1
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Statement 1 : Aniline on reaction with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol gives a dark blue coloured precipitate.

Statement 2 : The colour of the compound formed in the reaction of aniline with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol is due to the extended conjugation.

A
Statement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
B
Statement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
C
Statement 1 is True, Statement 2 is False.
D
Statement 1 is False, Statement 2 is True.
2
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+4
-1

Match the compounds in Column I with their characteristic test(s)/reaction(s) given in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) IIT-JEE 2008 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 18 English 1 (P) sodium fusion extract of the compound gives Prussian blue colour with FeSO$$_4$$.
(B) IIT-JEE 2008 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 18 English 2 (Q) gives positive FeCl$$_3$$ test.
(C) IIT-JEE 2008 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 18 English 3 (R) gives white precipitate with AgNO$$_3$$.
(D) IIT-JEE 2008 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 18 English 4 (S) reacts with aldehydes to form the corresponding hydrazone derivative.

A
A $$\to$$ (r, s); B $$\to$$ (p); C $$\to$$ (p, q); D $$\to$$ (s)
B
A $$\to$$ (r, s); B $$\to$$ (p, q); C $$\to$$ (p, q, r); D $$\to$$ (p, s)
C
A $$\to$$ (r); B $$\to$$ (p, q); C $$\to$$ (p, r); D $$\to$$ (p, s)
D
A $$\to$$ (r); B $$\to$$ (p); C $$\to$$ (p, q, r); D $$\to$$ (s)
3
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

$\mathrm{CH}_3 \mathrm{NH}_2+\mathrm{CHCl}_3+\mathrm{KOH} \rightarrow$ Nitrogen containing compound $+\mathrm{KCl}+\mathrm{H}_2 \mathrm{O}$.

Nitrogen containing compound is :

A

$\mathrm{CH}_3-\mathrm{C} \equiv \mathrm{N}$

B

$\mathrm{CH}_3-\mathrm{NH}-\mathrm{CH}_3$

C

$\mathrm{CH}_3-\overline{\mathrm{N}} \equiv \stackrel{+}{\mathrm{C}}$

D

$\mathrm{CH}_3-\stackrel{+}{\mathrm{N}} \equiv \stackrel{-}{\mathrm{C}}$

4
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

$\mathrm{RCONH}_2$ is converted into $\mathrm{RNH}_2$ by means of Hofmann bromamide degradation.

IIT-JEE 2006 Chemistry - Compounds Containing Nitrogen Question 2 English Comprehension

In this reaction, RCONHBr is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.

How can the conversion of (i) to (ii) be brought about?

A

KBr

B

$\mathrm{KBr}+\mathrm{CH}_3 \mathrm{ONa}$

C

$\mathrm{KBr}+\mathrm{KOH}$

D

$\mathrm{Br}_2+\mathrm{KOH}$

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