Among the following complexes (K-P),

K₃[Fe(CN)₆] (K), [Co(NH₃)₆]Cl₃ (L), Na₃[Co(oxalate)₃] (M), [Ni(H₂O)₃]Cl₂ (N), K₂[Pt(CN)₄] (O) and [Zn(H₂O)₆(NO₃)₂] (P)

The diamagnetic complexes are

The major product of the following reaction is

Passing H₂S gas into a mixture of Mn²⁺, Ni²⁺, Cu²⁺ and Hg²⁺ ions in an acidified aqueous solution precipitates

Amongst the compounds given, the one that would from a brilliant coloured dye on treatment with NaNO₂ in dil. HCl followed by addition to an alkaline solution of $$\beta$$-naphthlol is

The following carbohydrate is

The equilibrium

$$2C{u^+} \to Cu^\circ + C{u^{2+}}$$

In aqueous medium at 25$$^\circ$$C shifts towards the left in the presence of

The correct functional group X and the reagent/reaction condition Y in the following scheme are

Reduction of the metal centre in aqueous permanganate ion involves

The total number of contributing structure showing hyper-conjugation (involving C-H bonds) for the following carbocation is _________.

Among the following, the number of compounds that can react with PCl₅ to given POCl₃ is _____________.

O₂, CO₂, SO₂, H₂O, H₂SO₄, P₄O₁₀

The volume (in mL) of 0.1 M AgNO₃ required for complete precipitation of chloride ions present in 30 mL of 0.01 M solution of $$[Cr{({H_2}O)_5}Cl]C{l_2}$$, as silver chloride is close to ____________.

The maximum number of isomers (including stereoisomers) that are possible on mono-chlorination of the following compound, is ____________.

Match the reactions in Column I with appropriate types of steps/reactive intermediate involved in these reactions as given in Column II :

	Column I		Column II
(A)		(P)	Nucleophilic substitution
(B)		(Q)	Electrophilic substitution
(C)		(R)	Dehydration
(D)		(S)	Nucleophilic
		(T)	Carbanion

Then the value of $${{{{\left| x \right|}^2} + {{\left| y \right|}^2} + {{\left| z \right|}^2}} \over {{{\left| a \right|}^2} + {{\left| b \right|}^2} + {{\left| c \right|}^2}}}$$ is

have one root in common is

Let $${R_1} = \int\limits_{ - 1}^2 {xf\left( x \right)dx,} $$ and $${R_2}$$ be the area of the region bounded by $$y=f(x),$$ $$x=-1,$$ $$x=2,$$ and the $$x$$-axis. Then

$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$ Column-$$I$$
(A) $$\,\,\,\,$$If $$\overrightarrow a = \widehat j + \sqrt 3 \widehat k,\overrightarrow b = - \widehat j + \sqrt 3 \widehat k$$ and $$\overrightarrow c = 2\sqrt 3 \widehat k$$ form a triangle, then the internal angle of the triangle between $$\overrightarrow a $$ and $$\overrightarrow b $$ is
(B)$$\,\,\,\,$$ If $$\int\limits_a^b {\left( {f\left( x \right) - 3x} \right)dx = {a^2} - {b^2},} $$ then the value of $$f$$ $$\left( {{\pi \over 6}} \right)$$ is
(C)$$\,\,\,\,$$ The value of $${{{\pi ^2}} \over {\ell n3}}\int\limits_{7/6}^{5/6} {\sec \left( {\pi x} \right)dx} $$ is
(D)$$\,\,\,\,$$ The maximum value of $$\left| {Arg\left( {{1 \over {1 - z}}} \right)} \right|$$ for $$\left| z \right| = 1,\,z \ne 1$$ is given by

$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$ Column-$$II$$
(p)$$\,\,\,\,$$ $${{\pi \over 6}}$$
(q)$$\,\,\,\,$$ $${{2\pi \over 3}}$$
(r)$$\,\,\,\,$$ $${{\pi \over 3}}$$
(s)$$\,\,\,\,$$ $$\pi $$
(t) $$\,\,\,\,$$ $${{\pi \over 2}}$$

If $$\mathop {\lim }\limits_{x \to 0} {[1 + x\ln (1 + {b^2})]^{1/x}} = 2b{\sin ^2}\theta $$, $$b > 0$$ and $$\theta \in ( - \pi ,\pi ]$$, then the value of $$\theta$$ is

Let f(x) = x² and g(x) = sin x for all x $$\in$$ R. Then the set of all x satisfying $$(f \circ g \circ g \circ f)(x) = (g \circ g \circ f)(x)$$, where $$(f \circ g)(x) = f(g(x))$$, is

Let $$\omega$$ $$\ne$$ 1 be a cube root of unity and S be the set of all non-singular matrices of the form $$\left[ {\matrix{ 1 & a & b \cr \omega & 1 & c \cr {{\omega ^2}} & \omega & 1 \cr } } \right]$$, where each of a, b, and c is either $$\omega$$ or $$\omega$$². Then the number of distinct matrices in the set S is

If $$f(x) = \left\{ {\matrix{ { - x - {\pi \over 2},} & {x \le - {\pi \over 2}} \cr { - \cos x} & { - {\pi \over 2} < x \le 0} \cr {x - 1} & {0 < x \le 1} \cr {\ln x} & {x > 1} \cr } } \right.$$, then

Let $$f:(0,1) \to R$$ be defined by $$f(x) = {{b - x} \over {1 - bx}}$$, where b is a constant such that $$0 < b < 1$$. Then

Let L be a normal to the parabola y² = 4x. If L passes through the point (9, 6), then L is given by

Let M be a 3 $$\times$$ 3 matrix satisfying $$M\left[ {\matrix{ 0 \cr 1 \cr 0 \cr } } \right] = \left[ {\matrix{ { - 1} \cr 2 \cr 3 \cr } } \right]$$, $$M\left[ {\matrix{ 1 \cr { - 1} \cr 0 \cr } } \right] = \left[ {\matrix{ 1 \cr 1 \cr { - 1} \cr } } \right]$$ and $$M\left[ {\matrix{ 1 \cr 1 \cr 1 \cr } } \right] = \left[ {\matrix{ 0 \cr 0 \cr {12} \cr } } \right]$$. Then the sum of the diagonal entries of M is ___________.

Match the statements given in Column I with the intervals/union of intervals given in Column II :

A ball of mass 0.2 kg rests on a vertical post of height 5 m. A bullet of mass 0.01 kg, traveling with a velocity V m/s in a horizontal direction, hits the center of the ball. After the collision, the ball and bullet travel independently. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post. The velocity V of the bullet is

A block of mass 0.18 kg is attached to a spring of force-constant 2 N/m. The coefficient of friction between the block and the floor is 0.1. Initially the block is at rest and the spring is un-stretched. An impulse is given to the block as shown in the figure. The block slides a distance of 0.06 m and comes to rest for the first time. The initial velocity of the block in m/s is V = N/10. Then N is

A light ray travelling in glass medium is incident on glass-air interface at an angle of incidence $$\theta$$. The reflected (R) and transmitted (T) intensities, both as function of $$\theta$$, are plotted. The correct sketch is

A long insulated copper wire is closely wound as a spiral of N turns. The spiral has inner radius a and outer radius b. The spiral lies in the xy-plane and a steady current I flows through the wire. The z-component of the magnetic field at the centre of the spiral is

Two solid spheres A and B of equal volumes but of different densities d_A and d_B are connected by a string. They are fully immersed in a fluid of density d_F. They get arranged into an equilibrium state as shown in the figure with a tension in the string. The arrangement is possible only if

A thin ring of mass 2 kg and radius 0.5 m is rolling without on a horizontal plane with velocity 1 m/s. A small ball of mass 0.1 kg, moving with velocity 20 m/s in the opposite direction hits the ring at a height of 0.75 m and goes vertically up with velocity 10 m/s. Immediately after the collision,

A series RC-current is connected to AC voltage source. Consider two cases : (A) When C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. The current I_R through the resistor and voltage V_C across the capacitor are compared in the two cases. Which of the following is/are true?

A series RC combination is connected to an AC voltage of angular frequency $$\omega$$ = 500 rad/s. If the impedance of the RC circuit is R$$\sqrt{1.25}$$, the time constant (in millisecond) of the circuit is __________.

A silver sphere of radius 1 cm and work function 4.7 eV is suspended from an insulating thread in free-space. It is under continuous illumination of 200 nm wavelength light. As photoelectrons are emitted, the sphere gets charged and acquires a potential. The maximum number of photoelectrons emitted from the spheres is A $$\times$$ 10^Z (where 1 < A < 10). The value of Z is _____________.

Two batteries of different emfs and different internal resistance are connected as shown. The voltage across AB in volts is __________.

Water (with refractive index = 4/3) in a tank is 18 cm deep. Oil of refractive index 7/4 lies on water making a convex surface of radius of curvature R = 6 cm as shown. Consider oil to act a thin lens. An object S is placed 24 cm above water surface. The location of its image is at x cm above the bottom of the tank. Then x is __________.

One mole of a monatomic gas is taken through a cycle ABCDA as shown in the PV diagram. Column II give the characteristics involved in the cycle. Match them with each of the processes given in Column I.

Column I shows four systems, each of the same length L, for producing standing waves. The lowest possible natural frequency of a system is called its fundamental frequency, whose wavelength is denoted as $$\lambda$$_f. Match each system with statements given in Column II describing the nature and wavelength of the standing waves :