Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

	Column 1		Column 2		Column 3
(I)	Toluene	(i)	NaOH/Br2	(P)	Condensation
(II)	Acetophenone	(ii)	Br2/hv	(Q)	Carboxylation
(III)	Benzaldehyde	(iii)	(CH3CO)2O/ CH3COOK	(R)	Substitution
(IV)	Phenol	(iv)	NaOH/CO2	(S)	Haloform

For the synthesis of benzoic acid, the only CORRECT combination is

The wave function, $${\psi _{n,1,{m_1}}}$$ is a mathematical function whose value depends upon spherical polar coordinates $$\left( {r,\theta ,\phi } \right)$$ of the electron and characterized by the quantum numbers $$n,1$$ and $${m_1}$$. Here $$r$$ is distance from nucleus, $$\theta $$ is colatitude and $$\phi $$ is azimuth. In the mathematical functions given in the table, $$Z$$ is atomic number and $${a_0}$$ is Bohr radius.

For the given orbital in Column 1, the only CORRECT combination for any hydrogen-like species is :

An ideal gas is expanded from $$\left( {{p_1},{V_1},{T_1}} \right)$$ to $$\left( {{p_2},{V_2},{T_2}} \right)$$ under different conditions. The correct statement(s) among the following is (are)

The sum of the number of lone pairs of electrons on each central atom in the following species is

$${[TeB{r_6}]^{2 - }},{\left[ {Br{F_2}} \right]^ + },SNF_3,$$ and $${\left[ {Xe{F_3}} \right]^ - }$$

(Atomic numbers: $$N = 7,F = 9,$$ $$S = 16,Br = 35,$$ $$Te = 52,Xe = 54$$)