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JEE Advanced 2025 Paper 1 Online
MCQ (More than One Correct Answer)
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-2
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For the reaction sequence given below, the correct statement(s) is(are)

JEE Advanced 2025 Paper 1 Online Chemistry - Haloalkanes and Haloarenes Question 1 English

(In the options, X is any atom other than carbon and hydrogen, and it is different in P, Q and R)

A

C–X bond length in P, Q and R follows the order Q > R > P.

B

C–X bond enthalpy in P, Q and R follows the order R > P > Q.

C

Relative reactivity toward SN2 reaction in P, Q and R follows the order P > R > Q.

D

pKa value of the conjugate acids of the leaving groups in P, Q and R follows the order R > Q > P.

2
JEE Advanced 2025 Paper 1 Online
Numerical
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In an electrochemical cell, dichromate ions in aqueous acidic medium are reduced to Cr3+. The current (in amperes) that flows through the cell for 48.25 minutes to produce 1 mole of Cr3+ is ______.

Use: 1 Faraday = 96500 C mol−1

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3
JEE Advanced 2025 Paper 1 Online
Numerical
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At 25 °C, the concentration of H+ ions in 1.00 × 10−3 M aqueous solution of a weak monobasic acid having acid dissociation constant (Ka) of 4.00 × 10−11 is X × 10−7 M. The value of X is ______.

Use: Ionic product of water (Kw) = 1.00 × 10−14 at 25 °C

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4
JEE Advanced 2025 Paper 1 Online
Numerical
+4
-0
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Molar volume (Vm) of a van der Waals gas can be calculated by expressing the van der Waals equation as a cubic equation with Vm as the variable. The ratio (in mol dm−3) of the coefficient of Vm2 to the coefficient of Vm for a gas having van der Waals constants a = 6.0 dm6 atm mol−2 and b = 0.060 dm3 mol−1 at 300 K and 300 atm is ______.

Use: Universal gas constant (R) = 0.082 dm3 atm mol−1 K−1

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