Match each of the compounds in Column I with its characteristic reaction(s) in Column II.
| Column I | Column II | ||
|---|---|---|---|
| (A) | $$C{H_3}C{H_2}C{H_2}CN$$ | (P) | Reduction with $$Pd - C/{H_2}$$ |
| (B) | $$C{H_3}C{H_2}OCOC{H_3}$$ | (Q) | Reduction with $$SnC{l_2}/HCl$$ |
| (C) | $$C{H_3} - CH = CH - C{H_2}OH$$ | (R) | Development of foul smell on treatment with chloroform and alcoholic KOH |
| (D) | $$C{H_3}C{H_2}C{H_2}C{H_2}N{H_2}$$ | (S) | Reduction with diisobutylaluminium hydride (DIBAL-H) |
| (T) | Alkaline hydrolysis |
Statement 1 : Aniline on reaction with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol gives a dark blue coloured precipitate.
Statement 2 : The colour of the compound formed in the reaction of aniline with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol is due to the extended conjugation.
Match the compounds in Column I with their characteristic test(s)/reaction(s) given in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.
| Column I | Column II | ||
|---|---|---|---|
| (A) |  |
(P) | sodium fusion extract of the compound gives Prussian blue colour with FeSO$$_4$$. |
| (B) |  |
(Q) | gives positive FeCl$$_3$$ test. |
| (C) |  |
(R) | gives white precipitate with AgNO$$_3$$. |
| (D) |  |
(S) | reacts with aldehydes to form the corresponding hydrazone derivative. |
$\mathrm{CH}_3 \mathrm{NH}_2+\mathrm{CHCl}_3+\mathrm{KOH} \rightarrow$ Nitrogen containing compound $+\mathrm{KCl}+\mathrm{H}_2 \mathrm{O}$.
Nitrogen containing compound is :
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