Two aliphatic aldehydes $\mathbf{P}$ and $\mathbf{Q}$ react in the presence of aqueous $\mathrm{K}_2 \mathrm{CO}_3$ to give compound $\mathbf{R}$, which upon treatment with HCN provides compound $\mathbf{S}$. On acidification and heating, $\mathbf{S}$ gives the product shown below :
Column I | Column II |
---|---|
(A) |
(P) Racemic mixture |
(B) |
(Q) Addition reaction |
(C) |
(R) Substitution reaction |
(D) |
(S) Coupling reaction |
All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in Column II.
Column I | Column II |
---|---|
(A) (CH3)2SiCl2 | (P) Hydrogen halide formation |
(B) XeF4 | (Q) Redox reaction |
(C) Cl2 | (R) Reacts with glass |
(D) VCl5 | (S) Polymerisation |
(T) O2 formation |
$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$ Column-$$I$$
(A)$$\,\,\,\,$$ A line from the origin meets the lines $$\,{{x - 2} \over 1} = {{y - 1} \over { - 2}} = {{z + 1} \over 1}$$
and $${{x - {8 \over 3}} \over 2} = {{y + 3} \over { - 1}} = {{z - 1} \over 1}$$ at $$P$$ and $$Q$$ respectively. If length $$PQ=d,$$ then $${d^2}$$ is
(B)$$\,\,\,\,$$ The values of $$x$$ satisfying $${\tan ^{ - 1}}\left( {x + 3} \right) - {\tan ^{ - 1}}\left( {x - 3} \right) = {\sin ^{ - 1}}\left( {{3 \over 5}} \right)$$ are
(C)$$\,\,\,\,$$ Non-zero vectors $$\overrightarrow a ,\overrightarrow b $$ and $$\overrightarrow c \,\,$$ satisfy $$\overrightarrow a \,.\,\overrightarrow b \, = 0.$$
$$\left( {\overrightarrow b - \overrightarrow a } \right).\left( {\overrightarrow b + \overrightarrow c } \right) = 0$$ and $$2\left| {\overrightarrow b + \overrightarrow c } \right| = \left| {\overrightarrow b - \overrightarrow a } \right|.$$
If $$\overrightarrow a = \mu \overrightarrow b + 4\overrightarrow c \,\,,$$ then the possible values of $$\mu $$ are
(D)$$\,\,\,\,$$ Let $$f$$ be the function on $$\left[ { - \pi ,\pi } \right]$$ given by $$f(0)=9$$
and $$f\left( x \right) = \sin \left( {{{9x} \over 2}} \right)/\sin \left( {{x \over 2}} \right)$$ for $$x \ne 0$$
The value of $${2 \over \pi }\int_{ - \pi }^\pi {f\left( x \right)dx} $$ is
$$\,\,\,\,$$ $$\,\,\,\,$$ $$\,\,\,\,$$Column-$$II$$
(p)$$\,\,\,\,$$ $$-4$$
(q)$$\,\,\,\,$$ $$0$$
(r)$$\,\,\,\,$$ $$4$$
(s)$$\,\,\,\,$$ $$5$$
(t)$$\,\,\,\,$$ $$6$$