Numerical
An aqueous solution is prepared by dissolving $0.1 \mathrm{~mol}$ of an ionic salt in $1.8 \mathrm{~kg}$ of water at $35^{\circ} \mathrm{C}$. The salt...
The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x$$^\circ$$C. To this solution A, an equal volume of 0.1 molal aqueo...
The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x$$^\circ$$C. To this solution A, an equal volume of 0.1 molal aqueo...
Liquids A and B form ideal solution for all compositions of A and B at 25$$^\circ $$C. Two such solutions with 0.25 and 0.50 mole fractions of A have ...
On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapor pressure decreases from 650 mmHg to 640 mmHg. The depression of f...
Liquids A and B form ideal solution over the entire range of composition. At temperature $$T,$$ equimolar binary solution of liquids $$A$$ and $$B$$ ...
The plot given below shows $$P-T$$ curves (where $$P$$ is the pressure and $$T$$ is the temperature) for two solvents $$X$$ and $$Y$$ and isomolal sol...
The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as its
molality. Density of this solution at 298 K...
MX2 dissociates in M2+ and X- ions in an aqueous solution, with a degree of dissociation ($$\alpha$$) of 0.5. The
ratio of the observed depression of ...
A compound H2X with molar weight of 80g is dissolved in a solvent having density of 0.4 gml–1 . Assuming no change in volume upon dissolution, the mol...
75.2 g of C6H5OH (phenol) is dissolved in a solvent of Kf = 14. If the depression in freezing point is 7 K then find the % of phenol that dimerises....
MCQ (Single Correct Answer)
Pure water freezes at $$273$$ $$K$$ and $$1$$ bar. The addition of $$34.5$$ $$g$$ of ethanol to $$500$$ $$g$$ of water changes the freezing point of t...
The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions...
For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water. the elevation in boiling point at 1 atm pressure is...
The freezing point (in oC) of a solution containing 0.1 g of K3[Fe(CN)6] (Mol. wt. 329) in 100 g of water (Kf = 1.86 K kg mol-1) is...
The elevation in boiling point of a solution of 13.44 g of CuCl2 in 1kg of water using the following information will be (Molecular weight of CuCl2 = ...
The freezing point of equimolal aqueous solutions will be highest for
MCQ (More than One Correct Answer)
For a solution formed by mixing liquids $$L$$ and $$M,$$ the vapor pressure of $$L$$ plotted against the mole fraction of $$M$$ in solution is shown i...
Mixture (s) showing positive deviation from Raoult’s law at 35oC is (are)
Subjective
1.22 g of benzoic acid is dissolved in 100 g of acetone and 100 g of benzene separately. Boiling point of the solution in acetone increases by 0.17 o...
To 500 cm3 of water, 3.0 $$\times$$ 10-3 kg of acetic acid is added. If 23% of acetic acid is dissociated, what will be the depression in freezing poi...
Nitrobenzene is formed as the major product along with a minor product in the reaction of benzene with a hot mixture of nitric acid and sulphuric acid...
A solution of a nonvolatile solute in water freezes at -0.30oC. The vapour pressure of pure water at 298 K s 23.51 mm Hg and Kf for water is 1.86 K kg...
The molar volume of liquid benzene (density = 0.877 g mL-1) increases by a factor of 2750 as it vaporises at 20oC and that of liquid toluene (density ...
What weight of the non-volatile solute, urea(NH2 - CO - NH2) needs to be dissolved in 100g of water, in order to decrease the vapour pressure of water...
The degree of dissociation of calcium nitrate in a dilute aqueous solution, containing 7.0 g. of the salt per 100 gm of water at 100oC is 70%. If the ...
The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile non-electrolyte solid weighing 2.175 g is added to 39.0 g of...
The vapour pressure of a dilute aqueous solution of glucose (C6H12O6) is 750 mm of mercury at 373 K. Calculate (i) molality, and (ii) mole fraction of...
The vapour pressure of ethanol and methanol are 44.5 and 88.7 mm Hg respectively. An ideal solution is formed at the same temperature by mixing 60 g o...
An organic compound CxH2yOy was burnt with twice the amount of oxygen needed for complete combustion of CO2 and H2O. The hot gases when cooled to 0oC ...
The vapour pressure of pure benzene is 639.7 mm of mercury and the vapour of a solution of a solute in benzene at the same temperature is 631.9 mm of ...
What is the molarity and molality of a 13% solution (by weight) of sulphuric acid with a density of 1.02 g/ml? To what volume should 100 ml of this ac...