IIT-JEE 2010 Paper 1 Offline
Paper was held on Sun, Apr 11, 2010 9:00 AM
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Chemistry

1
Based on VSEPR theory, the number of 90 degree F-Br-F angles in BrF5 is
2
The species which by definition has ZERO standard molar enthalpy of formation at 298 K is
3
Among the following, the intensive property is (properties are)
4
Aqueous solution of HNO3, KOH and CH3COOH and CH3COONa of identical concentrations are provided. The pairs of solutions which form a buffer upon mixing is(are)
5
Amongst the following the total number of compounds whose aqueous solution turns red litmus paper blue is
KCN, K2SO4, (NH4)2C2O4, NaCl, Zn(NO3)2, FeCl3, K2CO3, NH4NO3 and LiCN
6
The reagent(s) used for softening the temporary hardness of water is (are)
7
The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6 is
8
The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and and alkyne
9
The bond energy (in kcal mol-1) of a C-C single bond is approximately
10
The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is :
M(s) | M+ (aq ; 0.05 molar) || M+ (aq ; 1 molar) | M(s)
For the above electrolytic cell the magnitude of the cell potential | Ecell | = 70 mV.

For the above cell :
11
The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is :
M(s) | M+ (aq ; 0.05 molar) || M+ (aq ; 1 molar) | M(s)
For the above electrolytic cell the magnitude of the cell potential | Ecell | = 70 mV.

If the 0.05 molar solution of M+ is replaced by a 0.0025 molar M+ solution, then the magnitude of the cell potential would be :
12
The concentration of R in the reaction R $$\to$$ P was measured as a function of time and the following data is obtained
[R] molar 1.0 0.75 0.40 0.10
t (min.) 0.0 0.05 0.12 0.18
The order of reaction is
13
The number of neutrons emitted when $${}_{92}^{235}U$$ undergoes controlled nuclear fission to $${}_{54}^{142}Xe$$ and $${}_{38}^{90}Sr$$ is
14
A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL, and 25.0 mL. The number of significant figures in the average titre value is
15

The correct statement about the following disaccharide is :

IIT-JEE 2010 Paper 1 Offline Chemistry - Biomolecules Question 6 English

16

In the reaction

IIT-JEE 2010 Paper 1 Offline Chemistry - Alcohols, Phenols and Ethers Question 9 English

the products are :

17

Plots showing the variation of the rate constant ($$k$$) with temperature ($$T$$) are given below. The point that follows Arrhenius equation is

18

The correct structure of ethylenediaminetetraacetic acid (EDTA) is

19

The ionisation isomer of $$\mathrm{[Cr(H_2O)_4Cl(NO_2)]Cl}$$ is

20

In the Newman projection for 2,2-dimethylbutane, X and Y can, respectively, be

IIT-JEE 2010 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 11 English

21

In the reaction

IIT-JEE 2010 Paper 1 Offline Chemistry - Alcohols, Phenols and Ethers Question 8 English

The intermediate(s) is(are)

22

Partial roasting of chalcopyrite produces

23

Iron is removed from chalcopyrite as

24

In self-reduction, the reducing species is

25

The total number of basic groups in the following form of lysine is

IIT-JEE 2010 Paper 1 Offline Chemistry - Biomolecules Question 5 English

26

In the scheme given below, the total number of intra molecular aldol condensation products formed from Y is ____________.

IIT-JEE 2010 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 22 English

27

Amongst the following, the total number of compounds soluble in aqueous NaOH is _________.

IIT-JEE 2010 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 21 English

28

The value of $$n$$ in the molecular formula $$\mathrm{Be_n Al_2Si_6O_{18}}$$ is ___________.

Mathematics

1
The number of values of $$\theta $$ in the interval, $$\left( { - {\pi \over 2},\,{\pi \over 2}} \right)$$ such that$$\,\theta \ne {{n\pi } \over 5}$$ for $$n = 0,\, \pm 1,\, \pm 2$$ and $$\tan \,\theta = \cot \,5\theta \,$$ as well as $$\sin \,2\theta = \cos \,4 \theta $$ is
2
The number of all possible values of $$\theta $$ where $$0 < \theta < \pi ,$$ for which the system of equations $$$\left( {y + z} \right)\cos {\mkern 1mu} 3\theta = \left( {xyz} \right){\mkern 1mu} \sin 3\theta $$$ $$$x\sin 3\theta = {{2\cos 3\theta } \over y} + {{2\sin 3\theta } \over z}$$$ $$$\left( {xyz} \right){\mkern 1mu} \sin 3\theta = \left( {y + 2z} \right){\mkern 1mu} \cos 3\theta + y{\mkern 1mu} sin3\theta $$$

have a solution $$\left( {{x_0},{y_0},{z_0}} \right)$$ with $${y_0}{z_0}{\mkern 1mu} \ne {\mkern 1mu} 0,$$ is

3
The maximum value of the expression $${1 \over {{{\sin }^2}\theta + 3\sin \theta \cos \theta + 5{{\cos }^2}\theta }}$$ is
4
Let $${{z_1}}$$ and $${{z_2}}$$ be two distinct complex number and let z =( 1 - t)$${{z_1}}$$ + t$${{z_2}}$$ for some real number t with 0 < t < 1. IfArg (w) denote the principal argument of a non-zero complex number w, then
5
Let $$p$$ and $$q$$ be real numbers such that $$p \ne 0,\,{p^3} \ne q$$ and $${p^3} \ne - q.$$ If $${p^3} \ne - q.$$ and $$\,\beta $$ are nonzero complex numbers satisfying $$\alpha \, + \beta = - p\,$$ and $${\alpha ^3} + {\beta ^3} = q,$$ then a quadratic equation having $${\alpha \over \beta }$$ and $${\beta \over \alpha }$$ as its roots is
6
Let $${S_k}$$= 1, 2,....., 100, denote the sum of the infinite geometric series whose first term is $$\,{{k - 1} \over {k\,!}}$$ and the common ratio is $${1 \over k}$$. Then the value of $${{{{100}^2}} \over {100!}}\,\, + \,\,\sum\limits_{k = 1}^{100} {\left| {({k^2} - 3k + 1)\,\,{S_k}} \right|\,\,} $$ is
7
Let $$A$$ and $$B$$ be two distinct points on the parabola $${y^2} = 4x$$. If the axis of the parabola touches a circle of radius $$r$$ having $$AB$$ as its diameter, then the slope of the line joining $$A$$ and $$B$$ can be
8
The circle $${x^2} + {y^2} - 8x = 0$$ and hyperbola $${{{x^2}} \over 9} - {{{y^2}} \over 4} = 1$$ intersect at the points $$A$$ and $$B$$.

Equation of a common tangent with positive slope to the circle as well as to the hyperbola is

9
The circle $${x^2} + {y^2} - 8x = 0$$ and hyperbola $${{{x^2}} \over 9} - {{{y^2}} \over 4} = 1$$ intersect at the points $$A$$ and $$B$$.

Equation of the circle with $$AB$$ as its diameter is

10

The line $$2x + y = 1$$ is tangent to the hyperbola $${{{x^2}} \over {{a^2}}} - {{{y^2}} \over {{b^2}}} = 1$$.

If this line passes through the point of intersection of the nearest directrix and the $$x$$-axis, then the eccentricity of the hyperbola is

11
If the angles $$A, B$$ and $$C$$ of a triangle are in an arithmetic progression and if $$a, b$$ and $$c$$ denote the lengths of the sides opposite to $$A, B$$ and $$C$$ respectively, then the value of the expression $${a \over c}\sin 2C + {c \over a}\sin 2A$$ is
12
Let $$f$$ be a real-valued differentiable function on $$R$$ (the set of all real numbers) such that $$f(1)=1$$. If the $$y$$-intercept of the tangent at any point $$P(x,y)$$ on the curve $$y=f(x)$$ is equal to the cube of the abscissa of $$P$$, then find the value of $$f(-3)$$
13
If the distance between the plane $$Ax-2y+z=d$$ and the plane containing the lines $${{x - 1} \over 2} = {{y - 2} \over 3} = {{z - 3} \over 4}$$ and $${{x - 2} \over 3} = {{y - 3} \over 4} = {{z - 4} \over 5}\,$$ is $$\sqrt 6 \,\,,$$ then $$\left| d \right|$$ is ___________.
14
If $$\overrightarrow a $$ and $$\overrightarrow b $$ are vectors in space given by $$\overrightarrow a = {{\widehat i - 2\widehat j} \over {\sqrt 5 }}$$ and $$\overrightarrow b = {{2\widehat i + \widehat j + 3\widehat k} \over {\sqrt {14} }},$$ then find the value of $$\,\left( {2\overrightarrow a + \overrightarrow b } \right).\left[ {\left( {\overrightarrow a \times \overrightarrow b } \right) \times \left( {\overrightarrow a - 2\overrightarrow b } \right)} \right].$$
15
Equation of the plane containing the straight line $${x \over 2} = {y \over 3} = {z \over 4}$$ and perpendicular to the plane containing the straight lines $${x \over 3} = {y \over 4} = {z \over 2}$$ and $${x \over 4} = {y \over 2} = {z \over 3}$$ is
16
Let $$P,Q,R$$ and $$S$$ be the points on the plane with position vectors $${ - 2\widehat i - \widehat j,4\widehat i,3\widehat i + 3\widehat j}$$ and $${ - 3\widehat i + 2\widehat j}$$ respectively. The quadrilateral $$PQRS$$ must be a
17
Let $$\omega $$ be a complex cube root of unity with $$\omega \ne 1.$$ A fair die is thrown three times. If $${r_1},$$ $${r_2}$$ and $${r_3}$$ are the numbers obtained on the die, then the probability that $${\omega ^{{r_1}}} + {\omega ^{{r_2}}} + {\omega ^{{r_3}}} = 0$$ is
18
For any real number $$x,$$ let $$\left[ x \right]$$ denote the largest integer less than or equal to $$x.$$ Let $$f$$ be a real valued function defined on the interval $$\left[ { - 10,10} \right]$$ by $$$f\left( x \right) = \left\{ {\matrix{ {x - \left[ x \right]} & {if\left[ x \right]is\,odd,} \cr {1 + \left[ x \right] - x} & {if\left[ x \right]is\,even} \cr } } \right.$$$

Then the value of $${{{\pi ^2}} \over {10}}\int\limits_{ - 10}^{10} {f\left( x \right)\cos \,\pi x\,dx} $$ is

19
Let $$f$$ be a real-valued function defined on the interval $$\left( {0,\infty } \right)$$
by $$\,f\left( x \right) = \ln x + \int\limits_0^x {\sqrt {1 + \sin t\,} dt.} $$ then which of the following
statement(s) is (are) true?
20
The value of $$\int\limits_0^1 {{{{x^4}{{\left( {1 - x} \right)}^4}} \over {1 + {x^2}}}dx} $$ is (are)
21
The value of $$\mathop {\lim }\limits_{x \to 0} {1 \over {{x^3}}}\int\limits_0^x {{{t\ln \left( {1 + t} \right)} \over {{t^4} + 4}}} dt$$ is
22
Let $$ABC$$ be a triangle such that $$\angle ACB = {\pi \over 6}$$ and let $$a, b$$ and $$c$$ denote the lengths of the sides opposite to $$A$$, $$B$$ and $$C$$ respectively. The value(s) of $$x$$ for which $$a = {x^2} + x + 1,\,\,\,b = {x^2} - 1\,\,\,$$ and $$c = 2x + 1$$ is (are)
23

The number of $3 \times 3$ matrices A whose entries are either 0 or 1 and for which the system

$\mathrm{A}\left[\begin{array}{l}x \\ y \\ z\end{array}\right]=\left[\begin{array}{l}1 \\ 0 \\ 0\end{array}\right]$ has exactly two distinct solutions, is

24

Let $f, g$ and $h$ be real valued functions defined on the interval $[0,1]$ by

$f(x)=e^{x^2}+e^{-x^2}$,

$g(x)=x e^{x^2}+e^{-x^2}$

and $h(x)=x^2 e^{x^2}+e^{-x^2}$.

If $a, b$ and $c$ denote, respectively, the absolute maximum of $f, g$ and $h$ on $[0,1]$, then :

25

Let $z_1$ and $z_2$ be two distinct complex numbers let $z=(1-t) z_1+t z_2$ for some real number t with $0 < t < 1$.

If $\operatorname{Arg}(w)$ denotes the principal argument of a nonzero complex number $w$, then :

26
The number of $A$ in $T_p$ such that $A$ is either symmetric or skew-symmetric or both, and $\operatorname{det}(\mathrm{A}) \operatorname{divisible}$ by $p$ is :
27

The number of A in $\mathrm{T}_p$ such that the trace of A is not divisible by $p$ but $\operatorname{det}(\mathrm{A})$ is divisible by $p$ is

[Note : The trace of a matrix is the sum of its diagonal entries.]

28
The number of A in $\mathrm{T}_p$ such that $\operatorname{det}(\mathrm{A})$ is not divisible by $p$ is :

Physics

1
A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1 m and its crosssectional area is 4.9 $$ \times $$ 10-7 m2. If the mass is pulled a little in the vertically downward direction and released, it performs simple harmonic motion of angular frequency 140 rad s−1. If the Young’s modulus of the material of the wire is n $$ \times $$ 109 Nm-2, the value of n is
2

A block of mass m is on an inclined plane of angle θ. The coefficient of friction between the block and the plane is μ and tan θ > μ. The block is held stationary by applying a force P parallel to the plane. The direction of force pointing up the plane is taken to be positive. As P is varied from P1 = mg(sinθ − μ cosθ) to P2 = mg(sinθ + μ cosθ), the frictional force f versus P graph will look like

IIT-JEE 2010 Paper 1 Offline Physics - Laws of Motion Question 24 English
3
A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After their collision, the 1 kg mass reverses its direction and moves with a speed of 2 ms−1. Which of the following statement(s) is (are) correct for the system of these two masses?
4
A binary star consists of two stars A (mass 2.2Ms) and B (mass 11Ms), where Ms is the mass of the sun. They are separated by distance d and are rotating about their centre of mass, which is stationary. The ratio of the total angular momentum of the binary star to the angular momentum of star B about the centre of mass is
5
Gravitational acceleration on the surface of a planet is $${{\sqrt 6 } \over {11}}g$$, where $$g$$ is the gravitational acceleration on the surface of the earth. The average mass density of the planet is $${2 \over 3}$$ times that of the earth. If the escape speed on the surface of the earth is taken to be 11 kms-1, the escape speed on the surface of the planet in kms-1 will be
6
A real gas behaves like an ideal gas if its
7
Two spherical bodies A (radius 6 cm ) and B (radius 18 cm ) are at temperature T1 and T2, respectively. The maximum intensity in the emission spectrum of A is at 500 nm and in that of B is at 1500 nm. Considering them to be black bodies, what will be the ratio of the rate of total energy radiated by A to that of B?
8
A piece of ice (heat capacity = 2100 J kg-1 oC-1 and latent heat = 3.36 $$ \times $$ 105 J kg-1 ) of mass m grams is at - 5 oC at atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 gm of ice has melted. Assuming there is no other heat exchange in the process, the value of m is
9
A few electric field lines for a system of two charges $${Q_1}$$ and $${Q_2}$$ fixed at two different points on the $$x$$-axis are shown in the figure. These lines suggest that

IIT-JEE 2010 Paper 1 Offline Physics - Electrostatics Question 48 English
10
A student uses a simple pendulum of exactly 1m length to determine g, the acceleration due to gravity. He uses a stop watch with the least count of 1 sec for this and records 40 seconds for 20 oscillations. For this observation, which of the following statement(s) is (are) true?
11

Incandescent bulbs are designed by keeping in mind that the resistance of their filament increases with the increase in temperature. If at room temperature, 100, 60 and 40 W bulbs have filament resistances R100, R60 and R40 respectively, the relation between these resistances is

12

To verify Ohm's law, a student is provided with a test resitor RT, a high resistance R1, a small resistance R2, two identical galvanometers G1 and G2, and a variable voltage source V. The correct circuit to carry out the experiment is

13

An AC voltage source of variable angular frequency $$\omega$$ and fixed amplitude V0 is connected in series with a capacitance C and an electric bulb of resistance R (inductance zero). When $$\omega$$ is increased

14

A thin flexible wire of length L is connected to two adjacent fixed points and carries a current I in the clockwise direction, as shown in the figure. When the system is put in a uniform magnetic field of strength B going into the plane of the paper, the wire takes the shape of a circle. The tension in the wire is

IIT-JEE 2010 Paper 1 Offline Physics - Magnetism Question 12 English

15

A thin uniform annular disc (see figure) of mass M has outer radius 4R and inner radius 3R. The work required to take a unit mass from point P on its axis to infinity is

IIT-JEE 2010 Paper 1 Offline Physics - Gravitation Question 7 English

16

Consider a thin square sheet of side L and thickness, made of a material of resistivity $$\rho$$. The resistance between two opposite faces, shown by the shaded areas in the figure is

IIT-JEE 2010 Paper 1 Offline Physics - Current Electricity Question 10 English

17

One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as shown in the figure. Its pressure at A is P0. Choose the correct option(s) from the following:

IIT-JEE 2010 Paper 1 Offline Physics - Heat and Thermodynamics Question 20 English

18

A ray OP of monochromatic light is incident on the face AB of prism ABCD near vertex B at an incident angle of 60$$^\circ$$ (see figure). If the refractive index of the material of the prism is $$\sqrt3$$, which of the following is(are) correct?

IIT-JEE 2010 Paper 1 Offline Physics - Geometrical Optics Question 24 English

19

In the graph below, the resistance R of a superconductor is shown as a friction of its temperature T for two different magnetic fields B1 (solid line) and B2 (dashed line). If B2 is larger than B1 which of the following graphs shows the correct variation of R with T in these fields?

20

A superconductor has Tc(0) = 100 K. When a magnetic field of 7.5 T is applied, its Tc decreases to 75 K. For this material, one can definitely say that when

21

If the total energy of the particle is E, it will perform periodic motion only if

22

For periodic motion of small amplitude A, the time period T of this particle is proportional to

23

The acceleration of this particle for $$|x| > {X_0}$$ is

24

A stationary source is emitting sound at a fixed frequency f0, which is reflected by two cars approaching the source. The difference between the frequencies of sound reflected from the cars is 1.2% of f0. What is the difference in the speeds of the cars (in km per hour) to the nearest integer? The cars are moving at constant speeds much smaller than the speed of sound which is 330 ms$$-$$1.

25

The focal length of a thin biconvex lens is 20 cm. When an object is moved from a distance of 25 cm in front of it to 50 cm, the magnification of its image changes from m25 to m50. The ratio $${{{m_{25}}} \over {{m_{50}}}}$$ is __________.

26

An $$\alpha$$-particle and a proton are accelerated from the rest by a potential difference of 100 V. After this, their de Broglie wavelengths are $$\lambda$$$$\alpha$$ and $$\lambda$$p, respectively. The ratio $${{{\lambda _p}} \over {{\lambda _\alpha }}}$$, to the nearest integer, is _____________.

27

When two identical batteries of internal resistance 1 $$\Omega$$ each are connected in series across a resistor R, the rate of heat produced in R is J1. When the same batteries are connected in parallel across R, the rate is J2. If J1 = 2.25 J2, then the value of R in $$\Omega$$ is __________.

28

When two progressive waves $${y_1} = 4\sin (2x - 6t)$$ and $${y_2} = 3\sin \left( {2x - 6t - {\pi \over 2}} \right)$$ are superimposed, the amplitude of the resultant wave is __________.

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