Coordination Compounds · Chemistry · JEE Advanced

Among $\mathrm{V}(\mathrm{CO})_6, \mathrm{Cr}(\mathrm{CO})_5, \mathrm{Cu}(\mathrm{CO})_3, \mathrm{Mn}(\mathrm{CO})_5, \mathrm{Fe}(\mathrm{CO})_5,\left[\mathrm{Co}(\mathrm{CO})_3\right]^{3-},\left[\mathrm{Cr}(\mathrm{CO})_4\right]^{4-}$, and $\operatorname{Ir}(\mathrm{CO})_3$, the total number of species isoelectronic with $\mathrm{Ni}(\mathrm{CO})_4$ is _________.

[Given, atomic number: $\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27, \mathrm{Ni}=28, \mathrm{Cu}=29, \mathrm{Ir}=77$ ]

Among the following complexes, the total number of diamagnetic species is ___________.

$\left[\mathrm{Mn}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{MnCl}_6\right]^{3-},\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+}$, and $\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$

[Given, atomic number: $\mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$;

$$ \text { en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right] $$

In the complex acetylbromidodicarbonylbis(triethylphosphine) iron(II), the number of Fe-C bond(s) is ___________.

Among the complex ions, [Co(NH₂-CH₂-CH₂-NH₂)₂Cl₂]⁺, [CrCl₂(C₂O₄)₂]^3$$-$$, [Fe(H₂O)₄)OH)₂]⁺, [Fe(NH₃)₂(CN)₄]^$$-$$, [Co(NH₂-CH₂-CH₂-NH₂)₂(NH₃)Cl]²⁺ and [Co(NH₃)₄(H₂O)Cl]²⁺, the number of complex ions that shows cis-trans isomerism is ______________.

For the octahedral complexes of Fe³⁺ in SCN^$$-$$ (thiocyana-to-S) and in CN^$$-$$ ligand environments, the difference between the spin-only magnetic moments in Bohr magnetons (when approximated to the nearest integer) is __________.

[Atomic number Fe = 26]

EDTA^4$$-$$ is ethylenediaminetetraacetate ion. The total number of N$$-$$Co$$-$$O bond angles in [Co(EDTA)]^1$$-$$ complex ion is ________.

The number of water molecule(s) directly bonded to the centre in CuSO$$_4$$ . 5H$$_2$$O is __________.

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.

$$ \text { [en }=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2 \text { ] } $$

LIST-I contains metal species and LIST-II contains their properties.

[Given: Atomic number of $\mathrm{Cr}=24, \mathrm{Ru}=44, \mathrm{Fe}=26$ ]

Match each metal species in LIST-I with their properties in LIST-II, and choose the correct option

Among [Ni(CO)₄], [NiCl₄]^2$$-$$, [Co(NH₃)₄)Cl₂]Cl, Na₃[CoF₆], Na₂O₂ and CsO₂, the total number of paramagnetic compound is

Match each coordination compound in List I with an appropriate pair of characteristics from List II and select the correct answer using the code given below the lists.

{en = H₂NCH₂CH₂NH₂; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}

Consider the following complex ions : P, Q and R.

$$P = {[Fe{F_6}]^{3 - }}$$, $$Q = {[V{({H_2}O)_6}]^{2 + }}$$ and $$R = {[Fe{({H_2}O)_6}]^{2 + }}$$

The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

$$NiC{l_2}{\{ P{({C_2}{H_5})_2}({C_6}{H_5})\} _2}$$ exhibits temperature-dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni²⁺ in the paramagnetic and diamagnetic states are, respectively,

As per IUPAC nomenclature, the name of the complex $$[Co{({H_2}O)_4}{(N{H_3})_2}]C{l_3}$$ is

Among the following complexes (K-P),

K₃[Fe(CN)₆] (K), [Co(NH₃)₆]Cl₃ (L), Na₃[Co(oxalate)₃] (M), [Ni(H₂O)₃]Cl₂ (N), K₂[Pt(CN)₄] (O) and [Zn(H₂O)₆(NO₃)₂] (P)

The diamagnetic complexes are

The correct structure of ethylenediaminetetraacetic acid (EDTA) is

The ionisation isomer of $$\mathrm{[Cr(H_2O)_4Cl(NO_2)]Cl}$$ is

The spin only magnetic moment value (in Bohr magneton units) of Cr(CO)$$_6$$ is

Among the following, the coloured compound is :

Both [Ni(CO)$$_4$$] and [Ni(CN)$$_4$$]$$^{2-}$$ are diamagnetic. They hybridisations of nickel in these complexes, respectively, are :

The IUPAC name of [Ni(NH$$_3$$)$$_4$$] [NiCl$$_4$$] is :

Statement 1 : [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ is paramagnetic.

Statement 2 : The Fe in [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ has three unpaired electrons.

Statement 1 : The geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] are optically inactive.

Statement 2 : Both geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] possess axis of symmetry.

The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is(are)

The compound(s) that exhibit(s) geometrical isomerism is(are)