For a first order reaction $$A\left( g \right) \to 2B\left( g \right) + C\left( g \right)$$ at constant volume and $$300K,$$ the total pressure at the beginning $$(t=0)$$ and at time $$t$$ are $${P_0}$$ and $${P_1},$$ respectively. Initially, only $$A$$ is present with concentration $${\left[ A \right]_0},$$ and $${t_{1/3}}$$ is the time required for the partial pressure of $$A$$ to reach $$1/{3^{rd}}$$ of its initial value. The correct option(s) is (are) (Assume that all these gases behave as ideal gases)

Match each set of hybrid orbitals from LIST - A with complex(es) given in LIST - B

	List - A			List - B
P.	dsp2		1.	[FeF6]4-
Q.	sp3		2.	[Ti(H2O)3Cl3]
R.	sp3d2		3.	[Cr(NH3)6]3+
S.	d2sp3		4.	[FeCl4]2-
			5.	Ni(CO)4
			6.	[Ni(CN)4]2-

The correct option is

Consider the following reversible reaction, $$A\left( g \right) + B\left( g \right) \to AB\left( g \right).$$

The activation energy of the backward reaction exceeds that of the forward reaction by $$2RT$$ (in $$J\,mo{l^{ - 1}}$$). If the pre-exponential factor of the forward reaction is $$4$$ times that of the reverse reaction, the absolute value of $$\Delta {G^ \circ }$$ (in $$J\,mo{l^{ - 1}}$$ ) for the reaction at $$300$$ $$K$$ is ____________.

(Given; $$\ln \left( 2 \right) = 0.7,RT = 2500$$ $$J\,mo{l^{ - 1}}$$ at $$300$$ $$K$$ and $$G$$ is the Gibbs energy)

Consider an electrochemical cell :

$$A\left( s \right)\left| {{A^{n + }}\left( {aq,2M} \right)} \right|{B^{2n + }}\left( {aq,1M} \right)\left| {B\left( s \right).} \right.$$

The value of $$\Delta {H^ \circ }$$ for the cell reaction is twice that of $$\Delta {G^ \circ }$$ at $$300$$ $$K.$$ If the $$emf$$ of the cell is zero, the $$\Delta {S^ \circ }$$ (in $$J\,{K^{ - 1}}mo{l^{ - 1}}$$) of the cell reaction per mole of $$B$$ formed at $$300$$ $$K$$ is ___________.

(Given: $$\ln \left( 2 \right) = 0.7,R$$ (universal gas constant) $$ = 8.3J\,{K^{ - 1}}\,mo{l^{ - 1}}.$$ $$H,S$$ and $$G$$ are enthalpy, entropy and Gibbs energy, respectively.)