Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.
Match each of the compounds in Column I with its characteristic reaction(s) in Column II.
Column I | Column II | ||
---|---|---|---|
(A) | $$C{H_3}C{H_2}C{H_2}CN$$ | (P) | Reduction with $$Pd - C/{H_2}$$ |
(B) | $$C{H_3}C{H_2}OCOC{H_3}$$ | (Q) | Reduction with $$SnC{l_2}/HCl$$ |
(C) | $$C{H_3} - CH = CH - C{H_2}OH$$ | (R) | Development of foul smell on treatment with chloroform and alcoholic KOH |
(D) | $$C{H_3}C{H_2}C{H_2}C{H_2}N{H_2}$$ | (S) | Reduction with diisobutylaluminium hydride (DIBAL-H) |
(T) | Alkaline hydrolysis |
Statement 1 : Aniline on reaction with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol gives a dark blue coloured precipitate.
Statement 2 : The colour of the compound formed in the reaction of aniline with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol is due to the extended conjugation.
Match the compounds in Column I with their characteristic test(s)/reaction(s) given in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.
Column I | Column II | ||
---|---|---|---|
(A) | ![]() |
(P) | sodium fusion extract of the compound gives Prussian blue colour with FeSO$$_4$$. |
(B) | ![]() |
(Q) | gives positive FeCl$$_3$$ test. |
(C) | ![]() |
(R) | gives white precipitate with AgNO$$_3$$. |
(D) | ![]() |
(S) | reacts with aldehydes to form the corresponding hydrazone derivative. |