1
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Statement 1 : [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ is paramagnetic.

Statement 2 : The Fe in [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ has three unpaired electrons.

A
Statement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
B
Statement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
C
Statement 1 is True, Statement 2 is False.
D
Statement 1 is False, Statement 2 is True.
2
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Statement 1 : The geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] are optically inactive.

Statement 2 : Both geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] possess axis of symmetry.

A
Statement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
B
Statement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
C
Statement 1 is True, Statement 2 is False.
D
Statement 1 is False, Statement 2 is True.
3
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Among the following metal carbonyl, the C-O bond order is lowest in

A
$$\mathrm{[Mn(CO)_6]^+}$$
B
$$\mathrm{[Fe(CO)_5]}$$
C
$$\mathrm{[Cr(CO)_6]}$$
D
$$\mathrm{[V(CO)_6]^-}$$
4
IIT-JEE 2007 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

Match the complexes in Column I with their properties listed in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) $$\mathrm{[Co(NH_3)_4(H_2O)_2]Cl_2}$$ (P) geometrical isomers
(B) $$\mathrm{[Pt(NH_3)_2Cl_2]}$$ (Q) paramagnetic
(C) $$\mathrm{[Co(H_2O)_5Cl]Cl}$$ (R) diamagnetic
(D) $$\mathrm{[Ni(H_2O)_6]Cl_2}$$ (S) metal ion with +2 oxidation state

A
A - (p, q, s); B - (p, r, s); C - (q, s); D - (q, s)
B
A - (q, s); B - (p, r, s); C - (q); D - (q, s)
C
A - (p, q, s); B - (p, r, s); C - (q); D - (s)
D
A - (p, q, s); B - (s); C - (q, s); D - (q)

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