JEE Advanced 2015 Paper 2 Offline
Paper was held on
Sun, May 24, 2015 2:00 AM
Chemistry
1
In dilute aqueous H2SO4, the complex diaquodioxalatoferrate(II) is oxidized by $$MnO_4^-$$. For this reaction,
the ratio of the rate of change of [H+] to the rate of change of $$[MnO_4^-]$$ is
2
A closed vessel with rigid walls contains 1 mol of $${}_{92}^{238}U$$ and 1 mol of air at 298 K. Considering complete decay of $${}_{92}^{238}U$$ to $${}_{82}^{206}Pb$$, the ratio of the final pressure to the initial pressure of the system at 298 K is
3
The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar conductivity of a solution of a weak acid HY (0.10 M). If $$\lambda _{{x^ - }}^0 \approx \lambda _{{y^ - }}^0$$ the difference in their pKa values,
pKa(HX) - pKa(HY), is (consider degree of ionization of both acids to be << 1)
4
When O2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O2. The true statement(s) regarding this adsorption is(are)
5
Paragraph
When 100 mL of 1.0 M KCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
The pH of the solution after Expt. 2 is
When 100 mL of 1.0 M KCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
The pH of the solution after Expt. 2 is
6
Paragraph
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
Enthalpy of dissociation (in kJ/mol) of acetic acid obtained from the Expt. 2 is
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
Enthalpy of dissociation (in kJ/mol) of acetic acid obtained from the Expt. 2 is
7
The number of hydroxyl group(s) in Q is ___________.
8
Among the following the number of reactions that produces benzaldehyde is _________.
9
In the complex acetylbromidodicarbonylbis(triethylphosphine) iron(II), the number of Fe-C bond(s) is ___________.
10
Among the complex ions, [Co(NH2-CH2-CH2-NH2)2Cl2]+, [CrCl2(C2O4)2]3$$-$$, [Fe(H2O)4)OH)2]+, [Fe(NH3)2(CN)4]$$-$$, [Co(NH2-CH2-CH2-NH2)2(NH3)Cl]2+ and [Co(NH3)4(H2O)Cl]2+, the number of complex ions that shows cis-trans isomerism is ______________.
11
Three moles of B2H6 are completely reacted with methanol. The number of moles of boron containing product formed is ____________.
12
In the following reactions, the product S is
13
The major product U in the following reactions is
14
In the following reactions, the major product W is
15
The correct statements regarding (i) HClO, (ii) HClO2, (iii) HClO3 and (iv) HClO4 is (are)
16
The pairs of ions where BOTH the ions are precipitated upon passing H2S gas in presence of dilute HCl, is(are)
17
Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination, respectively, are
18
One mole of a monoatomic real gas satisfies the equation p(V $$-$$ b) = RT where b is a constant. The relationship of interatomic potential V(r) and interatomic distance r for the gas is given by
19
In the following reactions
Compound X is
20
In the following reactions
The major compound Y is
Mathematics
1
Let $$S$$ be the set of all non-zero real numbers $$\alpha $$ such that the quadratic equation $$\alpha {x^2} - x + \alpha = 0$$ has two distinct real roots $${x_1}$$ and $${x_2}$$ satisfying the inequality $$\left| {{x_1} - {x_2}} \right| < 1.$$ Which of the following intervals is (are) $$a$$ subset(s) os $$S$$?
2
For any integer k, let $${a_k} = \cos \left( {{{k\pi } \over 7}} \right) + i\,\,\sin \left( {{{k\pi } \over 7}} \right)$$, where $$i = \sqrt { - 1} \,$$. The value of the expression $${{\sum\limits_{k = 1}^{12} {\left| {{\alpha _{k + 1}} - {a_k}} \right|} } \over {\sum\limits_{k = 1}^3 {\left| {{\alpha _{4k - 1}} - {\alpha _{4k - 2}}} \right|} }}$$ is
3
Suppose that $$\overrightarrow p ,\overrightarrow q $$ and $$\overrightarrow r $$ are three non-coplanar vectors in $${R^3}$$. Let the components of a vector $$\overrightarrow s $$ along $$\overrightarrow p ,$$ $$\overrightarrow q $$ and $$\overrightarrow r $$ be $$4, 3$$ and $$5,$$ respectively. If the components of this vector $$\overrightarrow s $$ along $$\left( { - \overrightarrow p + \overrightarrow q + \overrightarrow r } \right),\left( {\overrightarrow p - \overrightarrow q + \overrightarrow r } \right)$$ and $$\left( { - \overrightarrow p - \overrightarrow q + \overrightarrow r } \right)$$ are $$x, y$$ and $$z,$$ respectively, then the value of $$2x+y+z$$ is
4
Let $${n_1}$$ and $${n_2}$$ be the number of red and black balls, respectively, in box $${\rm I}$$. Let $${n_3}$$ and $${n_4}$$ be the number of red and black balls, respectively, in box $${\rm I}{\rm I}.$$
One of the two boxes, box $${\rm I}$$ and box $${\rm I}{\rm I},$$ was selected at random and a ball was drawn randomly out of this box. The ball was found to be red. If the probability that this red ball was drawn from box $${\rm I}{\rm I}$$ is $${1 \over 3},$$ then the correct option(s) with the possible values of $${n_1}$$ $${n_2},$$ $${n_3}$$ and $${n_4}$$ is (are)
5
Let $${n_1}$$ and $${n_2}$$ be the number of red and black balls, respectively, in box $${\rm I}$$. Let $${n_3}$$ and $${n_4}$$ be the number of red and black balls, respectively, in box $${\rm I}{\rm I}.$$
A ball is drawn at random from box $${\rm I}$$ and transferred to box $${\rm I}$$$${\rm I}.$$ If the probability of drawing a red ball from box $${\rm I},$$ after this transfer, is $${1 \over 3},$$ then the correct option(s) with the possible values of $${n_1}$$ and $${n_2}$$ is(are)
6
Let $$f:R \to R$$ be a continuous odd function, which vanishes exactly at one point and $$f\left( 1 \right) = {1 \over {2.}}$$ Suppose that $$F\left( x \right) = \int\limits_{ - 1}^x {f\left( t \right)dt} $$ for all $$x \in \,\,\left[ { - 1,2} \right]$$ and $$G(x)=$$ $$\int\limits_{ - 1}^x {t\left| {f\left( {f\left( t \right)} \right)} \right|} dt$$ for all $$x \in \,\,\left[ { - 1,2} \right].$$ If $$\mathop {\lim }\limits_{x \to 1} {{F\left( x \right)} \over {G\left( x \right)}} = {1 \over {14}},$$ then the value of $$f\left( {{1 \over 2}} \right)$$ is
7
Suppose that all the terms of an arithmetic progression (A.P) are natural numbers. If the ratio of the sum of the first seven terms to the sum of the first eleven terms is 6 : 11 and the seventh term lies in between 130 and 140, then the common difference of this A.P. is
8
The coefficient of $${x^9}$$ in the expansion of (1 + x) (1 + $${x^2)}$$ (1 + $${x^3}$$) ....$$(1 + {x^{100}})$$ is
9
Let $${E_1}$$ and $${E_2}$$ be two ellipses whose centres are at the origin. The major axes of $${E_1}$$ and $${E_2}$$ lie along the $$x$$-axis and the $$y$$-axis, respectively. Let $$S$$ be the circle $${x^2} + {\left( {y - 1} \right)^2} = 2$$. The straight line $$x+y=3$$ touches the curves $$S$$, $${E_1}$$ and $${E_2}$$ at $$P, Q$$ and $$R$$ respectively. Suppose that $$PQ = PR = {{2\sqrt 2 } \over 3}$$. If $${e_1}$$ and $${e_2}$$ are the eccentricities of $${E_1}$$ and $${E_2}$$, respectively, then the correct expression(s) is (are)
10
Consider the hyperbola $$H:{x^2} - {y^2} = 1$$ and a circle $$S$$ with center $$N\left( {{x_2},0} \right)$$. Suppose that $$H$$ and $$S$$ touch each other at a point $$P\left( {{x_1},{y_1}} \right)$$ with $${{x_1} > 1}$$ and $${{y_1} > 0}$$. The common tangent to $$H$$ and $$S$$ at $$P$$ intersects the $$x$$-axis at point $$M$$. If $$(l, m)$$ is the centroid of the triangle $$PMN$$, then the correct expressions(s) is(are)
11
Suppose that the foci of the ellipse $${{{x^2}} \over 9} + {{{y^2}} \over 5} = 1$$ are $$\left( {{f_1},0} \right)$$ and $$\left( {{f_2},0} \right)$$ where $${{f_1} > 0}$$ and $${{f_2} < 0}$$. Let $${P_1}$$ and $${P_2}$$ be two parabolas with a common vertex at $$(0,0)$$ and with foci at $$\left( {{f_1},0} \right)$$ and $$\left( 2{{f_2},0} \right)$$, respectively. Let $${T_1}$$ be a tangent to $${P_1}$$ which passes through $$\left( 2{{f_2},0} \right)$$ and $${T_2}$$ be a tangent to $${P_2}$$ which passes through $$\left( {{f_1},0} \right)$$. If $${m_1}$$ is the slope of $${T_1}$$ and $${m_2}$$ is the slope of $${T_2}$$, then the value of $$\left( {{1 \over {m_1^2}} + m_2^2} \right)$$ is
12
If $$\alpha $$ $$ = 3{\sin ^{ - 1}}\left( {{6 \over {11}}} \right)$$ and $$\beta = 3{\cos ^{ - 1}}\left( {{4 \over 9}} \right),$$ where the inverse trigonimetric functions take only the principal values, then the correct options(s) is (are)
13
Let $$f, g :$$ $$\left[ { - 1,2} \right] \to R$$ be continuous functions which are twice differentiable on the interval $$(-1, 2)$$. Let the values of f and g at the points $$-1, 0$$ and $$2$$ be as given in the following table:
| X = -1 | X = 0 | X = 2 | |
|---|---|---|---|
| f(x) | 3 | 6 | 0 |
| g(x) | 0 | 1 | -1 |
In each of the intervals $$(-1, 0)$$ and $$(0, 2)$$ the function $$(f-3g)''$$ never vanishes. Then the correct statement(s) is (are)
14
Let $$f\left( x \right) = 7{\tan ^8}x + 7{\tan ^6}x - 3{\tan ^4}x - 3{\tan ^2}x$$ for all $$x \in \left( { - {\pi \over 2},{\pi \over 2}} \right).$$
Then the correct expression(s) is (are)
Then the correct expression(s) is (are)
15
The option(s) with the values of a and $$L$$ that satisfy the following equation is (are)
$$${{\int\limits_0^{4\pi } {{e^t}\left( {{{\sin }^6}at + {{\cos }^4}at} \right)dt} } \over {\int\limits_0^\pi {{e^t}\left( {{{\sin }^6}at + {{\cos }^4}at} \right)dt} }} = L?$$$
16
Let $$f'\left( x \right) = {{192{x^3}} \over {2 + {{\sin }^4}\,\pi x}}$$ for all $$x \in R\,\,$$ with $$f\left( {{1 \over 2}} \right) = 0$$.
If $$m \le \int\limits_{1/2}^1 {f\left( x \right)dx \le M,} $$ then the possible values of $$m$$ and $$M$$ are
If $$m \le \int\limits_{1/2}^1 {f\left( x \right)dx \le M,} $$ then the possible values of $$m$$ and $$M$$ are
17
Let $$F:R \to R$$ be a thrice differentiable function. Suppose that
$$F\left( 1 \right) = 0,F\left( 3 \right) = - 4$$ and $$F\left( x \right) < 0$$ for all $$x \in \left( {{1 \over 2},3} \right).$$ Let $$f\left( x \right) = xF\left( x \right)$$ for all $$x \in R.$$
$$F\left( 1 \right) = 0,F\left( 3 \right) = - 4$$ and $$F\left( x \right) < 0$$ for all $$x \in \left( {{1 \over 2},3} \right).$$ Let $$f\left( x \right) = xF\left( x \right)$$ for all $$x \in R.$$
If $$\int_1^3 {{x^2}F'\left( x \right)dx = - 12} $$ and $$\int_1^3 {{x^3}F''\left( x \right)dx = 40,} $$ then the correct expression(s) is (are)
18
Let $$F:R \to R$$ be a thrice differentiable function. Suppose that
$$F\left( 1 \right) = 0,F\left( 3 \right) = - 4$$ and $$F'\left( x \right) < 0$$ for all $$x \in \left( {{1 \over 2},3} \right).$$ Let $$f\left( x \right) = xF\left( x \right)$$ for all $$x \in R.$$
$$F\left( 1 \right) = 0,F\left( 3 \right) = - 4$$ and $$F'\left( x \right) < 0$$ for all $$x \in \left( {{1 \over 2},3} \right).$$ Let $$f\left( x \right) = xF\left( x \right)$$ for all $$x \in R.$$
The correct statement(s) is (are)
19
If $$\alpha = \int\limits_0^1 {\left( {{e^{9x + 3{{\tan }^{ - 1}}x}}} \right)\left( {{{12 + 9{x^2}} \over {1 + {x^2}}}} \right)} dx$$ where $${\tan ^{ - 1}}x$$ takes only principal values, then the value of $$\left( {{{\log }_e}\left| {1 + \alpha } \right| - {{3\pi } \over 4}} \right)$$ is
20
Let m and n be two positive integers greater than 1. If
$$$\mathop {\lim }\limits_{\alpha \to 0} \left( {{{{e^{\cos \left( {{\alpha ^n}} \right)}} - e} \over {{\alpha ^m}}}} \right) = - \left( {{e \over 2}} \right)$$$
then the value of $${m \over n}$$ is _________.
Physics
1
Consider a uniform spherical charge distribution of radius $${R_1}$$ centred at the origin $$O.$$ In this distribution, a spherical cavity of radius $${R_2},$$ centred at $$P$$ with distance $$OP=a$$ $$ = {R_1} - {R_2}$$ (see figure) is made. If the electric field inside the cavity at position $$\overrightarrow r $$ is $$\overrightarrow E \overrightarrow {\left( r \right)} ,$$ then the correct statement(s) is (are)
2
A spherical body of radius R consists of a fluid of constant density and is in equilibrium under its own gravity. If P(r) is the pressure at r (r < R), then the correct option(s) is(are)
3
The densities of two solid spheres A and B of the same radii R vary with radial distance r as $${\rho _A}(r) = k\left( {{r \over R}} \right)$$ and $${\rho _B}(r) = k{\left( {{r \over R}} \right)^5}$$, , respectively, where k is a constant. The moments of inertia of the individual spheres about axes passing through their centres are $${I_A}$$ and $${I_B}$$, respectively. If, $${{{I_B}} \over {{I_A}}} = {n \over {10}}$$, the value of n is
4
The energy of a system as a function of time t is given as E(t) = $${A^2}\exp \left( { - \alpha t} \right)$$, where $$\alpha = 0.2\,{s^{ - 1}}$$. The
measurement of A has an error of 1.25 %. If the error in the measurement of time is 1.50 %, the percentage
error in the value of E(t) at t = 5 s is
5
In terms of potential difference V, electric current I, permittivity $${\varepsilon _0}$$, permeability $${\mu _0}$$ and speed of light c,
the dimensionally correct equation(s) is(are) :
6
Four harmonic waves of equal frequencies and equal intensities I0 have phase angles 0, $${\pi \over 3},{{2\pi } \over 3}$$ and $$\pi$$. When they are superposed, the intensity of the resulting wave is nI0. The value of n is
7
For a radioactive material, its activity A and rate of change of its activity R are defined as $$A = - {{dN} \over {dt}}$$ and $$R = - {{dA} \over {dt}}$$, where N(t) is the number of nuclei at time t. Two radioactive source P(mean life $$\tau $$) and Q (mean life 2$$\tau $$) have the same activity at t = 0. Their rate of change of activities at t = 2$$\tau $$ are RP and RQ, respectively. If $${{{R_P}} \over {{R_Q}}} = {n \over e}$$, then the value of n is
8
A monochromatic beam of light is incident at 60$$^\circ$$ on one face of an equilateral prism of refractive index n and emerges from the opposite face making an angle $$\theta$$(n) with the normal (see figure). For n = $$\sqrt 3 $$ the value of $$\theta$$ is 60$$^\circ$$ and $${{d\theta } \over {dn}} = m$$. The value of m is
9
In the following circuit, the current through the resistor R(=2$$\Omega$$) is I amperes. The value of I is :
10
An electron in an excited state of Li2+ ion has angular momentum $${{3h} \over {2\pi }}$$. The de Broglie wavelength of the electron in this state is p$$\pi$$a0 (where a0 is the Bohr radius). The value of p is
11
A large spherical mass M is fixed at one position and two identical masses m are kept on a line passing through the centre of M (see figure). The point masses are connected by a rigid massless rod of length l and this assembly is free to move along the line connecting them.
All three masses interact only through their mutual gravitational interaction. When the point mass nearer to M is at a distance r = 3l from M the tension in the rod is zero for m = $$k\left( {{M \over {288}}} \right)$$. The value of k is
All three masses interact only through their mutual gravitational interaction. When the point mass nearer to M is at a distance r = 3l from M the tension in the rod is zero for m = $$k\left( {{M \over {288}}} \right)$$. The value of k is
12
In plotting stress versus strain curves for two materials P and Q, a student by mistake puts strain on the y-axis and stress on the x-axis as shown in the figure. Then, the correct statements is/are
13
A parallel plate capacitor having plates of area S and plate separation d, has capacitance C1 in air. When two dielectrics of different relative permittivities ($$\varepsilon $$1 = 2 and $$\varepsilon $$2 = 4) are introduced between the two plates as shown in the figure, the capacitance becomes C2. The ratio $${{{C_2}} \over {{C_1}}}$$ is
14
An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the figure). Initially the gas is at temperature T1, pressure P1 and volume V1 and the spring is in its relaxed state. The gas is then heated very slowly to temperature T2, pressure P2 and volume V2. During this process the piston moves out by a distance x.
Ignoring the friction between the piston and the cylinder, the correct statements is/are
Ignoring the friction between the piston and the cylinder, the correct statements is/are
15
A fission reaction is given by $$_{92}^{236}U \to _{54}^{140}Xe + _{38}^{94}Sr + x + y$$, where x and y are two particles. Considering $$_{92}^{236}U$$ to be at rest, the kinetic energies of the products are denoted by $${K_{Xe}},{K_{Sr}},{K_x}(2MeV)$$ $$
\text { and } \mathrm{K}_{\mathrm{y}}(2 \mathrm{MeV})
$$, respectively. Let the binding energies per nucleon of $$_{92}^{236}U$$, $$_{54}^{140}Xe$$ and $$_{38}^{94}Sr$$ be 7.5 MeV, 8.5 MeV and 8.5 MeV, respectively. Considering different conservation laws, the correct options is/are
16
Two spheres P and Q for equal radii have densities $$\rho$$1 and $$\rho$$2, respectively. The spheres are connected by a massless string and placed in liquids L1 and L2 of densities $$\sigma$$1 and $$\sigma$$2 and viscosities $${\eta _1}$$ and $${\eta _2}$$, respectively. They float in equilibrium with the sphere P in L1 and sphere Q in L2 and the string being taut (see figure) If sphere P along in L2 has terminal velocity vP and Q alone in L1 ha terminal velocity vQ, then
17
For two structures namely S1 with n1 = $${{\sqrt {45} } \over 4}$$ and n2 = $${3 \over 2}$$, and S2 with n1 = $${8 \over 5}$$ and n2 = $${7 \over 5}$$ and taking the refractive index of water to be $${4 \over 3}$$ and that to air to be 1, the correct options is/are :
18
If two structures of same cross-sectional area, but different numeral apertures NA1 and NA2 (NA2 < NA1) are joined longitudinally, the numerical aperture of the combined structure is
19
Consider two different metallic strips (1 and 2) of the same material. Their lengths are the same, widths are w1 and w2 and thickness are d1 and d2, respectively. Two points K and M are symmetrically located on the opposite faces parallel to the x-y plane (see figure). V1 and V2 are the potential differences between K and M in strips 1 and 2, respectively. Then, for a given current I flowing through them in a given magnetic field strength B, the correct statements is/are
20
Consider two different metallic strips (1 and 2) of same dimensions (length l, width w and thickness d) with carrier densities n1 and n2, respectively. Strip 1 is placed in magnetic field B1 and strip 2 is placed in magnetic field B2, both along positive y-directions. Then V1 and V2 are the potential differences developed between K and M in strips 1 and 2, respectively. Assuming that the current I is the same for both the strips, the correct options is/are :