IIT-JEE 2012 Paper 2 Offline
Paper was held on Sun, Apr 8, 2012 2:00 AM
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Chemistry

1
In the cyanide extraction process of silver from argentite ore, the oxidising and reducing agents used are
2
The electrochemical cell shown below is a concentration cell. M | M2+ (saturated solution of a sparingly soluble salt, MX2) || M2+ (0.001 mol dm–3) | M The emf of the cell depends on the difference in concentrations of M2+ ions at the two electrodes. The emf of the cell at 298 K is 0.059 V.

The value of ∆G (kJ mol–1) for the given cell is (take 1F = 96500 C mol–1)
3
The electrochemical cell shown below is a concentration cell. M | M2+ (saturated solution of a sparingly soluble salt, MX2) || M2+ (0.001 mol dm–3) | M The emf of the cell depends on the difference in concentrations of M2+ ions at the two electrodes. The emf of the cell at 298 K is 0.059 V.

The solubility product (Ksp; mol3 dm–9) of MX2 at 298 K based on the information available for the given concentration cell is (take 2.303 $$\times$$ R $$\times$$ 298/F = 0.059 V)
4
For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water. the elevation in boiling point at 1 atm pressure is 2oC. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take Kb = 0.76 K Kg mol-1)
5

The major product H of the given reaction sequence is

$$C{H_3} - C{H_2} - CO - C{H_3}\buildrel {\overline C N} \over \longrightarrow G\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Heat}^{95\% \,{H_2}S{O_4}}} H$$

6

$$NiC{l_2}{\{ P{({C_2}{H_5})_2}({C_6}{H_5})\} _2}$$ exhibits temperature-dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are, respectively,

7

The reaction of white phosphorous with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type; the oxidation states of phosphorus in phosphine and the other product are, respectively,

8

The shape of XeO2F2 molecule is

9

The compound that undergoes decarboxylation most readily under mild condition is

10

Using the data provided, calculate the multiple bond energy (kJ mol$$-$$1) of a C=C bond in C2H2. That energy is (take the bond energy of C-H bond as 350 kJ mol$$-$$1).

$$\matrix{ \hfill {2C(s) + {H_2}(g) \to {C_2}{H_2}} & \hfill {\Delta H = 225\,kJ\,mo{l^{ - 1}}} \cr \hfill {2C(s) \to 2C(g)} & \hfill {\Delta H = 1410\,kJ\,mo{l^{ - 1}}} \cr \hfill {{H_2}(g) \to 2H(g)} & \hfill {\Delta H = 330\,kJ\,mo{l^{ - 1}}} \cr } $$

11
The compound I is
12

The compound K is

13

Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of that oxoacid is

14

25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used to reach the end point. The molarity of the household bleach solution is

15

The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following statement(s) is(are) correct?

IIT-JEE 2012 Paper 2 Offline Chemistry - Thermodynamics Question 12 English

16

For the given aqueous reactions, which of the statement(s) is(are) true?

IIT-JEE 2012 Paper 2 Offline Chemistry - d and f Block Elements Question 6 English

17

With reference to the scheme given, which of the given statement(s) about T, U, V and W is(are) correct?

IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 31 English

18

Which of the given statement(s) about N, O, P and Q with respect to M is(are) correct?

IIT-JEE 2012 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 17 English

19

With respect to graphite and diamond, which of the statement(s) given below is(are) correct?

20

The given graphs/data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions of temperature and pressure. Which of the following choice(s) about I, II, III and IV is(are) correct?

IIT-JEE 2012 Paper 2 Offline Chemistry - Surface Chemistry Question 6 English 1

IIT-JEE 2012 Paper 2 Offline Chemistry - Surface Chemistry Question 6 English 2

IIT-JEE 2012 Paper 2 Offline Chemistry - Surface Chemistry Question 6 English 3

IIT-JEE 2012 Paper 2 Offline Chemistry - Surface Chemistry Question 6 English 4

Mathematics

1
Let $${{a_n}}$$ denote the number of all n-digit positive integers formed by the digits 0, 1 or both such that no consecutive digits in them are 0.Let $${{b_n}}$$ = the number of such n-digit integers ending with digit 1 and $${{c_n}}$$ =the number of such n-digit integers ending with digit 0.

The value of $${{b_6}}$$ is

2
If the straight lines $$\,{{x - 1} \over 2} = {{y + 1} \over k} = {z \over 2}$$ and $${{x + 1} \over 5} = {{y + 1} \over 2} = {z \over k}$$ are coplanar, then the plane (s) containing these two lines is (are)
3
If $$\overrightarrow a $$ and $$\overrightarrow b $$ are vectors such that $$\left| {\overrightarrow a + \overrightarrow b } \right| = \sqrt {29} $$ and $$\,\overrightarrow a \times \left( {2\widehat i + 3\widehat j + 4\widehat k} \right) = \left( {2\widehat i + 3\widehat j + 4\widehat k} \right) \times \widehat b,$$ then a possible value of $$\left( {\overrightarrow a + \overrightarrow b } \right).\left( { - 7\widehat i + 2\widehat j + 3\widehat k} \right)$$ is
4
The equation of a plane passing through the line of intersection of the planes $$x+2y+3z=2$$ and $$x-y+z=3$$ and at a distance $${2 \over {\sqrt 3 }}$$ from the point $$(3, 1, -1)$$ is
5
Let $$X$$ and $$Y$$ be two events such that $$P\left( {X|Y} \right) = {1 \over 2},$$ $$P\left( {Y|X} \right) = {1 \over 3}$$ and $$P\left( {X \cap Y} \right) = {1 \over 6}.$$ Which of the following is (are) correct ?
6
Four fair dice $${D_1,}$$ $${D_2,}$$ $${D_3}$$ and $${D_4}$$ ; each having six faces numbered $$1, 2, 3, 4, 5$$ and $$6$$ are rolled simultaneously. The probability that $${D_4}$$ shows a number appearing on one of $${D_1},$$ $${D_2}$$ and $${D_3}$$ is
7
The value of the integral $$\int\limits_{ - \pi /2}^{\pi /2} {\left( {{x^2} + 1n{{\pi + x} \over {\pi - x}}} \right)\cos xdx} $$ is
8
Let $$f\left( x \right) = {\left( {1 - x} \right)^2}\,\,{\sin ^2}\,\,x + {x^2}$$ for all $$x \in IR$$ and let
$$g\left( x \right) = \int\limits_1^x {\left( {{{2\left( {t - 1} \right)} \over {t + 1}} - In\,t} \right)f\left( t \right)dt} $$ for all $$x \in \left( {1,\,\infty } \right)$$.

Consider the statements:
$$P:$$ There exists some $$x \in R$$ such that $$f\left( x \right) + 2x = 2\left( {1 + {x^2}} \right)$$
$$Q:\,\,$$ There exists some $$x \in R$$ such that $$2\,f\left( x \right) + 1 = 2x\left( {1 + x} \right)$$
Then

9
Let $$f\left( x \right) = {\left( {1 - x} \right)^2}\,\,{\sin ^2}\,\,x + {x^2}$$ for all $$x \in IR$$ and let
$$g\left( x \right) = \int\limits_1^x {\left( {{{2\left( {t - 1} \right)} \over {t + 1}} - In\,t} \right)f\left( t \right)dt} $$ for all $$x \in \left( {1,\,\infty } \right)$$.

Which of the following is true?

10
If $$f\left( x \right) = \int_0^x {{e^{{t^2}}}} \left( {t - 2} \right)\left( {t - 3} \right)dt$$ for all $$x \in \left( {0,\infty } \right),$$ then
11
Let $$PQR$$ be a triangle of area $$\Delta $$ with $$a=2$$, $$b = {7 \over 2}$$ and $$c = {5 \over 2}$$; where $$a, b,$$ and $$c$$ are the lengths of the sides of the triangle opposite to the angles at $$P.Q$$ and $$R$$ respectively. Then $${{2\sin P - \sin 2P} \over {2\sin P + \sin 2P}}$$ equals.
12
A tangent PT is drawn to the circle $${x^2}\, + {y^2} = 4$$ at the point P $$\left( {\sqrt 3 ,1} \right)$$. A straight line L, perpendicular to PT is a tangent to the circle $${(x - 3)^2}$$ + $${y^2}$$ = 1

A common tangent of the two circles is

13
A tangent PT is drawn to the circle $${x^2}\, + {y^2} = 4$$ at the point P $$\left( {\sqrt 3 ,1} \right)$$. A straight line L, perpendicular to PT is a tangent to the circle $${(x - 3)^2}$$ + $${y^2}$$ = 1.

A possible equation of L is

14
Let $${a_1},{a_2},{a_3},.....$$ be in harmonic progression with $${a_1} = 5$$ and $${a_{20}} = 25.$$ The least positive integer $$n$$ for which $${a_n} < 0$$ is
15
Let $${{a_n}}$$ denote the number of all n-digit positive integers formed by the digits 0, 1 or both such that no consecutive digits in them are 0.Let $${{b_n}}$$ = the number of such n-digit integers ending with digit 1 and $${{c_n}}$$ =the number of such n-digit integers ending with digit 0.

Which of the following is correct?

16

If P is a 3 $$\times$$ 3 matrix such that PT = 2P + I, where PT is the transpose of P and I is the 3 $$\times$$ 3 identity matrix, then there exists a column matrix $$X = \left[ {\matrix{ x \cr y \cr z \cr } } \right] \ne \left[ {\matrix{ 0 \cr 0 \cr 0 \cr } } \right]$$ such that

17

Let $$\alpha$$(a) and $$\beta$$(a) be the roots of the equation $$(\root 3 \of {1 + a} - 1){x^2} + (\sqrt {1 + a} - 1)x + (\root 6 \of {1 + a} - 1) = 0$$ where $$a > - 1$$. Then $$\mathop {\lim }\limits_{a \to {0^ + }} \alpha (a)$$ and $$\mathop {\lim }\limits_{a \to {0^ + }} \beta (a)$$ are

18

For every integer n, let an and bn be real numbers. Let function f : R $$\to$$ R be given by

$$f(x) = \left\{ {\matrix{ {{a_n} + \sin \pi x,} & {for\,x \in [2n,2n + 1]} \cr {{b_n} + \cos \pi x,} & {for\,x \in (2n - 1,2n)} \cr } } \right.$$, for all integers n. If f is continuous, then which of the following hold(s) for all n ?

19

If the ad joint of a 3 $$\times$$ 3 matrix P is $$\left[ {\matrix{ 1 & 4 & 4 \cr 2 & 1 & 7 \cr 1 & 1 & 3 \cr } } \right]$$, then the possible value(s) of the determinant of P is(are)

20

Let $$f:( - 1,1) \to R$$ be such that $$f(\cos 4\theta ) = {2 \over {2 - {{\sec }^2}\theta }}$$ for $$\theta \in \left( {0,{\pi \over 4}} \right) \cup \left( {{\pi \over 4},{\pi \over 2}} \right)$$. Then the value(s) of $$f\left( {{1 \over 3}} \right)$$ is(are)

Physics

1
Two identical discs of same radius R are rotating about their axes in opposite directions with the same constant angular speed $$\omega $$. The discs are in the same horizontal plane. At time t = 0, the points P and Q are facing each other as shown in the figure. The relative speed between the two points P and Q is vr. In one time period (T) of rotation of the discs, vr as a function of time is best represented by
IIT-JEE 2012 Paper 2 Offline Physics - Rotational Motion Question 58 English
2
Six point charges are kept at the vertices of a regular hexagon of side $$L$$ and center $$O,$$ as shown in the figure. Given that $$K = {1 \over {4\pi {\varepsilon _0}}}{q \over {{L^2}}},$$ which of the following statement(s) is (are) correct ?
IIT-JEE 2012 Paper 2 Offline Physics - Electrostatics Question 46 English
3
In the given circuit, a charge of $$+80$$ $$\mu C$$ is given to the upper plate of the $$4$$ $$\mu F$$ capacitor. Then in the steady state, the charge on the upper plate of the $$3$$ $$\mu F$$ capacitor is
IIT-JEE 2012 Paper 2 Offline Physics - Capacitor Question 16 English
4
A student is performing the experiment of resonance Column. The diameter of the column tube is 4 cm. The frequency of the tuning fork is 512 Hz. The air temperature is 38oC in which the speed of sound is 336 m/s. The zero of the meter scale coincides with the top end of the Resonance Column tube. When the first resonance occurs, the reading of the water level in the column is
5
Two moles of ideal helium gas are in a rubber balloon at 30oC. The balloon is fully expandable and can be assumed to require no energy in its expansion. The temperature of the gas in the balloon is slowly changed to 35oC. The amount of heat required in raising the temperature is nearly (take R = 8.31 J/mol.K)
6
A thin uniform cylindrical shell, closed at both ends, is partially filled with water. It is floating vertically in water in half-submerged state. If $${\rho _c}$$ is the relative density of the material of the shell with respect to water, then the correct statement is that the shell is
7
Two spherical planets P and Q have the same uniform density r, masses MP and MQ and surface areas A and 4A respectively. A spherical planet R also has uniform density r and its mass is (MP + MQ). The escape velocities from the planets P, Q and R are VP, VQ and VR, respectively. Then
8
The figure shows a system consisting of (i) a ring of outer radius 3R rolling clockwise without slipping on a horizontal surface with angular speed $$\omega $$ and (ii) an inner disc of radius 2R rotating anti-clockwise with angular speed $${\omega \over 2}$$. The ring and disc are separated by frictionless ball bearings. The point P on the inner disc is at a distance R from the origin, where OP makes an angle of $$30^\circ $$ with the horizontal. Then with respect to the horizontal surface,
IIT-JEE 2012 Paper 2 Offline Physics - Rotational Motion Question 54 English
9
Two solid cylinders P and Q of same mass and same radius start rolling down a fixed inclined plane from the same height at the same time. Cylinder P has most of its mass concentrated near its surface, while Q has most of its mass concentrated near the axis. Which statement(s) is(are) correct?
10
Consider a disc rotating in the horizontal plane with a constant angular speed $$\omega $$ about its centre O. The disc has a shaded region on one side of the diameter and an unshaded region on the other side as shown in the figure. When the disc is in the orientation as shown, two pebbles P and Q are simultaneously projected at an angle towards R. The velocity of projection is in the y - z plane and is same for both pebbles with respect to the disc. Assume that (i) they land back on the disc before the disc has completed $${1 \over 8}$$ rotation, (ii) their range is less than half the disc radius, and (iii) $$\omega $$ remains constant throughout. Then

IIT-JEE 2012 Paper 2 Offline Physics - Rotational Motion Question 57 English
11

A loop carrying current $$l$$ lies in the xy-plane as shown in the figure. The unit vector $$\widehat k$$ is coming out of the plane of the paper. The magnetic moment of the current loop is

IIT-JEE 2012 Paper 2 Offline Physics - Magnetism Question 19 English

12

An infinite long hollow conducting cylinder with inner radius R/2 and outer radius R carries a uniform current density along its length. The magnitude of the magnetic field, $$\left| {\overrightarrow B } \right|$$ as a function of the radial distance r from the axis is best represented by

13

Which of the following statements about the instantaneous axis (passing through the centre of mass) is correct?

14

Which of the following statements regarding the angular speed about the instantaneous axis (passing through the centre of mass) is correct?

15

What is the maximum energy of the anti-neutrino?

16

If the anti-neutrino had a mass of 3 eV/c2 (where c is the speed of light) instead of zero mass, what should be the range of the kinetic energy, K, of the electron?

17

For light incident from air on a meta-material, the appropriate ray diagram is

18

Choose the correct statement.

19

In the given circuit, the AC source has $$\omega$$ = 100 rad/s. Considering the inductor and capacitor to be ideal, the correct choice(s) is(are)

IIT-JEE 2012 Paper 2 Offline Physics - Alternating Current Question 8 English

20

A current carrying infinitely long wire is kept along the diameter of a circular wire loop, without touching it, the correct statement(s) is(are)

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