An aqueous solution containing 0.10 g KIO₃ (formula weight = 214.0) was treated with an excess of KI solution. The solution was acidified with HCl. The liberated I₂ consumed 45.0 mL of thiosulphate solution to decolourise the blue strach-iodine complex. Calculate the molarity of the sodium thiosulphate solution.

A 3.00 g sample containing Fe₃O₄, Fe₂O₃ and an inert impure substance is treated with excess of KI solution in presence of dilute H₂SO₄. The entire iron is converted into Fe²⁺ along with the liberation of iodine. The resulting solution is diluted to 100 ml, A 20 ml of the diluted solution requires 11.0 ml of 0.5 M Na₂S₂O₃ solution to reduce the iodine present. A 50 ml of the diluted solution, after complete extraction of the iodine requires 12.80 ml of 0.25 M KMnO₄ solution in the dilute H₂SO₄ medium for the oxidation of Fe²⁺. Calculate the percentages of Fe₂O₃ and Fe₃O₄ in the original sample.

8.0575 $$\times$$ 10^-2 kg of Glauber's salt is dissolved in water to obtain 1 dm³ of a solution of density 1077.2 kg.m^-3. Calculate the molarity, molality and mole fraction Na₂SO₄ in the solution.

The composition of a sample of Wustite is Fe_0.93O_1.00 what percentage of the iron is present in the form of Fe(III)?