1
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Among the following metal carbonyl, the C-O bond order is lowest in

A
$$\mathrm{[Mn(CO)_6]^+}$$
B
$$\mathrm{[Fe(CO)_5]}$$
C
$$\mathrm{[Cr(CO)_6]}$$
D
$$\mathrm{[V(CO)_6]^-}$$
2
IIT-JEE 2007 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

Match the complexes in Column I with their properties listed in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) $$\mathrm{[Co(NH_3)_4(H_2O)_2]Cl_2}$$ (P) geometrical isomers
(B) $$\mathrm{[Pt(NH_3)_2Cl_2]}$$ (Q) paramagnetic
(C) $$\mathrm{[Co(H_2O)_5Cl]Cl}$$ (R) diamagnetic
(D) $$\mathrm{[Ni(H_2O)_6]Cl_2}$$ (S) metal ion with +2 oxidation state

A
A - (p, q, s); B - (p, r, s); C - (q, s); D - (q, s)
B
A - (q, s); B - (p, r, s); C - (q); D - (q, s)
C
A - (p, q, s); B - (p, r, s); C - (q); D - (s)
D
A - (p, q, s); B - (s); C - (q, s); D - (q)
3
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

The coordination of $$\mathrm{Ni^2+}$$ is 4.

$$\mathrm{NiCl_2+KCN}$$ (excess) $$\to$$ A (cyano complex)

$$\mathrm{NiCl_2+ conc.~HCl}$$ (excess) $$\to$$ B (chloro complex)

The IUPAC names of $$\mathbf{A}$$ and $$\mathbf{B}$$ are

A
Potassium tetracyanonickelate (II), potassium tetrachloronickelate (II).
B
Tetracyanopotassiumnickelate (II), teterachloroptassiumnickelate (II).
C
Tetracyanonickel (II), tetrachloronickel (II).
D
Potassium tetracyanonickel (II), potassium tetrachloronickel (II).
4
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

The coordination of $$\mathrm{Ni^2+}$$ is 4.

$$\mathrm{NiCl_2+KCN}$$ (excess) $$\to$$ A (cyano complex)

$$\mathrm{NiCl_2+ conc.~HCl}$$ (excess) $$\to$$ B (chloro complex)

Predict the magnetic nature of $\mathbf{A}$ and $\mathbf{B}$.

A

Both are diamagnetic.

B

A is diamagnetic and B is paramagnetic with one unpaired electron.

C

A is diamagnetic and B is paramagnetic with two unpaired electrons.

D

Both are paramagnetic.

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