The term that corrects for the attractive forces present in a real gas in the van der Waals equation is

Among the electrolytes Na$$_2$$SO$$_4$$, CaCl$$_2$$, Al$$_2$$(SO$$_4$$)$$_3$$ and NH$$_4$$Cl, the most effective coagulating agent for Sb$$_2$$S$$_3$$ sol is

The Henry's law constant for the solubility of N$$_2$$ gas in water at 298 K is 1.0 $$\times$$ 10$$^5$$ atm. The mole fraction of N$$_2$$ in air is 0.8. The number of moles of N$$_2$$ from air dissolved in 10 moles of water at 298 K and 5 atm pressure is

The reaction of P$$_4$$ with X leads selectively to P$$_4$$O$$_6$$. The X is

The correct acidity order of the following is

Among cellulose, poly(vinyl chloride), nylon and natural rubber, the polymer in which the intermolecular force of attraction is weakest is

The IUPAC name of the following compound is

The correct statement(s) regarding defects in solids is (are)

The compound(s) that exhibit(s) geometrical isomerism is(are)

The correct statement(s) about the compound $$\mathrm{H_3C(HO)HC-CH=CH-CH(OH)CH_3~~(X)}$$ is (are)

The compound X is

The compound Y is

The compound Z is

The structure of the carbonyl compound P is

The structures of the products Q and R, respectively, are

The structure of the product S is

Match each of the diatomic molecules in Column I with its property/properties in Column II:

Match each of the compounds in Column I with its characteristic reaction(s) in Column II.

Let $$z = x + iy$$ be a complex number where x and y are integers. Then the area of the rectangle whose vertices are the roots of the equation $$\overline z {z^3} + z{\overline z ^3} = 350$$ is

Then the value of $$\mu $$ for which the vector $${\overrightarrow {PQ} }$$ is parallel to the plane $$x - 4y + 3z = 1$$ is :

If $$\overrightarrow a ,\overrightarrow b ,\overrightarrow c $$ and $$\overrightarrow d $$ are unit vectors such that $$(\overrightarrow a \times \overrightarrow b )\,.\,(\overrightarrow c \times \overrightarrow d ) = 1$$ and $$\overrightarrow a \,.\,\overrightarrow c = {1 \over 2}$$, then

The conditional probability that $$X\ge6$$ given $$X>3$$ equals :

The probability that $$X\ge3$$ equals :

Let $$f$$ be a non-negative function defined on the interval $$[0,1]$$.

If $$\int\limits_0^x {\sqrt {1 - {{(f'(t))}^2}dt} = \int\limits_0^x {f(t)dt,0 \le x \le 1} } $$, and $$f(0) = 0$$, then

Match the conics in Column I with the statements/expressions in Column II :

If $$a, b$$ and $$c$$ denote the lengths of the sides of the triangle opposite to the angles $$A, B$$ and $$C$$, respectively, then

Match the statements/expressions in Column I with the open intervals in Column II :

Let $$L = \mathop {\lim }\limits_{x \to 0} {{a - \sqrt {{a^2} - {x^2}} - {{{x^2}} \over 4}} \over {{x^4}}},a > 0$$. If L is finite, then

The number of matrices in A is

The number of matrices A in A for which the system of linear equations $$A\left[ {\matrix{ x \cr y \cr z \cr } } \right] = \left[ {\matrix{ 1 \cr 0 \cr 0 \cr } } \right]$$ has a unique solution, is

The number of matrices A in A for which the system of linear equations $$A\left[ {\matrix{ x \cr y \cr z \cr } } \right] = \left[ {\matrix{ 1 \cr 0 \cr 0 \cr } } \right]$$ is inconsistent, is

Look at the drawing given in the figure below which has been drawn with ink of uniform line-thickness. The mass of ink used to draw each of the two inner circles, and each of the two line segments is $$m$$. the mass of the ink used to draw the outer circle is $$6m$$. The coordinates of the centres of the different parts are: outer circle (0, 0), left inner circle ($$-a,a$$), right inner circle ($$a,a$$), vertical line (0, 0) and horizontal line ($$0,-a$$). The y-coordinate of the centre of mass of the ink in this drawing is

The figure shows certain wire segments joined together to form a coplanar loop. The loop is placed in a perpendicular magnetic field in the direction going into the plane of the figure. The magnitude of the field increases with time. $$I_1$$ and $$I_2$$ are the currents in the segments ab and cd. Then,

Two small particles of equal masses start moving in opposite directions from a point A in a horizontal circular orbit. Their tangential velocities are $$v$$ and 2$$v$$, respectively, as shown in the figure. Between collisions, the particles move with constant speeds. After making how many elastic collisions, other than that at A, these two particles will again reach the point A?

A disk of radius $${a \over 4}$$ having a uniformly distributed charge 6C is placed in the xy-plane with its centre at ($$-$$a/2, 0, 0). A rod of length a carrying a uniformly distributed charge 8C is placed on the x-axis from x = a/4 to x = 5a/4. Two points charges $$-$$7C and 3C are placed at (a/4, $$-$$a/4, 0) and ($$-$$3a/4, 3a/4, 0), respectively. Consider a cubical surface formed by six surfaces $$x=\pm a/2,y=\pm a/2,z=\pm a/2$$. The electric flux through this cubical surface is

Three concentric metallic spherical shells of radii $$R,2R,3R$$ are given charges $$Q_1,Q_2,Q_3$$, respectively. It is found that the surface charge densities on the outer surfaces of the shells are equal. Then, the ratio of the charges given to the shells, $$Q_1:Q_2:Q_3$$, is

The $$x$$-$$t$$ graph of a particle undergoing simple harmonic motion is shown in the figure. The acceleration of the particle at $$t=4/3$$ s is

A ball is dropped from a height of 20 m above the surface of water in a lake. The refractive index of water is 4/3. A fish inside the lake, in the line of fall of the ball, is looking at the ball. At an instant, when the ball is 12.8 m above the water surface, the fish sees the speed of ball as (Take g = 10 m/s$$^2$$)

For the circuit shown in the figure

$$C_V$$ and $$C_P$$ denote the molar specific heat capacities of a gas at constant volume and constant pressure, respectively. Then

A student performed the experiment of determination of focal length of a concave mirror by $$u$$-$$v$$ method using an optical bench of length 1.5 m. The focal length of the mirror used is 24 cm. The maximum error in the location of the image can be 0.2 cm. The 5 sets of ($$u,v$$) values recorded by the student (in cm) are : (42, 56), (48, 48), (60, 40), (66, 33), (78, 39). The data set(s) that cannot come from experiment and is (are) incorrectly recorded, is (are)

If the resultant of all the external forces acting on a system of particles is zero, then from an inertial frame, one can surely say that

The allowed energy for the particle for a particular value of $$n$$ is proportional to

If the mass of the particle is $$m=1.0\times10^{-30}$$ kg and $$a=6.6$$ nm, the energy of the particle in its ground state is closest to

The speed of the particle, that can take discrete values, is proportional to

In the core of nuclear fusion reactor, the gas becomes plasma because of

Assume that two deuteron nuclei in the core of fusion reactor at temperature T are moving towards each other, each with kinetic energy 1.5 kT, when the separation between them is large enough to neglect Coulomb potential energy. Also neglect any interaction from other particles in the core. The minimum temperature T required for them to reach a separation of 4 $$\times$$ 10$$^{-15}$$ m is in the range

Results of calculations for four different designs of a fusion reactor using D-D reaction are given below. Which of these is most promising based on Lawson criterion?

Column II shows five systems in which two objects are labelled as X and Y. Also in each case a point P is shown. Column I gives some statements about X and/or Y. Match these statements to the appropriate system(s) from Column II:

	Column I		Column II
(A)	The force exerted by X on Y has a magnitude $$Mg$$.	(P)	Block Y of mass M left on a fixed inclined plane X, slides on it with a constant velocity.
(B)	The gravitational potential energy of X is continuously increasing.	(Q)	Two rings magnets Y and Z, each of mass M, are kept in frictionless vertical plastic stand so that they repel each other. Y rests on the base X and Z hangs in air in equilibrium. P is the topmost point of the stand on the common axis of the two rings. The whole system is in a lift that is going up with a constant velocity.
(C)	Mechanical energy of the system X + Y is continuously decreasing.	(R)	A pulley Y of mass $$m_0$$ is fixed to a table through a clamp X. A block of mass M hangs from a string that goes over the pulley and is fixed at point P of the table. The whole system is kept in a lift that is going down with a constant velocity.
(D)	The torque of the weight of Y about point is zero.	(S)	A sphere Y of mass M is put in a non-viscous liquid X kept in a container at rest. The sphere is released and it moves down in the liquid.
		(T)	A sphere Y of mass M is falling with its terminal velocity in a viscous liquid X kept in a container.

Six point charges, each of the same magnitude q, are arranged in different manners as shown in Column II. In each case, a point M and a line PQ passing through M are shown. Let E be the electric field and V be the electric potential at M (potential at infinity is zero) due to the given charge distribution when it is at rest. Now, the whole system is set into rotation with a constant angular velocity about the line PQ. Let B be the magnetic field at M and $$\mu$$ be the magnetic moment of the system in this condition. Assume each rotating charge to be equivalent to a steady current.

	Column I		Column II
(A)	$$E=0$$	(P)	Charge are at the corners of a regular hexagon. M is at the centre of the hexagon. PQ is perpendicular to the plane of the hexagon.
(B)	$$V\ne 0$$	(Q)	Charges are on a line perpendicular to PQ at equal intervals. M is the midpoint between the two innermost charges.
(C)	$$B=0$$	(R)	Charges are placed on two coplanar insulating rings at equal intervals. M is the common centre of the rings. PQ is perpendicular to the plane of the rings.
(D)	$$\mu \ne 0$$	(S)	Charges are placed at the corners of a rectangle of sides a and 2a and at the mid points of the longer sides. M is at the centre of the rectangle. PQ is parallel to the longer sides.
		(T)	Charges are placed on two coplanar, identical insulating rings are equal intervals. M is the midpoint between the centres of the rings. PQ is perpendicular to the line joining the centres and coplanar to the rings.