| Observation No. | Time (in minute) | Px (in mm of Hg) |
|---|---|---|
| 1 | 0 | 800 |
| 2 | 100 | 400 |
| 3 | 200 | 200 |
(i) What is the order of the reaction to X?
(ii) Find the rate constant
(iii) Find the time for 75% completion of the reaction.
(iv) Find the total pressure when pressure of X is 700 mm of Hg
Fill in the blanks:
(A) $$_{92}^{235}$$U + $$_{0}^{1}$$n $$\to$$ $$_{52}^{137}$$A + $$_{40}^{97}$$B + ____________.
(B) $$_{34}^{82}$$Se $$\to$$ 2 $${}_{ - 1}{e^0}$$ + __________.
For the following reaction
2X(g) $$\to$$ 3Y(g) + 2Z(g)
assuming ideal gas conditions, the data for change of partial pressure with time is as follows:
$$ \begin{array}{llll} \hline \text { Time (in min) } & 0 & 100 & 200 \\ \hline \begin{array}{l} \text { Partial pressure of X } \\ \text { (in mm of Hg) } \end{array} & 800 & 400 & 200 \end{array} $$
Calculate
(A) Order of reaction.
(B) Rate constant.
(C) Time taken for 75% completion of reaction.
(D) Total pressure of the reaction mixture when $$p_x=700$$ mm.
| [Ao] | [Bo] | Ro (mol L-1 s-1) | |
|---|---|---|---|
| 1 | 0.1 | 0.1 | 0.05 |
| 2 | 0.2 | 0.1 | 0.10 |
| 3 | 0.1 | 0.2 | 0.05 |
(b) Find the rate constant
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