For the reaction, $\mathrm{M}(s)+2 \mathrm{H}^{+}(a q) \rightarrow \mathrm{H}_{2}(g)+\mathrm{M}^{2+}(a q)$, if $\frac{d E_\text{cell}}{d T}=\frac{R}{F}$, then the entropy change of the reaction is $\mathrm{R}$ (assume that entropy and internal energy changes are temperature independent).

The cell reaction, $\operatorname{Pt}(s) \mid \mathrm{H}_{2}(g, 1$ bar $)\left|\mathrm{H}^{+}(a q, 0.01 \mathrm{M}) \| \mathrm{H}^{+}(a q, 0.1 \mathrm{M})\right| \mathrm{H}_{2}(g, 1 \mathrm{bar}) \mid \operatorname{Pt}(s)$, is an entropy driven process.

For racemization of an optically active compound, $\Delta \mathrm{S}>0$.

$\Delta \mathrm{S}>0$, for $\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}+3$ en $\rightarrow\left[\mathrm{Ni}(\mathrm{en})_{3}\right]^{2+}+6 \mathrm{H}_{2} \mathrm{O}$ (where en $=$ ethylenediamine).

$\mathrm{B}$

$\mathrm{B}_{2} \mathrm{H}_{6}$

$\mathrm{B}_{2} \mathrm{O}_{3}$

$\mathrm{HBF}_{4}$

Limestone is used to remove silicate impurity.

Pig iron obtained from blast furnace contains about $4 \%$ carbon.

Coke (C) converts $\mathrm{CO}_{2}$ to $\mathrm{CO}$.

Exhaust gases consist of $\mathrm{NO}_{2}$ and $\mathrm{CO}$.

Compounds $\mathbf{P}$ and $\mathbf{Q}$ are carboxylic acids.

Compound $\mathbf{S}$ decolorizes bromine water.

Compounds $\mathbf{P}$ and $\mathbf{S}$ react with hydroxylamine to give the corresponding oximes.

Compound $\mathbf{R}$ reacts with dialkylcadmium to give the corresponding tertiary alcohol.