Considering the following reaction sequence,

the correct option(s) is(are)
Match the rate expressions in LIST-I for the decomposition of $X$ with the corresponding profiles provided in LIST-II. $X_{\mathrm{s}}$ and $\mathrm{k}$ are constants having appropriate units.
| List-I | List-II |
|---|---|
| (I) rate $=\frac{\mathrm{k}[\mathrm{X}]}{\mathrm{X}_{\mathrm{s}}+[\mathrm{X}]}$ under all possible initial concentrations of $\mathrm{X}$ |
(P) ![]() |
| (II) rate $=\frac{k[X]}{X_{s}+[X]}$ where initial concentrations of $X$ are much less than $X_{s}$ |
(Q) ![]() |
| (III) rate $=\frac{k[X]}{X_{s}+[X]}$ where initial concentrations of $\mathrm{X}$ are much higher than $X_{s}$ |
(R) ![]() |
| (IV) rate $=\frac{k[X]^{2}}{X_{s}+[X]}$ where initial concentration of $X$ is much higher than $\mathrm{X}_{\mathrm{s}}$ |
(S) ![]() |
(T) ![]() |
LIST-I contains compounds and LIST-II contains reactions
| List-I | List-II |
|---|---|
| (I) $\mathrm{H}_{2} \mathrm{O}_{2}$ |
(P) $\mathrm{Mg}\left(\mathrm{HCO}_{3}\right)_{2}+\mathrm{Ca}(\mathrm{OH})_{2} \rightarrow$ |
| (II) $\mathrm{Mg}(\mathrm{OH})_{2}$ |
(Q) $\mathrm{BaO}_{2}+\mathrm{H}_{2} \mathrm{SO}_{4} \rightarrow$ |
| (III) $\mathrm{BaCl}_{2}$ |
(R) $\mathrm{Ca}(\mathrm{OH})_{2}+\mathrm{MgCl}_{2} \rightarrow$ |
| (IV) $\mathrm{CaCO}_{3}$ |
(S) $\mathrm{BaO}_{2}+\mathrm{HCl} \rightarrow$ |
| (T) $\mathrm{Ca}\left(\mathrm{HCO}_{3}\right)_{2}+\mathrm{Ca}(\mathrm{OH})_{2} \rightarrow$ |
Match each compound in LIST-I with its formation reaction(s) in LIST-II, and choose the correct option
LIST-I contains metal species and LIST-II contains their properties.
| List-I | List-II |
|---|---|
| (I) $\left[\mathrm{Cr}(\mathrm{CN})_{6}\right]^{4-}$ |
(P) $t_{2 \mathrm{g}}$ orbitals contain 4 electrons |
| (II) $\left[\mathrm{RuCl}_{6}\right]^{2-}$ | (Q) $\mu$ (spin-only $)=4.9 \mathrm{BM}$ |
| (III) $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ |
(R) low spin complex ion |
| (IV) $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ |
(S) metal ion in $4+$ oxidation state |
| (T) $d^{4}$ species |
[Given: Atomic number of $\mathrm{Cr}=24, \mathrm{Ru}=44, \mathrm{Fe}=26$ ]
Match each metal species in LIST-I with their properties in LIST-II, and choose the correct option
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