One gram of commercial AgNO₃ is dissolved in 50 ml. of water. It is treated with 50 ml. of a KI solution. The silver iodide thus precipitated is filtered off. Excess of KI in the filterate is titrated with (M/10) KIO₃ solution in presence of 6M HCl till all I^- ions are converted into ICl. It requires 50 ml. of (M/10) KIO₃ solution. 20 ml. of the same stock solution of KI requires 30 ml. of (M/10) KIO₃ under similar conditions. Calculate the percentage of AgNO₃ in the sample.
(Reaction : KIO₃ + 2KI + 6HCl $$\to$$ 3ICl + 3KCl + 3H₂O)

A solution of 0.2 g of a compound containing Cu²⁺ and $$C_2O_4^{2-}$$ ions on titration with 0.02M $$KMnO_4$$ in presence of $$H_2SO_4$$ consumes 22.6 ml. of the oxidant. The resultant solution in neutralized with Na₂CO₃, acidified with dil. acetic acid and treated with excess KI. The liberated iodine requires 11.3 ml of 0.05M Na₂S₂O₃ solution for complete reduction.

Find out the molar ratio of Cu²⁺ to $$C_2O_4^{2-}$$ in the compound.Write down the balanced redox reactions involved in the above titrations.

A 1.0 g sample of Fe₂O₃ solid of 55.2% purity is dissolved in acid and reduced by heating the solution with zinc dust. The resultant solution is cooled and made upto 100.0 ml. An aliquot of 25.0 ml of this solution requires 17.0 ml of 0.0167M solution of an oxidant for titration. Calculate the number of electrons taken by the oxidant in the reaction of the above titration.

A mixture of H₂C₂O₄ (oxalic acid) and NaHC₂O₄ weighing 2.02 g was dissolved in water and solution made upto one litre. Ten millilitres of the solution required 3.0 ml. of 0.1 N sodium hydroxide solution for complete neutralization. In another experiment, 10.0 ml. of the same solution, in hot dilute sulphuric acid medium. require 4.0 ml. of 0.1 N potassium permanganate solution for complete reaction. Calculate the amount of H₂C₂O₄ and NaHC₂O₄ in the mixture.