1
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of ${ }^{14} \mathrm{C}$ by neutron capture in the upper atmosphere.

$$ { }^{14} \mathrm{~N}+{ }_0^1 n \rightarrow{ }_6{ }^{14} \mathrm{C}+{ }_1^1 \mathrm{H} $$

${ }^{14} \mathrm{C}$ is absorbed by living organisms during photosynthesis. The ${ }^{14} \mathrm{C}$ content is constant in living organism once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of ${ }^{14} \mathrm{C}$ in the dead being, falls due to decay which ${ }^{14} \mathrm{C}$ undergoes.

$$ { }_6^{14} \mathrm{C} \rightarrow{ }_7^{14} \mathrm{~N}+\beta^{-} $$

The half-life period of ${ }^{14} \mathrm{C}$ is 5770 years. The decay constant ( $\lambda$ ) be calculated by using the following formula $\lambda=\frac{0.693}{t_{1 / 2}}$.

The comparison of the $\beta^{-}$activity of the dead matter with that of the carbon still in circulation enables measurement of the period of the isolation of the material from the living cycle. The method however, ceases to be accurate over periods longer than 30,000 years. The proportion of ${ }^{14} \mathrm{C}$ to ${ }^{12} \mathrm{C}$ in living matter is $1: 10^{12}$.

Which of the following option is correct?

A

In living organisms, circulation of ${ }^{14} \mathrm{C}$ from atmosphere is high, so the carbon content is constant in organism.

B

Carbon dating can be used to find out the age of earth crust and rocks.

C

Radioactive absorption due to cosmic radiation is equal to the rate of radioactive decay; hence, the carbon content remains constant in living organism.

D

Carbon dating cannot be used to determine concentration of ${ }^{14} \mathrm{C}$ in dead beings.

2
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of ${ }^{14} \mathrm{C}$ by neutron capture in the upper atmosphere.

$$ { }^{14} \mathrm{~N}+{ }_0^1 n \rightarrow{ }_6{ }^{14} \mathrm{C}+{ }_1^1 \mathrm{H} $$

${ }^{14} \mathrm{C}$ is absorbed by living organisms during photosynthesis. The ${ }^{14} \mathrm{C}$ content is constant in living organism once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of ${ }^{14} \mathrm{C}$ in the dead being, falls due to decay which ${ }^{14} \mathrm{C}$ undergoes.

$$ { }_6^{14} \mathrm{C} \rightarrow{ }_7^{14} \mathrm{~N}+\beta^{-} $$

The half-life period of ${ }^{14} \mathrm{C}$ is 5770 years. The decay constant ( $\lambda$ ) be calculated by using the following formula $\lambda=\frac{0.693}{t_{1 / 2}}$.

The comparison of the $\beta^{-}$activity of the dead matter with that of the carbon still in circulation enables measurement of the period of the isolation of the material from the living cycle. The method however, ceases to be accurate over periods longer than 30,000 years. The proportion of ${ }^{14} \mathrm{C}$ to ${ }^{12} \mathrm{C}$ in living matter is $1: 10^{12}$.

What should be the age of fossil for meaningful determination of its age?

A

6 years

B

6000 years

C

60,000 years

D

It can be used to calculate any age

3
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of ${ }^{14} \mathrm{C}$ by neutron capture in the upper atmosphere.

$$ { }^{14} \mathrm{~N}+{ }_0^1 n \rightarrow{ }_6{ }^{14} \mathrm{C}+{ }_1^1 \mathrm{H} $$

${ }^{14} \mathrm{C}$ is absorbed by living organisms during photosynthesis. The ${ }^{14} \mathrm{C}$ content is constant in living organism once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of ${ }^{14} \mathrm{C}$ in the dead being, falls due to decay which ${ }^{14} \mathrm{C}$ undergoes.

$$ { }_6^{14} \mathrm{C} \rightarrow{ }_7^{14} \mathrm{~N}+\beta^{-} $$

The half-life period of ${ }^{14} \mathrm{C}$ is 5770 years. The decay constant ( $\lambda$ ) be calculated by using the following formula $\lambda=\frac{0.693}{t_{1 / 2}}$.

The comparison of the $\beta^{-}$activity of the dead matter with that of the carbon still in circulation enables measurement of the period of the isolation of the material from the living cycle. The method however, ceases to be accurate over periods longer than 30,000 years. The proportion of ${ }^{14} \mathrm{C}$ to ${ }^{12} \mathrm{C}$ in living matter is $1: 10^{12}$.

A nuclear explosion has taken place leading to increase in concentration of ${ }^{14} \mathrm{C}$ in nearby areas. ${ }^{14} \mathrm{C}$ concentration is $\mathrm{C}_1$ in nearby areas and $C_2$ in areas far away. If the age of the fossil is determined to be $T_1$ and $T_2$ at the places respectively then,

A

The age of the fossil will increase at the place where explosion has taken place and $\mathrm{T}_1-\mathrm{T}_2=\frac{1}{\lambda} \ln \frac{\mathrm{C}_1}{\mathrm{C}_2}$.

B

The age of the fossil will decrease at the place where explosion has taken place and $\mathrm{T}_1-\mathrm{T}_2=\frac{1}{\lambda} \ln \frac{\mathrm{C}_1}{\mathrm{C}_2}$.

C

The age of fossil will be determined to be the same.

D

$\frac{\mathrm{T}_1}{\mathrm{~T}_2}=\frac{\mathrm{C}_1}{\mathrm{C}_2}$.

4
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-0

$$ \text { Match Column I with Column II : } $$

Column I Column II
(A) $\mathrm{CH}_3-\mathrm{CHBr}-\mathrm{CD}_3$ on treatment with alc. KOH gives $\mathrm{CH}_2=\mathrm{CH}-\mathrm{CD}_3$ as a major product. (P) E1 reaction
(B) $$
\begin{aligned}
&\mathrm{Ph}-\mathrm{CHBr}-\mathrm{CH}_3\\
&\text { reacts faster than }\\
&\mathrm{Ph}-\mathrm{CHBr}-\mathrm{CD}_3 .
\end{aligned}
$$
(Q) E2 reaction
(C) $$
\mathrm{Ph}-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{Br}
$$

on treatment with

$$
\mathrm{C}_2 \mathrm{H}_5 \mathrm{OD} / \mathrm{C}_2 \mathrm{H}_5 \mathrm{O}^{-}
$$

gives $\mathrm{Ph}-\mathrm{CD}=\mathrm{CH}_2$
as the major product.
(R) E1 cb reaction
(D) $\mathrm{PhCH}_2, \mathrm{CH}_2 \mathrm{Br}$ and $\mathrm{PhCD}_2 \mathrm{CH}_2 \mathrm{Br}$ react with same rate. (S) First order reaction
A

$$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{Q}) ; \mathrm{C} \rightarrow( \mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{P}, \mathrm{~S})] .$$

B

$$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{Q}) ; \mathrm{C} \rightarrow(\mathrm{R}, \mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{P})] .$$

C

$$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{Q}) ; \mathrm{C} \rightarrow(\mathrm{R}, \mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{P}, \mathrm{~S})] .$$

D

$$ [\mathrm{A} \rightarrow(\mathrm{Q}, P) ; \mathrm{B} \rightarrow(\mathrm{Q}) ; \mathrm{C} \rightarrow(\mathrm{R}, \mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{P}, \mathrm{~S})] .$$

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