Among $\left[\mathrm{Co}(\mathrm{CN})_4\right]^{4-},\left[\mathrm{Co}(\mathrm{CO})_3(\mathrm{NO})\right], \mathrm{XeF}_4,\left[\mathrm{PCl}_4\right]^{+},\left[\mathrm{PdCl}_4\right]^{2-},\left[\mathrm{ICl}_4\right]^{-},\left[\mathrm{Cu}(\mathrm{CN})_4\right]^{3-}$ and $\mathrm{P}_4$ the total number of species with tetrahedral geometry is _______.

An organic compound $\mathbf{P}$ having molecular formula $\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3$ gives ferric chloride test and does not have intramolecular hydrogen bond. The compound $\mathbf{P}$ reacts with 3 equivalents of $\mathrm{NH}_2 \mathrm{OH}$ to produce oxime $\mathbf{Q}$. Treatment of $\mathbf{P}$ with excess methyl iodide in the presence of $\mathrm{KOH}$ produces compound $\mathbf{R}$ as the major product. Reaction of $\mathbf{R}$ with excess iso-butylmagnesium bromide followed by treatment with $\mathrm{H}_3 \mathrm{O}^{+}$gives compound $\mathbf{S}$ as the major product.

The total number of methyl $\left(-\mathrm{CH}_3\right)$ group(s) in compound $\mathbf{S}$ is ___.

An organic compound $\mathbf{P}$ with molecular formula $\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2$ decolorizes bromine water and also shows positive iodoform test. $\mathbf{P}$ on ozonolysis followed by treatment with $\mathrm{H}_2 \mathrm{O}_2$ gives $\mathbf{Q}$ and $\mathbf{R}$. While compound $\mathbf{Q}$ shows positive iodoform test, compound $\mathbf{R}$ does not give positive iodoform test. $\mathbf{Q}$ and $\mathbf{R}$ on oxidation with pyridinium chlorochromate (PCC) followed by heating give $\mathbf{S}$ and $\mathbf{T}$, respectively. Both $\mathbf{S}$ and $\mathbf{T}$ show positive iodoform test.

Complete copolymerization of 500 moles of $\mathbf{Q}$ and 500 moles of $\mathbf{R}$ gives one mole of a single acyclic copolymer $\mathbf{U}$.

[Given, atomic mass: $\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16$ ]

Sum of number of oxygen atoms in $\mathbf{S}$ and $\mathbf{T}$ is _______.

An organic compound $\mathbf{P}$ with molecular formula $\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2$ decolorizes bromine water and also shows positive iodoform test. $\mathbf{P}$ on ozonolysis followed by treatment with $\mathrm{H}_2 \mathrm{O}_2$ gives $\mathbf{Q}$ and $\mathbf{R}$. While compound $\mathbf{Q}$ shows positive iodoform test, compound $\mathbf{R}$ does not give positive iodoform test. $\mathbf{Q}$ and $\mathbf{R}$ on oxidation with pyridinium chlorochromate (PCC) followed by heating give $\mathbf{S}$ and $\mathbf{T}$, respectively. Both $\mathbf{S}$ and $\mathbf{T}$ show positive iodoform test.

Complete copolymerization of 500 moles of $\mathbf{Q}$ and 500 moles of $\mathbf{R}$ gives one mole of a single acyclic copolymer $\mathbf{U}$.

[Given, atomic mass: $\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16$ ]

The molecular weight of $\mathbf{U}$ is ______ .