IIT-JEE 1986
Paper was held on Fri, Apr 11, 1986 9:00 AM
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Chemistry

1
The bond between two identical non-metal atoms has a pair of electrons
2
A molal solution is one that contains one mole of solute in
3
Complete and balance the following equation:

S + OH- $$\to$$ S2- + $$S_2O_3^-$$
4
Complete and balance the following equation:

Ag+ + AsH3 $$\to$$ H3AsO3 + H+
5
Complete and balance the following equation:

Mn2+ + PbO2 $$\to$$ $$MnO_4^-$$ + H2O
6
Complete and balance the following equation:

$$ClO_3^-$$ + I- + H2SO4 $$\to$$ Cl- + $$HSO_4^-$$
7
Arrange the following in increasing oxidation number of iodine.

I2, HI, HIO4, ICl
8
The electron density in the XY plane in 3dx2 - y2 orbital is zero
9
Rutherford's alpha particle scattering experiment eventually led to the conclusion that:
10
Which one of the following sets of quantum numbers represents an impossible arrangement?
11
The ratio of the energy of a photon of 2000Å wavelength to that 4000Å radiation is
12
The sum of the number of neutrons and proton in the isotope of hydrogen is
13
Arrange the following in:
Increasing size:
Cl-, S2-, Ca2+, Ar
14
The hydrogen bond is strongest in
15
The hybridisation of sulphur in sulphur dioxide is
16
CO2 is isostructural with
17
Write the lewis dot structure of the following:
O3, COCl2
18
The rate of diffusion of gas is _______ proportional to both ________ and square root of molecular mass.
19
The average velocity of an ideal gas molecule at 27oC is 0.3m/sec. The average velocity at 927oC will be
20
The softness of group I-A metals increases down the group with increasing atomic number.
21
The pair of compound which cannot exist together in solution is:
22
Give reasons of the following:
Hydrogen peroxide is a better oxidising agent than water.
23
Write the IUPAC name of :
CH3CH2CH = CHCOOH
24
The vapour pressure of ethanol and methanol are 44.5 and 88.7 mm Hg respectively. An ideal solution is formed at the same temperature by mixing 60 g of ethanol with 40 g of methanol. Calculate the total vapour pressure of the solution and the mole fraction of methanol in the vapour.

Mathematics

1
The position vectors of the points $$A, B, C$$ and $$D$$ are $$3\widehat i - 2\widehat j - \widehat k,\,2\widehat i + 3\widehat j - 4\widehat k,\, - \widehat i + \widehat j + 2\widehat k$$ and $$4\widehat i + 5\widehat j + \lambda \widehat k,$$
respectively. If the points $$A, B, C$$ and $$D$$ lie on a plane, find the value of $$\lambda .$$
2
Let $$\overrightarrow a = {a_1}i + {a_2}j + {a_3}k,\,\,\,\overrightarrow b = {b_1}i + {b_2}j + {b_3}k$$ and $$\overrightarrow c = {c_1}i + {c_2}j + {c_3}k$$ be three non-zero vectors such that $$\overrightarrow c $$ is a unit vector perpendicular to both the vectors $$\overrightarrow a $$ and $$\overrightarrow b .$$ If the angle between $$\overrightarrow a $$ and $$\overrightarrow b $$ is $${\pi \over 6},$$ then
$${\left| {\matrix{ {{a_1}} & {{a_2}} & {{a_3}} \cr {{b_1}} & {{b_2}} & {{b_3}} \cr {{c_1}} & {{c_2}} & {{c_3}} \cr } } \right|^2}$$ is equal to
3
From the point A(0, 3) on the circle $${x^2} + 4x + {(y - 3)^2} = 0$$, a chord AB is drawn and extended to a point M such that AM = 2AB. The equation of the locus of M is..........................
4
The expression $$2\left[ {{{\sin }^6}\left( {{\pi \over 2} + \alpha } \right) + {{\sin }^6}\left( {5\pi - \alpha } \right)} \right]$$ is equal to
5
Show that the area of the triangle on the Argand diagram formed by the complex numbers z, iz and z + iz is $${1 \over 2}\,{\left| z \right|^2}$$ .
6
If $$S$$ is the set of all real $$x$$ such that $${{2x - 1} \over {2{x^3} + 3{x^2} + x}}$$ is positive, then $$S$$ contains
7
If $$a,\,b$$ and $$c$$ are distinct positive numbers, then the expression
$$\left( {b + c - a} \right)\left( {c + a - b} \right)\left( {a + b - c} \right) - abc$$ is
8
For $$a \le 0,$$ determine all real roots of the equation $$${x^2} - 2a\left| {x - a} \right| - 3{a^2} = 0$$$
9
If the quadratic equations $${x^2} + ax + b = 0$$ and $${x^2} + bx + a = 0$$ $$(a \ne b)$$ have a common root, then the numerical value of a + b is..........................
10
The solution of equation $${\log _7}\,{\log _5}\,\left( {\sqrt {x + 5} + \sqrt x } \right) = 0$$ is ........................
11
If $${C_r}$$ stands for $${}^n{C_r},$$ then the sum of the series $${{2\left( {{n \over 2}} \right){\mkern 1mu} !{\mkern 1mu} \left( {{n \over 2}} \right){\mkern 1mu} !} \over {n!}}\left[ {C_0^2 - 2C_1^2 + 3C_2^2 - } \right......... + {\left( { - 1} \right)^n}\left( {n + 1} \right)C_n^2\mathop ]\limits^ \sim \,,$$
where $$n$$ is an even positive integer, is equal to
12
A box contains two white balls, three black balls and four red balls. In how many ways can three balls be drawn from the box if at least one black ball is to be included in the draw?
13
The solution of the equation $$lo{g_7}$$ $$lo{g_5}$$ $$\left( {\sqrt {x + 5} + \sqrt x } \right) = 0$$ is .............
14
The points $$\left( {0,{8 \over 3}} \right),\,\,\left( {1,\,3} \right)$$ and $$\left( {82,\,30} \right)$$ are vertices of
15
All points lying inside the triangle formed by the points $$\left( {1,\,3} \right),\,\left( {5,\,0} \right)$$ and $$\left( { - 1,\,2} \right)$$ satisfy
16
A vector $$\overline a $$ has components $$2p$$ and $$1$$ with respect to a rectangular cartesian system. This system is rotated through a certain angle about the origin in the counter clockwise sense. If, with respect to the new system, $$\overline a $$ has components $$p + 1$$ and $$1$$, then
17
Let $${z_1}$$ and $${z_2}$$ be complex numbers such that $${z_1}$$ $$ \ne $$ $${z_2}$$ and $$\left| {{z_1}} \right| =\,\left| {{z_2}} \right|$$. If $${z_1}$$ has positive real and $${z_2}$$ has negative imaginary part, then $${{{z_1}\, + \,{z_2}} \over {{z_1}\, - \,{z_2}}}$$ may be
18
The equation of the line passing through the points of intersection of the circles $$3{x^2} + 3{y^2} - 2x + 12y - 9 = 0$$ and $${x^2} + {y^2} - 6x + 2y - 15 = 0$$ is..............................
19
Lines 5x + 12y - 10 = 0 and 5x - 12y - 40 = 0 touch a circle $$C_1$$ of diameter 6. If the centre of $$C_1$$ lies in the first quadrant, find the equation of the circle $$C_2$$ which is concentric with $$C_1$$ and cuts intercepts of length 8 on these lines.
20
The derivative of $${\sec ^{ - 1}}\left( {{1 \over {2{x^2} - 1}}} \right)$$ with respect to $$\sqrt {1 - {x^2}} $$ at $$x = {1 \over 2}$$ is ...............
21
There exists a triangle $$ABC$$ satisfying the conditions
22
If in a triangle $$ABC$$, $$\cos A\cos B + \sin A\sin B\sin C = 1,$$ Show that $$a:b:c = 1:1:\sqrt 2 $$
23
The principal value of $${\sin ^{ - 1}}\left( {\sin {{2\pi } \over 3}} \right)$$ is
24
Let $$P\left( x \right) = {a_0} + {a_1}{x^2} + {a_2}{x^4} + ...... + {a_n}{x^{2n}}$$ be a polynomial in a real variable $$x$$ with
$$0 < {a_0} < {a_1} < {a_2} < ..... < {a_n}.$$ The function $$P(x)$$ has
25
If the line $$ax+by+c=0$$ is a normal to the curve $$xy=1$$, then
26
Evaluate : $$\int\limits_0^\pi {{{x\,dx} \over {1 + \cos \,\alpha \,\sin x}},0 < \alpha < \pi } $$
27
If $${{1 + 3p} \over 3},\,\,\,{{1 - p} \over 4}$$ and $$\,{{1 - 2p} \over 2}$$ are the probabilities of three mutually exclusive events, then the set of all values of $$p$$ is ..............
28
A student appears for tests, $$I$$, $$II$$ and $$III$$. The student is successful if he passes either in tests $$I$$ and $$II$$ or tests $$I$$ and $$III$$. The probabilities of student passing in tests $$I$$, $$II$$ and $$III$$ are $$p, q$$ and $${1 \over 2}$$ respectively. If the probability that the student is successful is $${1 \over 2}$$, then
29
The probability that at least one of the events $$A$$ and $$B$$ occurs is $$0.6$$. If $$A$$ and $$B$$ occur simultaneously with probability $$0.2,$$ then $$P\left( {\overline A } \right) + P\left( {\overline B } \right)$$ is
30
A lot contains $$20$$ articles. The probability that the lot contains exactly $$2$$ defective articles is $$0.4$$ and the probability that the lot contains exactly $$3$$ defective articles is $$0.6$$. Articles are drawn from the lot at random one by one without replacement and are tested till all defective articles are found. What is the probability that the testing procedure ends at the twelth testing.

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