The composition of a sample of Wustite is Fe_0.93O_1.00 what percentage of the iron is present in the form of Fe(III)?

The compound YBa₂Cu₃O₇, which shows superconductivity, has copper in oxidation state ______ assume that the rare earth element yttrium is in its usual +3 oxidation state.

8.0575 $$\times$$ 10^-2 kg of Glauber's salt is dissolved in water to obtain 1 dm³ of a solution of density 1077.2 kg.m^-3. Calculate the molarity, molality and mole fraction Na₂SO₄ in the solution.

The outermost electronic configuration of Cr is _______.

Find out the number of waves made by a Bohr electron in once complete revolution in its 3rd orbit?

The two types of bond present in B₂H₆ are covalent and _______.

Using the VSEPR theory, identify the type of hybridization and draw the structure of OF₂. What are the oxidation states of O and F?

An LPG (liquefied petroleum gas) cylinder weighs 14.8 kg when empty. When full, it weighs 29.0 kg and shows a pressure of 2.5 atm. In the course of use at 27^o C, the weight of the full cylinder reduces to 23.2 kg. Find out the volume of the gas in cubic meters used up at the normal usage conditions find the final pressure inside the cylinder. Assume LPG to be n-butane with normal boiling point of 0^o C.

A 4 : 1 molar mixture of He and CH₄ is contained in a vessel at 20 bar pressure. Due to a hole in the vessel the gas mixture leaks out. What is the composition of the mixture effusing out initially?

Complete and balance the following reactions:
Ca₅(PO₄)₃F + H₂SO₄ + H₂O $$\buildrel {Heat} \over \longrightarrow $$ ........ + 5CaSO₄.2H₂O + ........

Statement (S) The alkali metals can form ionic hydrides which contain the hydride ion H^-.
Explanation (E) The alkali metals have low electronegativity; their hydrides conduct electricity when fused and liberate hydrogen at the anode.

The IUPAC name of succinic acid is _______.

The Edison storage cells is represented as
Fe(s) | FeO(s) | KOH (aq) | Ni₂O₃(s) | Ni(s)
The half-cell reactions are:
Ni₂O₃ + H₂O (l) + 2e^- $$\leftrightharpoons$$ 2NiO(s) + 2OH^-; E^o = +0.40V
FeO(s) + H₂O(l) + 2e^- $$\leftrightharpoons$$ Fe(s) + 2OH^-; E^o = -0.87V
(i) What is the cell reaction?
(ii) What is the cell e.m.f? How does it depend on the concentration of KOH?
(iii) What is the maximum amount of electrical energy that can be obtained from one mole of Ni₂O₃?

The standard reduction potential of the Ag⁺/Ag electrode at 298 K is 0.799V. Given that for AgI, K_sp = 8.7 $$\times$$ 10^-17, evaluate the potential of the Ag⁺/Ag electrode in a saturated solution of AgI. Also calculate the standard reduction potential of the I^-/ AgI/Ag electrode.

A is binary compound of a univalent metal. 1.422 g of A reacts completely with 0.321 g of sulphur in an evacuated and sealed tube to give 1.743 g of a white crystalline solid B, that forms a hydrated double salt, C with Al₂ (SO₄)₃ . Identify A, B and C.

The circle $${x^2} + {y^2} = 1$$ cuts the $$x$$-axis at $$P$$ and $$Q$$. Another circle with centre at $$Q$$ and variable radius intersects the first circle at $$R$$ above the $$x$$-axis and the line segment $$PQ$$ at $$S$$. Find the maximum area of the triangle $$QSR$$.

Find the indefinite integral $$\,\int {\cos 2\theta {\mkern 1mu} ln\left( {{{\cos \theta + \sin \theta } \over {\cos \theta - \sin \theta }}} \right)} {\mkern 1mu} d\theta $$

The value of $$\int\limits_2^3 {{{\sqrt x } \over {\sqrt {3 - x} + \sqrt x }}} dx$$ is ...........

Show that $$\int\limits_0^{n\pi + v} {\left| {\sin x} \right|dx = 2n + 1 - \cos \,v} $$ where $$n$$ is a positive integer and $$\,0 \le v < \pi .$$

In what ratio does the $$x$$-axis divide the area of the region
bounded by the parabolas $$y = 4x - {x^2}$$ and $$y = {x^2} - x?$$

A normal is drawn at a point $$P(x,y)$$ of a curve. It meets the $$x$$-axis at $$Q.$$ If $$PQ$$ is of constant length $$k,$$ then show that the differential equation describing such curves is $$y = {{dy} \over {dx}} = \pm \sqrt {{k^2} - {y^2}} $$

Find the equation of such a curve passing through $$(0,k).$$

If two events $$A$$ and $$B$$ are such that $$P\,\,\left( {{A^c}} \right)\,\, = \,\,0.3,\,\,P\left( B \right) = 0.4$$ and $$P\left( {A \cap {B^c}} \right) = 0.5,$$ then $$P\left( {B/\left( {A \cup {B^c}} \right)} \right.$$$$\left. \, \right] = $$ ............

Let $$A, B, C$$ be three mutually independent events. Consider the two statements $${S_1}$$ and $${S_2}$$
$${S_1}\,:\,A$$ and $$B \cup C$$ are independent
$${S_2}\,:\,A$$ and $$B \cap C$$ are independent
Then,

An unbiased coin is tossed. If the result is a head, a pair of unbiased dice is rolled and the number obtained by adding the numbers on the two faces is noted. If the result is a tail, a card from a well shuffled pack of eleven cards numbered $$2, 3,4,.....12$$ is picked and the number on the card is noted. What is the probability that the noted number is either $$7$$ or $$8$$?

A unit vector perpendicular to the plane determined by the points $$P\left( {1, - 1,2} \right)Q\left( {2,0, - 1} \right)$$ and $$R\left( {0,2,1} \right)$$ is ............

Let $$\overrightarrow p $$ and $$\overrightarrow q $$ be the position vectors of $$P$$ and $$Q$$ respectively, with respect to $$O$$ and $$\left| {\overrightarrow p } \right| = p,\left| {\overrightarrow q } \right| = q.$$ The points $$R$$ and $$S$$ divide $$PQ$$ internally and externally in the ratio $$2:3$$ respectively. If $$OR$$ and $$OS$$ are perpendicular then

Let $$\alpha ,\beta ,\gamma $$ be distinct real numbers. The points with position
vectors $$\alpha \widehat i + \beta \widehat j + \gamma \widehat k,\,\,\beta \widehat i + \gamma \widehat j + \alpha \widehat k,\,\,\gamma \widehat i + \alpha \widehat j + \beta \widehat k$$

The vector $$\,{1 \over 3}\left( {2\widehat i - 2\widehat j + \widehat k} \right)$$ is

If the vectors $$\overrightarrow b ,\overrightarrow c ,\overrightarrow d ,$$ are not coplanar, then prove that the vector
$$\left( {\overrightarrow a \times \overrightarrow b } \right) \times \left( {\overrightarrow c \times \overrightarrow d } \right) + \left( {\overrightarrow a \times \overrightarrow c } \right) \times \left( {\overrightarrow d \times \overrightarrow b } \right) + \left( {\overrightarrow a \times \overrightarrow d } \right) \times \left( {\overrightarrow b \times \overrightarrow c } \right)$$ is parallel to $$\overrightarrow a .$$

Let $$n$$ be a positive integer such that $$\sin {\pi \over {2n}} + \cos {\pi \over {2n}} = {{\sqrt n } \over 2}.$$ Then

Which one of the following curves cut the parabola $${y^2} = 4ax$$ at right angles?

Let $$0 < x < {\pi \over 4}$$ then $$\left( {\sec 2x - \tan 2x} \right)$$ equals

If $$\omega \,$$ is an imaginary cube root of unity then the value of $$\sin \left\{ {\left( {{\omega ^{10}} + {\omega ^{23}}} \right)\pi - {\pi \over 4}} \right\}$$ is

Suppose Z₁, Z₂, Z₃ are the vertices of an equilateral triangle inscribed in the circle $$\left| Z \right| = 2.$$ If Z₁ = $$1 + i\sqrt 3 $$ then Z2 = ......., Z₃ =..............

Let $$2{\sin ^2}x + 3\sin x - 2 > 0$$ and $${x^2} - x - 2 < 0$$ ($$x$$ is measured in radians). Then $$x$$ lies in the interval

The number of points of intersection of two curves y = 2 sin x and y $$ = 5{x^2} + 2x + 3$$ is

If p, q, r are + ve and are on A.P., the roots of quadratic equation $$p{x^2} + qx + r = 0$$ are all real for

Let $$p,q \in \left\{ {1,2,3,4} \right\}\,$$. The number of equations of the form $$p{x^2} + qx + 1 = 0$$ having real roots is

Let $$n$$ be positive integer. If the coefficients of 2nd, 3rd, and 4th terms in the expansion of $${\left( {1 + x} \right)^n}$$ are in A.P., then the value of $$n$$ is ................

If $$x$$ is not an integral multiple of $$2\pi $$ use mathematical induction to prove that : $$$\cos x + \cos 2x + .......... + \cos nx = \cos {{n + 1} \over 2}x\sin {{nx} \over 2}\cos ec{x \over 2}$$$

Let $$n$$ be a positive integer and $${\left( {1 + x + {x^2}} \right)^n} = {a_0} + {a_1}x + ............ + {a_{2n}}{x^{2n}}$$
Show that $$a_0^2 - a_1^2 + a_2^2...... + {a_{2n}}{}^2 = {a_n}$$

A committee of 12 is to be formed from 9 women and 8 men. In how many ways this can be done if at least five women have to included in a committee? In how many of these committees? In how may of these committees
(a) The women are in majority?
(b) The men are in majority?

If $$In\left( {a + c} \right),In\left( {a - c} \right),In\left( {a - 2b + c} \right)$$ are in A.P., then

The locus of a variable point whose distance from $$\left( { - 2,\,0} \right)$$ is $$2/3$$ times its distance from the line $$x = - {9 \over 2}$$ is

The equations to a pair of opposites sides of parallelogram are $${x^2} - 5x + 6 = 0$$ and $${y^2} - 6y + 5 = 0,$$ the equations to its diagonals are

The circles $${x^2} + {y^2} - 10x + 16 = 0$$ and $${x^2} + {y^2} = {r^2}$$ intersect each other in two distinct points if

The equation $$2{x^2} + 3{y^2} - 8x - 18y + 35 = k$$ represents

The curve $$y = a{x^3} + b{x^2} + cx + 5$$, touches the $$x$$-axis at $$P(-2, 0)$$ and cuts the $$y$$ axis at a point $$Q$$, where its gradient is $$3$$. Find $$a, b, c$$.

The function defined by $$f\left( x \right) = \left( {x + 2} \right){e^{ - x}}$$

Let $$P$$ be a variable point on the ellipse $${{{x^2}} \over {{a^2}}} + {{{y^2}} \over {{b^2}}} = 1$$ with foci $${F_1}$$ and $${F_2}$$. If $$A$$ is the area of the triangle $$P{F_1}{F_2}$$ then the maximum value of $$A$$ is ..........

Let $$C$$ be the curve $${y^3} - 3xy + 2 = 0$$. If $$H$$ is the set of points on the curve $$C$$ where the tangent is horizontal and $$V$$ is the set of the point on the curve $$C$$ where the tangent is vertical then $$H=$$.............. and $$V=$$ .................

If we consider only the principle values of the inverse trigonometric functions then the value of
$$\tan \left( {{{\cos }^{ - 1}}{1 \over {5\sqrt 2 }} - {{\sin }^{ - 1}}{4 \over {\sqrt {17} }}} \right)$$ is

A tower $$AB$$ leans towards west making an angle $$\alpha $$ with the vertical. The angular elevation of $$B$$, the topmost point of the tower is $$\beta $$ as observed from a point $$C$$ due west of $$A$$ at a distance $$d$$ from $$A$$. If the angular elevation of $$B$$ from a point $$D$$ due east of $$C$$ at a distance $$2d$$ from $$C$$ is $$\gamma $$, then prove that $$2$$ tan $$\alpha = - \cot \beta + \cot \gamma $$.

Consider the following statements connecting a triangle $$ABC$$

(i) The sides $$a, b, c$$ and area $$\Delta $$ are rational.

(ii) $$a,\tan {B \over 2},\tan {c \over 2}$$ are rational.

(iii) $$a,\sin A,\sin B,\sin C$$ are rational.
Prove that $$\left( i \right) \Rightarrow \left( {ii} \right) \Rightarrow \left( {iii} \right) \Rightarrow \left( i \right)$$

Let $${A_1},{A_2},........,{A_n}$$ be the vertices of an $$n$$-sided regular polygon such that $${1 \over {{A_1}{A_2}}} = {1 \over {{A_1}{A_3}}} + {1 \over {{A_1}{A_4}}}$$, Find the value of $$n$$.

If the lengths of the sides of triangle are $$3, 5, 7$$ then the largest angle of the triangle is

A circle is inscribed in an equilateral triangle of side $$a$$. The area of any square inscribed in this circle is ..............

In a triangle $$ABC$$, $$AD$$ is the altitude from $$A$$. Given $$b>c$$, $$\angle C = {23^ \circ }$$ and $$AD = {{abc} \over {{b^2} - {c^2}}}$$ then $$\angle B = $$.................

If $$y = {\left( {\sin x} \right)^{\tan x}},$$ then $${{dy} \over {dx}}$$ is equal to

Through the vertex $$O$$ of parabola $${y^2} = 4x$$, chords $$OP$$ and $$OQ$$ are drawn at right angles to one another . Show that for all positions of $$P$$, $$PQ$$ cuts the axis of the parabola at a fixed point. Also find the locus of the middle point of $$PQ$$.

Let $$E$$ be the ellipse $${{{x^2}} \over 9} + {{{y^2}} \over 4} = 1$$ and $$C$$ be the circle $${x^2} + {y^2} = 9$$. Let $$P$$ and $$Q$$ be the points $$(1, 2)$$ and $$(2, 1)$$ respectively. Then

The point of intersection of the tangents at the ends of the latus rectum of the parabola $${y^2} = 4x$$ is ...... .

A block of mass 0.1 is held against a wall applying a horizontal force of 5 N on the block. If the coefficient of friction between the block and the wall is 0.5, the magnitude of the frictional force acting on the block is:

A particle of mass m is moving in a circular path of constant radius r such that its centripetal acceleration $${a_c}$$ is varying with time t as $${a_c}$$ = k²rt² where k is a constant. The power delivered to the perticles by the force acting on it is:

An object of mass 0.2 kg executes simple harmonic oscillation along the x-axis with a frequency of $$\left( {{{25} \over \pi }} \right)$$ Hz. At the position x = 0.04, the object has kinetic energy of 0.5 J and potential energy 0.4 J. The amplitude of oscillations is ................ m.