The rate constant for an isomerisation reaction, A $$\to$$ B is 4.5 $$\times$$ 10^-3 min^-1. If the initial concentration of A is 1 M, calculate the rate of the reaction after 1 h.

The rate constant of a reaction is 1.5 $$\times$$ 10⁷ s^-1 at 50^oC and 4.5 $$\times$$ 10⁷ s^-1 at 100^oC. Evaluate the Arrhenius parameters A and E_a.

The ionisation constant of $$NH_4^+$$ in water is 5.6 $$\times$$ 10^-10 at 25^oC. The rate constant for the reaction of $$NH_4^+$$ and $$OH^-$$ to form NH₃ and H₂O at 25^oC is 3.4 $$\times$$ 10¹⁰ L mol^-1s^-1. Calculate the rate constant for proton transfer from water to NH3.

At 380^oC, the half-life period for the first order decomposition of H₂O₂ is 360 min. Calculate the time required for 75% decomposition at 450^oC.