1
JEE Advanced 2017 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-0.75
Change Language
The standard state Gibbs free energies of formation of $$C$$(graphite) and $$C$$(diamond) at $$T=298$$ $$K$$ are

$${\Delta _f}{G^0}$$ [$$C$$(graphite)] $$ = 0kJmo{l^{ - 1}}$$

$${\Delta _f}{G^0}$$ [$$C$$(diamond)] $$ = 2.9kJmo{l^{ - 1}}$$

The standard state means that the pressure should be $$1$$ bar, and substance should be pure at a given temperature. The conversion of graphite [$$C$$(graphite)] to diamond [$$C$$(diamond)] reduces its volume by $$2 \times {10^{ - 6}}\,{m^3}\,mo{l^{ - 1}}$$ If $$C$$(graphite) is converted to $$C$$(diamond) isothermally at $$T=298$$ $$K,$$ the pressure at which $$C$$(graphite) is in equilibrium with $$C$$(diamond), is

[Useful information : $$1$$ $$J=1$$ $$kg\,{m^2}{s^{ - 2}};1\,Pa = 1\,kg\,{m^{ - 1}}{s^{ - 2}};$$ $$1$$ bar $$ = {10^5}$$ $$Pa$$]
A
$$14501$$ bar
B
$$58001$$ $$bar$$
C
$$1450$$ bar
D
$$29001$$ bar
2
JEE Advanced 2017 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-0.75
Change Language
The order of the oxidation state of the phosphorous atom in

$${H_3}P{O_2},{H_3}P{O_4},{H_3}P{O_3}$$ and $${H_4}{P_2}{O_6}$$ is
A
$${H_3}P{O_3} > {H_3}P{O_2} > {H_3}P{O_4} > {H_4}{P_2}{O_6}$$
B
$${H_3}P{O_4} > {H_3}P{O_2} > {H_3}P{O_3} > {H_4}{P_2}{O_6}$$
C
$${H_3}P{O_4} > {H_4}{P_2}{O_6} > {H_3}P{O_3} > {H_3}P{O_2}$$
D
$${H_3}P{O_2} > {H_3}P{O_3} > {H_4}{P_2}{O_6} > {H_3}P{O_4}$$
3
JEE Advanced 2017 Paper 2 Offline
MCQ (More than One Correct Answer)
+4
-1
Change Language
For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant $$K$$ in terms of change in entropy is described by
A
With increase in temperature, the value of $$K$$ for exothermic reaction decreases because the entropy change of the system is positive
B
With increase in temperature, the value of $$K.$$ for endothermic reaction increases because unfavorable change in entropy of the surroundings decreases
C
With increase in temperature, the value of $$K$$ for endothermic reaction increases because the entropy change of the system is negative
D
with increase in temperature, the value of $$K$$ for exothermic reaction decreases because favorable change in entropy of the surroundings decreases
4
JEE Advanced 2017 Paper 2 Offline
MCQ (More than One Correct Answer)
+4
-1
Change Language
The correct statement(s) about surface properties is (are)
A
Adsorption is accompanied by decrease in ethalpy and decrease in entropy of the system
B
The critical temperatures of ethane and nitrogen are $$563$$ $$K$$ and $$126$$ $$K,$$ respectively. The adsorption of ethane will be more than that of nitrogen on same amount of activated charcoal at a given temperature
C
Cloud is an emulsion type of colloid in which liquid is dispersed phase and gas is dispersion medium
D
Brownian motion of colloidal particles does not depend on the size of the particles but depends on viscosity of the solution
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