1
IIT-JEE 1980
Subjective
+2
-0
(a) 1 litre of a mixture of CO and CO2 is taken. This mixture is passed through a tube containing red hot charcoal. The volume now becomes 1.6 litre. The volumes are measured under the same conditions. Find the composition of the mixture by volume.
(b) A compound contains 28 percent of nitrogen and 72 percent of metal by weight. 3 atoms of metal combine with 2 atoms of N. Find the atomic weight of metal.
2
IIT-JEE 1980
Subjective
+4
-0
(i). A sample of MnSO4.4H2O is strongly heated in air. The residue is Mn3O4.
(ii). The residue is dissolved in 100 ml of 0.1N FeSO4 containing dilute H2SO4.
(iii). The solution reacts completely with 50 ml of KMnO4 solution.
(iv). 25 ml of the KMnO4 solution used in step (iii) requires 30 ml of 0.1 N FeSO4 solution for complete reaction.
Find the amount of MnSO4.4H2O present in the sample
(ii). The residue is dissolved in 100 ml of 0.1N FeSO4 containing dilute H2SO4.
(iii). The solution reacts completely with 50 ml of KMnO4 solution.
(iv). 25 ml of the KMnO4 solution used in step (iii) requires 30 ml of 0.1 N FeSO4 solution for complete reaction.
Find the amount of MnSO4.4H2O present in the sample
3
IIT-JEE 1980
Subjective
+4
-0
(a) One litre of a sample of hard water contains 1 mg of CaCl2 and 1 mg of MgCl2. Find the total hardness in terms of parts of CaCO3 per 106 parts of water by weight.
(b) A sample of hard water contains 20 mg of Ca++ ions per litre. How many milli-equivalent of Na2CO3 would be required to soften 1 litre of the sample?
(c) 1 gm of Mg is burnt in a closed vessel which contains 0.5gm of O2.
(i) Which reactant is left in excess?
(ii) Find the weight of the excess reactants.
(iii) How many milliliters of 0.5N H2SO4 will dissolve the residue in the vessel?
(b) A sample of hard water contains 20 mg of Ca++ ions per litre. How many milli-equivalent of Na2CO3 would be required to soften 1 litre of the sample?
(c) 1 gm of Mg is burnt in a closed vessel which contains 0.5gm of O2.
(i) Which reactant is left in excess?
(ii) Find the weight of the excess reactants.
(iii) How many milliliters of 0.5N H2SO4 will dissolve the residue in the vessel?
4
IIT-JEE 1979
Subjective
+2
-0
4.215 g of a metallic carbonate was heated in a hard glass tube and the CO2 evolved was found to measure 1336 ml at 27oC and 700 mm pressure. What is the equivalent weight of metal?
Questions Asked from Some Basic Concepts of Chemistry (Subjective)
Number in Brackets after Paper Indicates No. of Questions
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