A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is 400 K. Calculate the activation energy of the reaction if the catalyst lowers the activation barrier by 20 kJ mol^-1.

The following electrochemical cell has been set up.
Pt(1) | Fe³⁺, Fe²⁺ (a = 1) | Ce⁴⁺, Ce³⁺ (a=1) | Pt(2)
E^o (Fe³⁺, Fe²⁺) = 0.77 V; E^o (Ce⁴⁺, Ce³⁺) = 1.61 V
If an ammeter is connected between the two platinum electrodes, predict the direction of flow of current. Will the current increase or decrease with time?

Copper sulphate solution (250 mL) was electrolysed using platinum anode and a copper cathode. A constant current of 2mA was passed for 16 minutes. It was found that after electrolysis the absorbance of the solution was reduced to 50% of its original value. Calculate the concentration of copper sulphate in the solution to begin with.

To 500 cm³ of water, 3.0 $$\times$$ 10^-3 kg of acetic acid is added. If 23% of acetic acid is dissociated, what will be the depression in freezing point? Kf and density of water are 1.86 K kg^-1 mol^-1 and 0.997 g cm^-3, respectively

Write down the M.O. electron distribution of O₂. Specify its bond order and magnetic property.

Calculate the energy required to excite one litre of hydrogen gas at 1 atm and 298 K to the first excited state of atomic hydrogen. The energy for the dissociation of H-H bond 436 kJ mol^-1.

If $$\alpha ,\,\beta $$ are the roots of $$a{x^2} + bx + c = 0$$, $$\,\left( {a \ne 0} \right)$$ and $$\alpha + \delta ,\,\,\beta + \delta $$ are the roots of $$A{x^2} + Bx + c = 0,$$ $$\left( {A \ne 0\,} \right)\,$$ for some contant $$\delta $$, then prove that $${{{b^2} - 4ac} \over {{a^2}}} = {{{B^2} - 4Ac} \over {{A^2}}}$$.

A coin has probability $$p$$ of showing head when tossed. It is tossed $$n$$ times. Let $${p_n}$$ denote the probability that no two (or more) consecutive heads occur. Prove that $${p_1} = 1,{p_2} = 1 - {p^2}$$ and $${p_n} = \left( {1 - p} \right).\,\,{p_{n - 1}} + p\left( {1 - p} \right){p_{n - 2}}$$ for all $$n \ge 3.$$

For $$x>0,$$ let $$f\left( x \right) = \int\limits_e^x {{{\ln t} \over {1 + t}}dt.} $$ Find the function
$$f\left( x \right) + f\left( {{1 \over x}} \right)$$ and show that $$f\left( e \right) + f\left( {{1 \over e}} \right) = {1 \over 2}.$$
Here, $$\ln t = {\log _e}t$$.

Suppose $$p\left( x \right) = {a_0} + {a_1}x + {a_2}{x^2} + .......... + {a_n}{x^n}.$$ If
$$\left| {p\left( x \right)} \right| \le \left| {{e^{x - 1}} - 1} \right|$$ for all $$x \ge 0$$, prove that
$$\left| {{a_1} + 2{a_2} + ........ + n{a_n}} \right| \le 1$$.

Let $$ABC$$ be a triangle with incentre $$I$$ and inradius $$r$$. Let $$D,E,F$$ be the feet of the perpendiculars from $$I$$ to the sides $$BC$$, $$CA$$ and $$AB$$ respectively. If $${r_1},{r_2}$$ and $${r_3}$$ are the radii of circles inscribed in the quadrilaterals $$AFIE$$, $$BDIF$$ and $$CEID$$ respectively, prove that $$${{{r_1}} \over {r - {r_1}}} + {{{r_2}} \over {r - {r_2}}} + {{{r_3}} \over {r - {r_3}}} = {{{r_1}{r_2}{r_3}} \over {\left( {e - {r_1}} \right)\left( {r - {r_2}} \right)\left( {r - {r_3}} \right)}}$$$

If $${x^2} + {y^2} = 1$$ then

Let $${C_1}$$ and $${C_2}$$ be respectively, the parabolas $${x^2} = y - 1$$ and $${y^2} = x - 1$$. Let $$P$$ be any point on $${C_1}$$ and $$Q$$ be any point on $${C_2}$$. Let $${P_1}$$ and $${Q_1}$$ be the reflections of $$P$$ and $$Q$$, respectively, with respect to the line $$y=x$$. Prove that $${P_1}$$ lies on $${C_2}$$, $${Q_1}$$ lies on $${C_1}$$ and $$PQ \ge $$ min $$\left\{ {P{P_1},Q{Q_1}} \right\}$$. Hence or otherwise determine points $${P_0}$$ and $${Q_0}$$ on the parabolas $${C_1}$$ and $${C_2}$$ respectively such that $${P_0}{Q_0} \le PQ$$ for all pairs of points $$(P,Q)$$ with $$P$$ on $${C_1}$$ and $$Q$$ on $${C_2}$$.

Let $$ABC$$ be an equilateral triangle inscribed in the circle $${x^2} + {y^2} = {a^2}$$. Suppose perpendiculars from $$A, B, C$$ to the major axis of the ellipse $$x.{{{x^2}} \over {{a^2}}} + {{{y^2}} \over {{b^2}}} = 1$$, $$(a>b)$$ meets the ellipse respectively, at $$P, Q, R$$. so that $$P, Q, R$$ lie on the same side of the major axis as $$A, B, C$$ respectively. Prove that the normals to the ellipse drawn at the points $$P, Q$$ and $$R$$ are concurrent.

Let $$ABC$$ and $$PQR$$ be any two triangles in the same plane. Assume that the prependiculars from the points $$A, B, C$$ to the sides $$QR, RP, PQ$$ respectively are concurrent. Using vector methods or otherwise, prove that the prependiculars from $$P, Q, R $$ to $$BC,$$ $$CA$$, $$AB$$ respectively are also concurrent.

For points $$P\,\,\, = \left( {{x_1},\,{y_1}} \right)$$ and $$Q\,\,\, = \left( {{x_2},\,{y_2}} \right)$$ of the co-ordinate plane, a new distance $$d\left( {P,\,Q} \right)$$ is defined by $$d\left( {P,\,Q} \right)$$$$ = \left( {{x_2},\,{y_2}} \right)\left| {{x_1} - {x_2}} \right| + \left| {{y_1} - {y_2}} \right|.$$ Let $$O = (0, 0)$$ and $$A = (3, 2)$$. Prove that the set of points in the first quadrant which are equidistant (with respect to the new distance) from $$O$$ and $$A$$ consists of the union of a line segment of finite length and an infinite ray. Sketch this set in a labelled diagram.

The fourth power of the common difference of an arithmatic progression with integer entries is added to the product of any four consecutive terms of it. Prove that the resulting sum is the square of an integer.

A coin probability $$p$$ of showing head when tossed. It is tossed $$n$$ times. Let $${p_n}$$ denote the probability that no two (or more) consecutive heads occur. Prove that $${p_1} = 1,\,\,{p_2} = 1 - {p^2}$$ and $${p_n} = \left( {1 - p} \right).\,\,{p_{n - 1}} + p\left( {1 - p} \right){p_{n - 2}}$$ for all $$n \ge 3.$$

Prove by induction on, that $${p_n} = A{\alpha ^n} + B{\beta ^n}$$ for all $$n \ge 1,$$ where $$\alpha $$ and $$\beta $$ are the roots of quadratic equation $${x^2} - \left( {1 - p} \right)x - p\left( {1 - p} \right) = 0$$ and $$A = {{{p^2} + \beta - 1} \over {\alpha \beta - {\alpha ^2}}},B = {{{p^2} + \alpha - 1} \over {\alpha \beta - {\beta ^2}}}.$$

Let $$a,\,b,\,c$$ be possitive real numbers such that $${b^2} - 4ac > 0$$ and let $${\alpha _1} = c.$$ Prove by induction that $${\alpha _{n + 1}} = {{a\alpha _n^2} \over {\left( {{b^2} - 2a\left( {{\alpha _1} + {\alpha _2} + ... + {\alpha _n}} \right)} \right)}}$$ is well-defined and
$${\alpha _{n + 1}} < {{{\alpha _n}} \over 2}$$ for all $$n = 1,2,....$$ (Here, 'well-defined' means that the denominator in the expression for $${\alpha _{n + 1}}$$ is not zero.)

For every possitive integer $$n$$, prove that
$$\sqrt {\left( {4n + 1} \right)} < \sqrt n + \sqrt {n + 1} < \sqrt {4n + 2}.$$
Hence or otherwise, prove that $$\left[ {\sqrt n + \sqrt {\left( {n + 1} \right)} } \right] = \left[ {\sqrt {4n + 1} \,\,} \right],$$
where $$\left[ x \right]$$ denotes the gratest integer not exceeding $$x$$.

For any positive integer $$m$$, $$n$$ (with $$n \ge m$$), let $$\left( {\matrix{ n \cr m \cr } } \right) = {}^n{C_m}$$
Prove that $$\left( {\matrix{ n \cr m \cr } } \right) + \left( {\matrix{ {n - 1} \cr m \cr } } \right) + \left( {\matrix{ {n - 2} \cr m \cr } } \right) + ........ + \left( {\matrix{ m \cr m \cr } } \right) = \left( {\matrix{ {n + 1} \cr {m + 2} \cr } } \right)$$

Hence or otherwise, prove that $$\left( {\matrix{ n \cr m \cr } } \right) + 2\left( {\matrix{ {n - 1} \cr m \cr } } \right) + 3\left( {\matrix{ {n - 2} \cr m \cr } } \right) + ........ + \left( {n - m + 1} \right)\left( {\matrix{ m \cr m \cr } } \right) = \left( {\matrix{ {n + 2} \cr {m + 2} \cr } } \right).$$.

In any triangle $$ABC,$$ prove that $$$\cot {A \over 2} + \cot {B \over 2} + \cot {C \over 2} = \cot {A \over 2}\cot {B \over 2}\cot {C \over 2}.$$$

A thin wire of length $L$ and uniform linear mass density $\rho$ is bent into a circular loop with centre at $O$ as shown. The moment of inertia of the loop about the axis $XX'$ is: