Among the following, the correct statement(s) is (are)

Compounds $$P$$ and $$R$$ upon ozonolysis produce $$Q$$ and $$S,$$ respectively. The molecular formula of $$Q$$ and $$S$$ is $${C_8}{H_8}O.Q$$ undergoes Canninzzaro reaction but not haloform reaction, whereas $$S$$ undergoes haloform reaction but not Cannizzaro reaction


The option(s) with suitable combination of $$P$$ and $$R,$$ respectively, is (are)

The order of basicity among the following compounds is

Pure water freezes at $$273$$ $$K$$ and $$1$$ bar. The addition of $$34.5$$ $$g$$ of ethanol to $$500$$ $$g$$ of water changes the freezing point of the solution. Use the freezing point depression constant of water as $$2$$ kg $$mo{l^{ - 1}}.$$ The figures shown below represent plots of vapor pressure $$(V.P.)$$ versus temperature $$(T).$$ [molecular weight of ethanol is $$46$$ $$g$$ $$mo{l^{ - 1}}.$$ ] Among the following, the option representing change in the freezing point is