The option(s) with correct sequence of reagents for the conversion of $\mathbf{P}$ to $\mathbf{Q}$ is(are)
To form a complete monolayer of acetic acid on $1 \mathrm{~g}$ of charcoal, $100 \mathrm{~mL}$ of $0.5 \mathrm{M}$ acetic acid was used. Some of the acetic acid remained unadsorbed. To neutralize the unadsorbed acetic acid, 40 $\mathrm{mL}$ of $1 \mathrm{M} \mathrm{NaOH}$ solution was required. If each molecule of acetic acid occupies $\mathbf{P} \times 10^{-23} \mathrm{~m}^2$ surface area on charcoal, the value of $\mathbf{P}$ is _____.
[Use given data: Surface area of charcoal $=1.5 \times 10^2 \mathrm{~m}^2 \mathrm{~g}^{-1}$; Avogadro's number $\left(\mathrm{N}_{\mathrm{A}}\right)=6.0 \times 10^{23}$ $\left.\mathrm{mol}^{-1}\right]$
The elevation of boiling point for solution in Vessel-1 is ________ $\%$ of the solution in Vessel-2.