A sugar syrup of weight 214.2 g contains 34.2 g of sugar (C₁₂H₂₂O₁₁). Calculate (i) molal concentration and (ii) mole fraction of sugar in the syrup

A sample of hydrazine sulphate (N₂H₆SO₄) was dissolved in 100 ml. of water, 10 ml of this solution was reacted with excess of ferric chloride solution and warmed to complete the reaction. Ferrous ion formed was estimated and it required 20 ml of M/50 potassium permanganate solution. Estimate the amount of hydrazine sulphate in one litre of the solution.

Reaction:

4Fe³⁺ + N₂H₄ $$\to$$ N₂ + 4Fe²⁺ + 4H⁺

$$MnO_4^-$$ + 4Fe²⁺ + 8H⁺ $$\to$$ Mn²⁺ + 5Fe³⁺ + 4H₂O

Five ml of 8N nitric acid, 4.8ml of 5N hydrochloric acid and a certain volume of 17M sulphuric acid are mixed together and made upto 2 litre. Thirty ml of this acid mixture neutralise 42.9 ml of sodium carbonate solution containing one gram of Na₂CO₃.10H₂O in 100 ml of water. Calculate the amount in gram of the sulphate ions in solution.

4.08 g of a mixture of BaO and an unknown carbonate MCO₃ was heated strongly. The residue weighed 3.64 g. This was dissolved in 100 ml of 1 N HCl. The excess acid required 16 ml of 2.5 N NaOH solution for complete neutralization. Identify the metal M. (At wt. H = 1, C = 12, O = 16, Cl = 35.5, Ba = 138)