JEE Advanced 2014 Paper 2 Offline
Paper was held on Sun, May 25, 2014 2:00 AM
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Chemistry

1
For the elementary reaction M $$\to$$ N, the rate of disappearance of M increases by a factor of 8 upon doubling the concentration of M. The order of the reaction with respect to M is
2
Hydrogen peroxide in its reaction with KIO4 and NH2OH respectively, is acting as a
3
For the process
H2O(l) $$\to$$ H2O(g)
at T = 100oC and 1 atmosphere pressure, the correct choice is
4
Assuming 2s – 2p mixing is NOT operative, the paramagnetic species among the following is
5

For the identification of $$\beta$$-naphthol using dye test, it is necessary to use

6

Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure.

JEE Advanced 2014 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 20 English

The correct order of their boiling point is

7

The acidic hydrolysis of ether (X) shown below is fastest when

JEE Advanced 2014 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 15 English

8

The major product in the following reaction is

JEE Advanced 2014 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 40 English
9

The product formed in the reaction of SOCl2 with white phosphorus is

10

Under ambient conditions, the total number of gases released as products in the final step of the reaction scheme shown below is

JEE Advanced 2014 Paper 2 Offline Chemistry - p-Block Elements Question 33 English

11
The value of d in cm (shown in the figure), as estimated from Graham's law, is
12

The experimental value of d is found to be smaller than the estimate obtained using Graham's law. This is due to

13
The product X is
14

The correct statement with respect to product Y is

15
M1, Q and R, respectively, are
16

Reagent S is

17

Match each coordination compound in List I with an appropriate pair of characteristics from List II and select the correct answer using the code given below the lists.

{en = H2NCH2CH2NH2; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}

List I List II
P. $$[Cr{(N{H_3})_3}C{l_2}]Cl$$
1. Paramagnetic and exhibits ionisation isomerism.
Q. $$[Ti{({H_2}O)_5}Cl]{(N{O_3})_2}$$
2. Diamagnetic and exhibits cis-trans isomerism.
R. $$[Pt(en)(N{H_3})Cl]N{O_3}$$
3. Paramagnetic and exhibits cis-trans isomerism.
S. $$[Co{(N{H_3})_4}{(N{O_3})_2}]N{O_3}$$
4. Diamagnetic and exhibits ionisation isomerism.

18

Match the orbital overlap figures shown in List I with the description given in List II and select the correct answer using the code given below the lists.

JEE Advanced 2014 Paper 2 Offline Chemistry - Chemical Bonding & Molecular Structure Question 8 English

19

Different possible thermal decomposition pathways for peroxyesters are shown below. Match each pathway from List I with an appropriate structure from List II and select the correct answer using the code given below the lists.

JEE Advanced 2014 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 39 English 1

JEE Advanced 2014 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 39 English 2

20

Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.

JEE Advanced 2014 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 15 English

Mathematics

1
Three boys and two girls stand in a queue. The probability, that the number of boys ahead of every girl is at least one more than the number of girls ahead of her, is
2
For $$x \in \left( {0,\pi } \right),$$ the equation $$\sin x + 2\sin 2x - \sin 3x = 3$$ has
3
Match List $$I$$ with List $$II$$ and select the correct answer using the code given below the lists:

$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$ List-$$I$$
(P.)$$\,\,\,\,$$ Let $$y\left( x \right) = \cos \left( {3{{\cos }^{ - 1}}x} \right),x \in \left[ { - 1,1} \right],x \ne \pm {{\sqrt 3 } \over 2}.$$ Then $${1 \over {y\left( x \right)}}\left\{ {\left( {{x^2} - 1} \right){{{d^2}y\left( x \right)} \over {d{x^2}}} + x{{dy\left( x \right)} \over {dx}}} \right\}$$ equals
(Q.)$$\,\,\,\,$$ Let $${A_1},{A_2},....,{A_n}\left( {n > 2} \right)$$ be the vertices of a regular polygon of $$n$$ sides with its centre at the origin. Let $${\overrightarrow {{a_k}} }$$ be the position vector of the point $${A_k},k = 1,2,......,n.$$ $$$f\left| {\sum\nolimits_{k = 1}^{n - 1} {\left( {\overrightarrow {{a_k}} \times \overrightarrow {{a_{k + 1}}} } \right)} } \right| = \left| {\sum\limits_{k = 1}^{n - 1} {\left( {\overrightarrow {{a_k}} .\,\overrightarrow {{a_{k + 1}}} } \right)} } \right|,$$$ then the minimum value of $$n$$ is
(R.)$$\,\,\,\,$$ If the normal from the point $$P(h, 1)$$ on the ellipse $${{{x^2}} \over 6} + {{{y^2}} \over 3} = 1$$ is perpendicular to the line $$x+y=8,$$ then the value of $$h$$ is
(S.)$$\,\,\,\,$$ Number of positive solutions satisfying the equation $${\tan ^{ - 1}}\left( {{1 \over {2x + 1}}} \right) + {\tan ^{ - 1}}\left( {{1 \over {4x + 1}}} \right) = {\tan ^{ - 1}}\left( {{2 \over {{x^2}}}} \right)$$ is

$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$List-$$II$$
(1.)$$\,\,\,\,$$ $$1$$
(2.)$$\,\,\,\,$$ $$2$$
(3.)$$\,\,\,\,$$ $$8$$
(4.)$$\,\,\,\,$$ $$9$$

4
Box $$1$$ contains three cards bearing numbers $$1,2,3;$$ box $$2$$ contains five cards bearing numbers $$1,2,3,4,5;$$ and box $$3$$ contains seven cards bearing numbers $$1,2,3,4,5,6,7.$$ A card is drawn from each of the boxes. Let $${x_i}$$ be number on the card drawn from the $${i^{th}}$$ box, $$i=1,2,3.$$

The probability that $${x_1},$$, $${x_2},$$ $${x_3}$$ are in an arithmetic progression, is

5
Box $$1$$ contains three cards bearing numbers $$1,2,3;$$ box $$2$$ contains five cards bearing numbers $$1,2,3,4,5;$$ and box $$3$$ contains seven cards bearing numbers $$1,2,3,4,5,6,7.$$ A card is drawn from each of the boxes. Let $${x_i}$$ be number on the card drawn from the $${i^{th}}$$ box, $$i=1,2,3.$$

The probability that $${x_1} + {x_2} + {x_3}$$ is odd, is

6
Let $$a, r, s, t$$ be nonzero real numbers. Let $$P\,\,\left( {a{t^2},2at} \right),\,\,Q,\,\,\,R\,\,\left( {a{r^2},2ar} \right)$$ and $$S\,\,\left( {a{s^2},2as} \right)$$ be distinct points on the parabola $${y^2} = 4ax$$. Suppose that $$PQ$$ is the focal chord and lines $$QR$$ and $$PK$$ are parallel, where $$K$$ is the point $$(2a,0)$$

If $$st=1$$, then the tangent at $$P$$ and the normal at $$S$$ to the parabola meet at a point whose ordinate is

7
Let $${z_k}$$ = $$\cos \left( {{{2k\pi } \over {10}}} \right) + i\,\,\sin \left( {{{2k\pi } \over {10}}} \right);\,k = 1,2....,9$$

List-I


P. For each $${z_k}$$ = there exits as $${z_j}$$ such that $${z_k}$$.$${z_j}$$ = 1
Q. There exists a $$k \in \left\{ {1,2,....,9} \right\}$$ such that $${z_1}.z = {z_k}$$ has no solution z in the set of complex numbers
R. $${{\left| {1 - {z_1}} \right|\,\left| {1 - {z_2}} \right|\,....\left| {1 - {z_9}} \right|} \over {10}}$$ equals
S. $$1 - \sum\limits_{k = 1}^9 {\cos \left( {{{2k\pi } \over {10}}} \right)} $$ equals

List-II


1. True
2. False
3. 1
4. 2
8
The quadratic equation $$p(x)$$ $$ = 0$$ with real coefficients has purely imaginary roots. Then the equation $$p(p(x))=0$$ has
9
Coefficient of $${x^{11}}$$ in the expansion of $${\left( {1 + {x^2}} \right)^4}{\left( {1 + {x^3}} \right)^7}{\left( {1 + {x^4}} \right)^{12}}$$ is
10
Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in envelopes so that each envelope contains exactly one card and no card is placed in the envelope bearing the same number and moreover the card numbered 1 is always placed in envelope numbered 2. Then the number of ways it can be done is
11
The common tangents to the circle $${x^2} + {y^2} = 2$$ and the parabola $${y^2} = 8x$$ touch the circle at the points $$P, Q$$ and the parabola at the points $$R$$, $$S$$. Then the area of the quadrilateral $$PQRS$$ is
12
Let $$a, r, s, t$$ be nonzero real numbers. Let $$P\,\,\left( {a{t^2},2at} \right),\,\,Q,\,\,\,R\,\,\left( {a{r^2},2ar} \right)$$ and $$S\,\,\left( {a{s^2},2as} \right)$$ be distinct points on the parabola $${y^2} = 4ax$$. Suppose that $$PQ$$ is the focal chord and lines $$QR$$ and $$PK$$ are parallel, where $$K$$ is the point $$(2a,0)$$

The value of $$r$$ is

13
The function $$y=f(x)$$ is the solution of the differential equation
$${{dy} \over {dx}} + {{xy} \over {{x^2} - 1}} = {{{x^4} + 2x} \over {\sqrt {1 - {x^2}} }}\,$$ in $$(-1,1)$$ satisfying $$f(0)=0$$.
Then $$\int\limits_{ - {{\sqrt 3 } \over 2}}^{{{\sqrt 3 } \over 2}} {f\left( x \right)} \,d\left( x \right)$$ is
14
Let $$f:\left[ {0,2} \right] \to R$$ be a function which is continuous on $$\left[ {0,2} \right]$$ and is differentiable on $$(0,2)$$ with $$f(0)=1$$. Let
$$F\left( x \right) = \int\limits_0^{{x^2}} {f\left( {\sqrt t } \right)dt} $$ for $$x \in \left[ {0,2} \right]$$. If $$F'\left( x \right) = f'\left( x \right)$$ for all $$x \in \left[ {0,2} \right]$$, then $$F(2)$$ equals
15
In a triangle the sum of two sides is $$x$$ and the product of the same sides is $$y$$. If $${x^2} - {c^2} = y$$, where $$c$$ is the third side of the triangle, then the ratio of the in radius to the circum-radius of the triangle is
16
The following integral $$\int\limits_{{\pi \over 4}}^{{\pi \over 2}} {{{\left( {2\cos ec\,\,x} \right)}^{17}}dx} $$ is equal to
17
List - $$I$$
P.$$\,\,\,\,$$ The number of polynomials $$f(x)$$ with non-negative integer coefficients of degree $$ \le 2$$, satisfying $$f(0)=0$$ and $$\int_0^1 {f\left( x \right)dx = 1,} $$ is
Q.$$\,\,\,\,$$ The number of points in the interval $$\left[ { - \sqrt {13} ,\sqrt {13} } \right]$$
at which $$f\left( x \right) = \sin \left( {{x^2}} \right) + \cos \left( {{x^2}} \right)$$ attains its maximum value, is
R.$$\,\,\,\,$$ $$\int\limits_{ - 2}^2 {{{3{x^2}} \over {\left( {1 + {e^x}} \right)}}dx} $$ equals
S.$$\,\,\,\,$$ $${{\left( {\int\limits_{ - {1 \over 2}}^{{1 \over 2}} {\cos 2x\log \left( {{{1 + x} \over {1 - x}}} \right)dx} } \right)} \over {\left( {\int\limits_0^{{1 \over 2}} {\cos 2x\log \left( {{{1 + x} \over {1 - x}}} \right)dx} } \right)}}$$

List $$II$$
1.$$\,\,\,\,$$ $$8$$
2.$$\,\,\,\,$$ $$2$$
3.$$\,\,\,\,$$ $$4$$
4.$$\,\,\,\,$$ $$0$$

18
Given that for each $$a \in \left( {0,1} \right),\,\,\,\mathop {\lim }\limits_{h \to {0^ + }} \,\int\limits_h^{1 - h} {{t^{ - a}}{{\left( {1 - t} \right)}^{a - 1}}dt} $$ exists. Let this limit be $$g(a).$$ In addition, it is given that the function $$g(a)$$ is differentiable on $$(0,1).$$

The value of $$g'\left( {{1 \over 2}} \right)$$ is

19
Given that for each $$a \in \left( {0,1} \right),\,\,\,\mathop {\lim }\limits_{h \to {0^ + }} \,\int\limits_h^{1 - h} {{t^{ - a}}{{\left( {1 - t} \right)}^{a - 1}}dt} $$ exists. Let this limit be $$g(a).$$ In addition, it is given that the function $$g(a)$$ is differentiable on $$(0,1).$$

The value of $$g\left( {{1 \over 2}} \right)$$ is

20
Let f1 : R $$ \to $$ R, f2 : [0, $$\infty $$) $$ \to $$ R, f3 : R $$ \to $$ R, and f4 : R $$ \to $$ [0, $$\infty $$) be defined by

$${f_1}\left( x \right) = \left\{ {\matrix{ {\left| x \right|} & {if\,x < 0,} \cr {{e^x}} & {if\,x \ge 0;} \cr } } \right.$$

f2(x) = x2 ;

$${f_3}\left( x \right) = \left\{ {\matrix{ {\sin x} & {if\,x < 0,} \cr x & {if\,x \ge 0;} \cr } } \right.$$

and

$${f_4}\left( x \right) = \left\{ {\matrix{ {{f_2}\left( {{f_1}\left( x \right)} \right)} & {if\,x < 0,} \cr {{f_2}\left( {{f_1}\left( x \right)} \right) - 1} & {if\,x \ge 0;} \cr } } \right.$$

JEE Advanced 2014 Paper 2 Offline Mathematics - Functions Question 12 English

Physics

1
Charges $$Q,$$ $$2Q$$ and $$4Q$$ are uniformly distributed in three dielectric solid spheres $$1,2$$ and $$3$$ of radii $$R/2,R$$ and $$2R$$ respectively, as shown in figure. If magnitude of the electric fields at point $$P$$ at a distance $$R$$ from the center of sphere $$1,2$$ and $$3$$ are $${E_1}$$, $${E_2}$$ and $${E_3}$$ respectively, then
JEE Advanced 2014 Paper 2 Offline Physics - Electrostatics Question 53 English 1
JEE Advanced 2014 Paper 2 Offline Physics - Electrostatics Question 53 English 2
2
Parallel rays of light of intensity $$I$$ = 912 Wm–2 are incident on a spherical black body kept in surroundings of temperature 300 K. Take Stefan-Boltzmann constant $$\sigma $$ = 5.7 $$ \times $$ 10–8 Wm–2K–4 and assume that the energy exchange with the surroundings is only through radiation. The final steady state temperature of the black body is close to
3

A person in a lift is holding a water jar, which has a small hole at the lower end of its side. When the lift is at rest, the water jet coming out of the hole hits the floor of the lift at a distance d of 1.2 m from the person. In the following, state of the lift’s motion is given in List I and the distance where the water jet hits the floor of the lift is given in List II. Match the statements from List I with those in List II and select the correct answer using the options given below the lists.

List - I List - II
P. Lift is accelerating vertically up. 1. d=1.2 m
Q. Lift is accelerating vertically down
with an acceleration less than the
gravitational acceleration.
2. d > 1.02 m
R. Lift is moving vertically up with
constant speed.
3. d < 1.2 m
S. Lift is falling freely. 4. No water leaks out of the jar
4
A planet of radius R = $${1 \over {10}} \times $$ (radius of Earth) has the same mass density as Earth. Scientists dig a well of depth $${R \over 5}$$ on it and lower a wire of the same length and of linear mass density 10-3 kg m-1 into it. If the wire is not touching anywhere, the force applied at the top of the wire by a person holding it in place is (take the radius of Earth = 6 $$ \times $$ 106 m and the acceleration due to gravity of Earth is 10 ms -2)
5
A tennis ball is dropped on a horizontal smooth surface. It bounces back to its original position after hitting the surface. The force on the ball during the collision is proportional to the length of compression of the ball. Which one of the following sketches describes the variation of its kinetic energy K with time t most appropriately? The figures are only illustrative and not to the scale.
6

If $$\lambda$$Cu is the wavelength of K$$\alpha$$ X-ray line of copper (atomic number 29) and $$\lambda$$Mo is the wavelength of the K$$\alpha$$ X-ray line of molybdenum (atomic number 42), then the ratio $$\lambda$$Cu/$$\lambda$$Mo is close to

7

A metal surface is illuminated by light of two different wavelengths 248 nm and 310 nm. The maximum speeds of the photoelectrons corresponding to these wavelengths are u1 and u2, respectively. If the ratio u1 : u2 = 2 : 1 and hc = 1240 eV nm, the work function of the metal is nearly

8

During an experiment with a metre bridge, the galvanometer shall a null point when the jockey is pressed at 40.0 cm using a standard resistance of 90$$\Omega$$, as shown in the figure. The least count of the scale used in the meter bridge is 1 mm. The unknown resistance is

JEE Advanced 2014 Paper 2 Offline Physics - Current Electricity Question 16 English

9

A wire, which passes through the hole in a small bead, is bent in the form of quarter of a circle. The wire is fixed vertically on ground as shown in the below figure. The bead is released from near the top of the wire and it slides along the wire without friction. As the bead moves from A to B, the force it applies on the wire is

JEE Advanced 2014 Paper 2 Offline Physics - Laws of Motion Question 7 English

10

A glass capillary tube is of the shape of truncated cone with an apex angle $$\alpha$$ so that its two ends have cross sections of different radii. When dipped in water vertically, water rises in it to a height h, where the radius of its cross section is b. If the surface tension of water is S, its density is $$\rho$$, and its contact angle with glass is $$\theta$$, the value of h will be (g is the acceleration due to gravity)

JEE Advanced 2014 Paper 2 Offline Physics - Properties of Matter Question 19 English

11

A point source S is placed at the bottom of a transparent block of height 10 mm and refractive index 2.72. It is immersed in a lower refractive index liquid as shown in the below figure. It is found that the light emerging from the block to the liquid forms a circular bright spot of diameter 11.54 mm on the top of the block. The refractive index of the liquid is

JEE Advanced 2014 Paper 2 Offline Physics - Geometrical Optics Question 31 English

12

When d $$\approx$$ a but wires are not touching the loop, it is found that the net magnetic field on the axis of the loop is zero at a height h above the loop. In that case

13

Consider d >> a, and the loop is rotated about its diameter parallel to the wires by 30$$^\circ$$ from the position shown in the below figure. If the currents in the wires are in the opposite directions, the torque on the loop at its new position will be (assume that the net field due to the wires is constant over the loop)

14

Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved, the final temperature of the gases will be

15

Now consider the partition to be free to move without friction so that the pressure of gases in both compartments is the same. Then total work done by the gases till the time they achieve equilibrium will be

16

If the piston is pushed at a speed of 5 mm s$$-$$1, the air comes out of the nozzle with a speed of

17

If the density of air is $$\rho$$a and that of the liquid $$\rho$$l, then for a given piston speed the rate (volume per unit time) at which the liquid is sprayed will be proportional to

18

Four charges Q1, Q2, Q3 and Q4 of same magnitude are fixed along the x axis at x = $$-$$2a, $$-$$a, +a and +2a, respectively. A positive charge q is placed on the positive y axis at a distance b > 0. Four options of the signs of these charges are given in List I. The direction of the forces on the charge q is given in List II. Match List I with List II and select the correct answer using the code given below the lists.

JEE Advanced 2014 Paper 2 Offline Physics - Electrostatics Question 24 English

List I List II
P. Q$$_1$$, Q$$_2$$, Q$$_3$$, Q$$_4$$ all positive 1. +x
Q. Q$$_1$$, Q$$_2$$ positive; Q$$_3$$, Q$$_4$$ negative 2. $$ - $$x
R. Q$$_1$$, Q$$_4$$ positive; Q$$_2$$, Q$$_3$$ negative 3. +y
S. Q$$_1$$, Q$$_3$$ positive; Q$$_2$$, Q$$_4$$ negative 4. $$ - $$y

19

Four combinations of two thin lenses are given in List I. The radius of curvature of all curved surfaces is r and the refractive index of all the lenses is 1.5. Match lens combinations in List I with their focal length in List II and select the correct answer using the code given below the lists.

JEE Advanced 2014 Paper 2 Offline Physics - Geometrical Optics Question 32 English

20

A block of mass m1 = 1 kg another mass m2 = 2 kg, are placed together (see figure) on an inclined plane with angle of inclination $$\theta$$. Various values of $$\theta$$ are given in List I. The coefficient of friction between the block m1 and the plane is always zero. The coefficient of static and dynamic friction between the block m2 and the plane are equal to $$\mu$$ = 0.3. In List II expressions for the friction on the block m2 are given. Match the correct expression of the friction in List II with the angles given in List I, and choose the correct option. The acceleration due to gravity is denoted by g.

[Useful information : tan (5.5$$^\circ$$) $$\approx$$ 0.1; tan (11.5$$^\circ$$) $$\approx$$ 0.2; tan (16.5$$^\circ$$) $$\approx$$ 0.3]

JEE Advanced 2014 Paper 2 Offline Physics - Laws of Motion Question 8 English

List I List II
P. $$\theta = 5^\circ $$
1. $${m_2}g\sin \theta $$
Q. $$\theta = 10^\circ $$
2. $$({m_1} + {m_2})g\sin \theta $$
R. $$\theta = 15^\circ $$
3. $$\mu {m_2}g\cos \theta $$
S. $$\theta = 20^\circ $$
4. $$\mu ({m_1} + {m_2})g\cos \theta $$

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