$$ and $$B$$ be two events such that $$P\,\,\left( A \right)\,\, = \,\,0.3$$ and $$P\left( {A \cup B} \right) = 0.8.$$ If $$A$$ and $$B$$ are independent events then $$P(B)=$$ ................
5
A is a set containing $$n$$ elements. $$A$$ subset $$P$$ of $$A$$ is chosen at random. The set $$A$$ is reconstructed by replacing the elements of $$P.$$ $$A$$ subset $$Q$$ of $$A$$ is again chosen at random. Find the probability that $$P$$ and $$Q$$ have no common elements.
6
Let $$\overrightarrow A = 2\overrightarrow i + \overrightarrow k ,\,\overrightarrow B = \overrightarrow i + \overrightarrow j + \overrightarrow k ,$$ and $$\overrightarrow C = 4\overrightarrow i - 3\overrightarrow j + 7\overrightarrow k .$$ Determine a vector $$\overrightarrow R .$$ Satisfying $$\overrightarrow R \times \overrightarrow B = \overrightarrow C \times \overrightarrow B $$ and $$\overrightarrow R \,.\,\overrightarrow A = 0$$
7
Let $${z_1}$$ = 10 + 6i and $${z_2}$$ = 4 + 6i. If Z is any complex number such that the argument of $${{(z - {z_1})} \over {(z - {z_2})}}\,is{\pi \over 4}$$ , then prove that $$\left| {z - 7 - 9i} \right| = 3\sqrt 2 $$.
8
If $$\int {{{4{e^x} + 6{e^{ - x}}} \over {9{e^x} - 4{e^{ - x}}}}\,dx = Ax + B\,\,\log \left( {9{e^{2x}} - 4} \right) + C,} $$ then
$$A = .....,B = .....$$ and $$C = .....$$
9
The equation $$\left( {\cos p - 1} \right){x^2} + \left( {\cos p} \right)x + \sin p = 0\,$$ In the variable x, has real roots. Then p can take any value in the interval
10
$$ABC$$ is a triangle such that $$$\sin \left( {2A + B} \right) = \sin \left( {C - A} \right) = \, - \sin \left( {B + 2C} \right) = {1 \over 2}.$$$

If $$A,\,B$$ and $$C$$ are in arithmetic progression, determine the values of $$A,\,B$$ and $$C$$.

11
If $$\,x < 0,\,\,y < 0,\,\,x + y + {x \over y} = {1 \over 2}$$ and $$(x + y)\,{x \over y} = - {1 \over 2}$$, then x =..........and y =.........
12
The number of solutions of the equation sin$${(e)^x} = {5^x} + {5^{ - x}}$$ is
13
Prove that $${{{n^7}} \over 7} + {{{n^5}} \over 5} + {{2{n^3}} \over 3} - {n \over {105}}$$ is an integer for every positive integer $$n$$
14
The number $${\log _2}\,7$$ is
15
If $${\log _3}\,2\,,\,\,{\log _3}\,({2^x} - 5)\,,\,and\,\,{\log _3}\,\left( {{2^x} - {7 \over 2}} \right)$$ are in arithmetic progression, determine the value of x.
16
Line $$L$$ has intercepts $$a$$ and $$b$$ on the coordinate axes. When the axes are rotated through a given angle, keeping the origin fixed, the same line $$L$$ has intercepts $$p$$ and $$q$$, then
17
A line cuts the $$x$$-axis at $$A (7, 0)$$ and the $$y$$-axis at $$B (0, -5)$$. A variable line $$PQ$$ is drawn perpendicular to $$AB$$ cutting the $$x$$axis in $$P$$ and they $$Y$$-axis in $$Q$$. If $$AQ$$ and $$BP$$ intersect at $$R$$, find the locus of R.
18
Straight lines $$3x + 4y = 5$$ and $$4x - 3y = 15$$ intersect at the point $$A$$. Points $$B$$ and $$C$$ are choosen on these two lines such that $$AB = AC$$. Determine the possible equations of the line $$BC$$ passing through the point $$(1, 2)$$.
19
A circle touches the line y = x at a point P such that OP = $${4\sqrt 2 \,}$$, where O is the origin. The circle contains the point (- 10, 2) in its interior and the length of its chord on the line x + y = 0 is $${6\sqrt 2 \,}$$. Determine the equation of the circle.
20
If $$f\left( x \right) = \left| {x - 2} \right|$$ and $$g\left( x \right) = f\left[ {f\left( x \right)} \right]$$, then $$g'\left( x \right) = ...............$$ for $$x > 20$$
21
Let $$f(x)$$ be a quadratic expression which is positive for all the real values of $$x$$. If $$g(x)=f(x)+f''(x)$$, then for any real $$x$$,
22
In a triangle $$ABC$$, angle $$A$$ is greater than angle $$B$$. If the measures of angles $$A$$ and $$B$$ satify the equation $$3{\mathop{\rm sinx}\nolimits} - 4si{n^3}x - k = 0,$$ $$0 < k < 1$$, then the measure of angle $$C$$ is
23
A vertical tower $$PQ$$ stands at a point $$P$$. Points $$A$$ and $$B$$ are located to the South and East of $$P$$ respectively. $$M$$ is the mid point of $$AB$$. $$PAM$$ is an equilateral triangle; and $$N$$ is the foot of the perpendicular from $$P$$ and $$AB$$. Let $$AN$$$$=20$$ mrtres and the angle of elevation of the top of the tower at $$N$$ is $${\tan ^{ - 1}}\left( 2 \right)$$. Determine the height of the tower and the angles of elevation of the top of the tower at $$A$$ and $$B$$.
24
Show that $$2\sin x + \tan x \ge 3x$$ where $$0 \le x < {\pi \over 2}$$.
25
A point $$P$$ is given on the circumference of a circle of radius $$r$$. Chord $$QR$$ is parallel to the tangent at $$P$$. Determine the maximum possible area of the triangle $$PQR$$.
26
Let $$f:R \to R$$ and $$\,\,g:R \to R$$ be continuous functions. Then the value of the integral
$$\int\limits_{ - \pi /2}^{\pi /2} {\left[ {f\left( x \right) + f\left( { - x} \right)} \right]\left[ {g\left( x \right) - g\left( { - x} \right)} \right]dx} $$ is

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