Choose the correct option(s) for the following reaction sequence


Consider Q, R and S as major products.

Choose the correct option(s) that give(s) an aromatic compound as the major product.

The ground state energy of hydrogen atom is $$-$$13.6 eV. Consider an electronic state $$\psi $$ of He⁺ whose energy, azimuthal quantum number and magnetic quantum number are $$-$$3.4 eV, 2 and 0, respectively.

Which of the following statement(s) is(are) true for the state $$\psi $$?

Consider the following reactions (unbalanced).

$$Zn + Hot\,conc.\,{H_2}S{O_4}\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}} G + R + X$$

$$Zn + conc.\,NaOH\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}} T + Q$$

$$G + {H_2}S + N{H_4}OH\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}} Z\,(a\,precipitate) + X + Y$$

Choose the correct option(s).

With reference to aqua-regia, choose the correct option(s).

Choose the correct option(s) from the following.

The cyanide process of gold extraction involves leaching out gold from its ore with CN^$$-$$ in the presence of Q in water to form R. Subsequently, R is treated with T to obtain Au and Z. Choose the correct option(s).

Which of the following reactions produce(s) propane as a major product?

The decomposition reaction

$$2{N_2}{O_5}(g)\buildrel \Delta \over \longrightarrow 2{N_2}{O_4}(g) + {O_2}(g)$$

is started in a closed cylinder under isothermal isochoric condition at an initial pressure of 1 atm. After Y $$ \times $$ 10³ s, the pressure inside the cylinder is found to be 1.45 atm. If the rate constant of the reaction is 5 $$ \times $$ 10^-4s^-1, assuming ideal gas behaviour, the value of Y is ...............

The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05. If the density of the solution is 1.2 g cm^$$-$$3, then molarity of urea solution is ................

(Given data : Molar masses of urea and water are 60 g mol^$$-$$1 and 18 g mol^$$-$$1, respectively)

Total number of hydroxyl groups present in a molecule of the major product P is ..............

Total number of $$cis\,N - Mn - Cl$$ bond angles (that is $$Mn - N$$ and $$Mn - Cl$$ bonds in cis positions) present in a molecule of $$cis[Mn{(en)_2}C{l_2}]$$ complex is ..................

(en = NH₂CH₂CH₂NH₂)

The amount of water produced (in g) in the oxidation of 1 mole of rhombic sulphur by conc. HNO₃ to a compound with the highest oxidation state of sulphur is ..............

(Given data : Molar mass of water = 18 g mol^$$-$$1)

Total number of isomers, considering both structural and stereoisomers of cyclic ethers with the molecular formula C₄H₈O is .................

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.


Which of the following options has the correct combination considering List-I and List-II?

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.


Which of the following options has the correct combination considering List-I and List-II?

Which of the following options has correct combination considering List-I and List-II?

Which of the following options has correct combination considering List-I and List-II?

For non-negative integers n, let

$$f(n) = {{\sum\limits_{k = 0}^n {\sin \left( {{{k + 1} \over {n + 2}}\pi } \right)} \sin \left( {{{k + 2} \over {n + 2}}\pi } \right)} \over {\sum\limits_{k = 0}^n {{{\sin }^2}\left( {{{k + 1} \over {n + 2}}\pi } \right)} }}$$

Assuming cos^$$-1$$ x takes values in [0, $$\pi $$], which of the following options is/are correct?

Let f : R $$ \to $$ R be given by

$$f(x) = (x - 1)(x - 2)(x - 5)$$. Define

$$F(x) = \int\limits_0^x {f(t)dt} $$, x > 0

Then which of the following options is/are correct?

Let, $$f(x) = {{\sin \pi x} \over {{x^2}}}$$, x > 0

Let x₁ < x₂ < x₃ < ... < x_n < ... be all the points of local maximum of f and y₁ < y₂ < y₃ < ... < y_n < ... be all the points of local minimum of f.

Then which of the following options is/are correct?

Three lines $${L_1}:r = \lambda \widehat i$$, $$\lambda $$ $$ \in $$ R,

$${L_2}:r = \widehat k + \mu \widehat j$$, $$\mu $$ $$ \in $$ R and

$${L_3}:r = \widehat i + \widehat j + v\widehat k$$, v $$ \in $$ R are given.

For which point(s) Q on L₂ can we find a point P on L₁ and a point R on L₃ so that P, Q and R are collinear?

For $$a \in R,\,|a|\, > 1$$, let

$$\mathop {\lim }\limits_{n \to \infty } \left( {{{1 + \root 3 \of 2 + ...\root 3 \of n } \over {{n^{7/3}}\left( {{1 \over {{{(an + 1)}^2}}} + {1 \over {{{(an + 2)}^2}}} + ... + {1 \over {{{(an + n)}^2}}}} \right)}}} \right) = 54$$

Let f : R be a function. We say that f has

PROPERTY 1 if $$\mathop {\lim }\limits_{h \to 0} {{f(h) - f(0)} \over {\sqrt {|h|} }}$$ exists and is finite, and

PROPERTY 2 if $$\mathop {\lim }\limits_{h \to 0} {{f(h) - f(0)} \over {{h^2}}}$$ exists and is finite. Then which of the following options is/are correct?

Let x $$ \in $$ R and let $$P = \left[ {\matrix{ 1 & 1 & 1 \cr 0 & 2 & 2 \cr 0 & 0 & 3 \cr } } \right]$$, $$Q = \left[ {\matrix{ 2 & x & x \cr 0 & 4 & 0 \cr x & x & 6 \cr } } \right]$$ and R = PQP^$$-$$1, which of the following options is/are correct?

$${P_1} = I = \left[ {\matrix{ 1 & 0 & 0 \cr 0 & 1 & 0 \cr 0 & 0 & 1 \cr } } \right],\,{P_2} = \left[ {\matrix{ 1 & 0 & 0 \cr 0 & 0 & 1 \cr 0 & 1 & 0 \cr } } \right],\,{P_3} = \left[ {\matrix{ 0 & 1 & 0 \cr 1 & 0 & 0 \cr 0 & 0 & 1 \cr } } \right],\,{P_4} = \left[ {\matrix{ 0 & 1 & 0 \cr 0 & 0 & 1 \cr 1 & 0 & 0 \cr } } \right],\,{P_5} = \left[ {\matrix{ 0 & 0 & 1 \cr 1 & 0 & 0 \cr 0 & 1 & 0 \cr } } \right],\,{P_6} = \left[ {\matrix{ 0 & 0 & 1 \cr 0 & 1 & 0 \cr 1 & 0 & 0 \cr } } \right]$$ and $$X = \sum\limits_{k = 1}^6 {{P_k}} \left[ {\matrix{ 2 & 1 & 3 \cr 1 & 0 & 2 \cr 3 & 2 & 1 \cr } } \right]P_k^T$$

where $$P_k^T$$ denotes the transpose of the matrix P_k. Then which of the following option is/are correct?

Let $$\overrightarrow a = 2\widehat i + \widehat j - \widehat k$$ and $$\overrightarrow b = \widehat i + 2\widehat j + \widehat k$$ be two vectors. Consider a vector c = $$\alpha $$$$\overrightarrow a$$ + $$\beta $$$$\overrightarrow b$$, $$\alpha $$, $$\beta $$ $$ \in $$ R. If the projection of $$\overrightarrow c$$ on the vector ($$\overrightarrow a$$ + $$\overrightarrow b$$) is $$3\sqrt 2 $$, then the
minimum value of ($$\overrightarrow c$$ $$-$$($$\overrightarrow a$$ $$ \times $$ $$\overrightarrow b$$)).$$\overrightarrow c$$ equals ................

Let |X| denote the number of elements in a set X. Let S = {1, 2, 3, 4, 5, 6} be a sample space, where each element is equally likely to occur. If A and B are independent events associated with S, then the number of ordered pairs (A, B) such that 1 $$ \le $$ |B| < |A|, equals .............

Suppose

det$$\left| {\matrix{ {\sum\limits_{k = 0}^n k } & {\sum\limits_{k = 0}^n {{}^n{C_k}{k^2}} } \cr {\sum\limits_{k = 0}^n {{}^n{C_k}.k} } & {\sum\limits_{k = 0}^n {{}^n{C_k}{3^k}} } \cr } } \right| = 0$$

holds for some positive integer n. Then $$\sum\limits_{k = 0}^n {{{{}^n{C_k}} \over {k + 1}}} $$ equals ..............

Five persons A, B, C, D and E are seated in a circular arrangement. If each of them is given a hat of one of the three colours red, blue and green, then the number of ways of distributing the hats such that the persons seated in adjacent seats get different coloured hats is ............

The value of the integral $$ \int\limits_0^{\pi /2} {{{3\sqrt {\cos \theta } } \over {{{(\sqrt {\cos \theta } + \sqrt {\sin \theta } )}^5}}}} d\theta $$ equals ..............

The value of

$${\sec ^{ - 1}}\left( \matrix{ {1 \over 4}\sum\limits_{k = 0}^{10} {\sec \left( {{{7\pi } \over {12}} + {{k\pi } \over 2}} \right)} \sec \left( {{{7\pi } \over {12}} + {{(k + 1)\pi } \over 2}} \right) \hfill \cr} \right)$$

in the interval $$\left[ { - {\pi \over 4},\,{{3\pi } \over 4}} \right]$$ equals ..........

Let f(x) = sin($$\pi $$ cos x) and g(x) = cos(2$$\pi $$ sin x) be two functions defined for x > 0. Define the following sets whose elements are written in the increasing order:

X = {x : f(x) = 0}, Y = {x : f'(x) = 0}

Z = {x : g(x) = 0}, W = {x : g'(x) = 0}

List - I contains the sets X, Y, Z and W. List - II contains some information regarding these sets.



Which of the following is the only CORRECT combination?

Let f(x) = sin($$\pi $$ cos x) and g(x) = cos(2$$\pi $$ sin x) be two functions defined for x > 0. Define the following sets whose elements are written in the increasing order :

X = {x : f(x) = 0}, Y = {x : f'(x) = 0}

Z = {x : g(x) = 0}, W = {x : g'(x) = 0}

List - I contains the sets X, Y, Z and W. List - II contains some information regarding these sets.


Which of the following combinations is correct?

Let the circles

C₁ : x² + y² = 9 and C₂ : (x $$-$$ 3)² + (y $$-$$ 4)² = 16, intersect at the points X and Y. Suppose that another circle C₃ : (x $$-$$ h)² + (y $$-$$ k)² = r² satisfies the following conditions :

(i) Centre of C₃ is collinear with the centres of C₁ and C₂.

(ii) C₁ and C₂ both lie inside C₃ and

(iii) C₃ touches C₁ at M and C₂ at N.

Let the line through X and Y intersect C₃ at Z and W, and let a common tangent of C₁ and C₃ be a tangent to the parabola x² = 8$$\alpha $$y.

There are some expression given in the List-I whose values are given in List-II below.



Which of the following is the only INCORRECT combination?

Let the circle C₁ : x² + y² = 9 and C₂ : (x $$-$$ 3)² + (y $$-$$ 4)² = 16, intersect at the points X and Y. Suppose that another circle C₃ : (x $$-$$ h)² + (y $$-$$ k)² = r² satisfies the following conditions :

(i) centre of C₃ is collinear with the centers of C₁ and C₂.

(ii) C₁ and C₂ both lie inside C₃, and

(iii) C₃ touches C₁ at M and C₂ at N.

Let the line through X and Y intersect C₃ at Z and W, and let a common tangent of C₁ and C₃ be a tangent to the parabola x² = 8$$\alpha $$y.

There are some expression given in the List-I whose values are given in List-II below.



Which of the following is the only CORRECT combination?

An electric dipole with dipole moment $${{{p_0}} \over {\sqrt 2 }}(\widehat i + \widehat j)$$ is held fixed at the origin O in the presence of a uniform electric field of magnitude E₀.



If the potential is constant on a circle of radius R centered at the origin as shown in figure, then the correct statement(s) is/are, ($$ \in $$₀ is the permittivity of the free space, R >> dipole size)

A small particle of mass m moving inside a heavy, hollow and straight tube along the tube axis undergoes elastic collision at two ends. The tube has no friction and it is closed at one end by a flat surface while the other end is fitted with a heavy movable flat piston as shown in figure.



When the distance of the piston from closed end is L = L₀, the particle speed is v = v₀. The piston is moved inward at a very low speed V such that $$V < < {{dL} \over L}{v_0}$$, where dL is the infinitesimal displacement of the piston. Which of the following statement(s) is/are correct?

Three glass cylinders of equal height H = 30 cm and same refractive index n = 1.5 are placed on a horizontal surface as shown in figure.



Cylinder I has a flat top, cylinder II has a convex top and cylinder III has a concave top. The radii of curvature of the two curved tops are same (R = 3 m). If H₁, H2, and H3 are the apparent depths of a point X on the bottom of the three cylinders, respectively, the correct statement(s) is/are

A block of mass 2M is attached to a massless spring with spring-constant k.This block is connected to two other blocks of masses M and 2M using two massless pulleys and strings. The accelerations of the blocks are a₁, a₂ and a₃ as shown in the figure. The system is released from rest with the spring in its unstretched state. The maximum extension of the spring is x₀. Which of the following option(s) is/are correct? [g is the acceleration due to gravity. Neglect friction]

A thin and uniform rod of mass M and length L is held vertical on a floor with large friction. The rod is released from rest so that it falls by rotating about its contact-point with the floor without slipping. Which of the following statement(s) is/are correct, when the rod makes an angle 60$$^\circ $$ with vertical? [g is the acceleration due to gravity]

In a Young's double slit experiment, the slit separation d is 0.3 mm and the screen distance D is 1 m. A parallel beam of light of wavelength 600 nm is incident on the slits at angle $$\alpha $$ as shown in figure.



On the screen, the point O is equidistant from the slits and distance PO is 11.0 mm. Which of the following statement(s) is/are correct?

A free hydrogen atom after absorbing a photon of wavelength $$\lambda $$_a gets excited from the state n = 1 to the state n = 4. Immediately after that the electron jumps to n = m state by emitting a photon of wavelength $$\lambda $$_e. Let the change in momentum of atom due to the absorption and the emission be $$\Delta {p_a}$$ and $$\Delta {p_e}$$, respectively. If $${{{\lambda _a}} \over {{\lambda _e}}} = {1 \over 5}$$, which of the option(s) is/are correct? [Use hc = 1242 eVnm; 1 nm = 10^-9 m, h and c are Planck's constant and speed of light in vacuum, respectively]

A mixture of ideal gas containing 5 moles of monatomic gas and 1 mole of rigid diatomic gas is initially at pressure P₀, volume V₀, and temperature T₀. If the gas mixture is adiabatically compressed to a volume $${{{V_0}} \over 4}$$, then the correct statement(s) is/are

(Given, 2^1.2 = 2.3; 2^3.2 = 9.2; R is a gas constant)

Suppose a $$_{88}^{226}Ra$$ nucleus at rest and in ground state undergoes $$\alpha $$-decay to a $$_{86}^{222}Rn$$ nucleus in its excited state. The kinetic energy of the emitted $$\alpha $$ particle is found to be 4.44 MeV. $$_{86}^{222}Rn$$ nucleus then goes to its ground state by $$\gamma $$-decay. The energy of the emitted $$\gamma $$ photon is ............ keV.

[Given : atomic mass of $$_{86}^{226}Ra$$ = 226.005 u, atomic of $$_{86}^{222}Rn$$ = 222.000 u, atomic mass of $$\alpha $$ particle = 4.000 u, 1 u = 931 MeV/e², c is speed of the light]

A monochromatic light is incident from air on a refracting surface of a prism of angle 75$$^\circ $$ and refractive index $${n_0} = \sqrt 3 $$. The other refracting surface of the prism is coated by a thin film of material of refractive index n as shown in figure. The light suffers total internal reflection at the coated prism surface for an incidence angle of $$\theta \le 60^\circ $$. The value of n² is .............

A perfectly reflecting mirror of mass M mounted on a spring constitutes a spring-mass system of angular frequency $$\Omega $$ such that $${{4\pi M\Omega } \over h} = {10^{24}}{m^{ - 2}}$$ with h as Planck's constant. N photons of wavelength $$\lambda $$ = 8$$\pi $$ $$ \times $$ 10^{$$ - $$6} m strike the mirror simultaneously at normal incidence such that the mirror gets displaced by 1 $$\mu $$m. If the value of N is x $$ \times $$ 10¹², then the value of x is ................ [Consider the spring as massless]

An optical bench has 1.5 m long scale having four equal divisions in each cm. While measuring the focal length of a convex lens, the lens is kept at 75 cm mark of the scale and the object pin is kept at 45 cm mark. The image of the object pin on the other side of the lens overlaps with image pin that is kept at 135 cm mark. In this experiment, the percentage error in the measurement of the focal length of the lens is ..............

A ball is thrown from ground at an angle $$\theta $$ with horizontal and with an initial speed u₀. For the resulting projectile motion, the magnitude of average velocity of the ball up to the point when it hits the ground for the first time is V₁. After hitting the ground, the ball rebounds at the same angle $$\theta $$ but with a reduced speed of $${{{u_0}} \over \alpha }$$. Its motion continues for a long time as shown in figure. If the magnitude of average velocity of the ball for entire duration of motion is 0.8 V₁, the value of $$\alpha $$ is ..................

A 10 cm long perfectly conducting wire PQ is moving with a velocity I cm/s on a pair of horizontal rails of zero resistance. One side of the rails is connected to an inductor L = 1 mH and a resistance R = 1$$\Omega $$ as shown in figure. The horizontal rails, L and R lie in the same plane with a uniform magnetic field B = 1 T perpendicular to the plane. If the key S is closed at certain instant, the current in the circuit after 1 millisecond is x $$ \times $$ 10^-3 A, where the value of x is ...........

[Assume the velocity of wire PQ remains constant (1 cm/s) after key S is closed. Given e^-1 = 0.37, where e is base of the natural logarithm]

A musical instrument is made using four different metal strings, 1, 2, 3 and 4 with mass per unit length $$\mu $$, 2$$\mu $$, 3$$\mu $$ and 4$$\mu $$ respectively. The instrument is played by vibrating the strings by varying the free length in between the range L₀ and 2L₀. It is found that in string-1$$\mu $$ at free length L₀ and tension T₀ the fundamental mode frequency is f₀.

List-I gives the above four strings while list-II lists the magnitude of some quantity.



If the tension in each string is T₀, the correct match for the highest fundamental frequency in f₀ units will be

A musical instrument is made using four different metal strings, 1, 2, 3 and 4 with mass per unit length $$\mu $$, 2$$\mu $$, 3$$\mu $$ and 4$$\mu $$ respectively. The instrument is played by vibrating the strings by varying the free length in between the range L₀ and 2L₀. It is found that in string-1$$\mu $$ at free length L₀ and tension T₀ the fundamental mode frequency is f₀.

List-I gives the above four strings while list-II lists the magnitude of some quantity.



The length of the strings 1, 2, 3 and 4 are kept fixed at L₀, $${{3{L_0}} \over 2}$$, $${{5{L_0}} \over 4}$$ and $${{7{L_0}} \over 4}$$ respectively. Strings 1, 2, 3 and 4 are vibrated at their 1st, 3rd, 5th and 14th harmonies, respectively such that all the strings have same frequency.

The correct match for the tension in the four strings in the units of T₀ will be

If the process on one mole of monatomic ideal gas is as shown in the TV-diagram with $${P_0}{V_0} = {1 \over 3}R{T_0}$$, the correct match is,

If the process carried out on one mole of monoatomic ideal gas is as shown in the PV-diagram with $${p_0}{V_0} = {1 \over 3}R{T_0}$$, the correct match is,