1
IIT-JEE 2011 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves O and gives an intense blue solution.

The metal rod M is
A
Fe
B
Cu
C
Ni
D
Co
2
IIT-JEE 2011 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves O and gives an intense blue solution.

The compound N is

A
AgNO3
B
Zn(NO3)2
C
Al(NO3)3
D
Pb(NO3)2
3
IIT-JEE 2011 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves O and gives an intense blue solution.

The final solution contains :

A
$${[Pb{(N{H_3})_4}]^{2 + }}$$ and $${[CoC{l_2}]^{2 - }}$$
B
$${[Al{(N{H_3})_4}]^{3 + }}$$ and $${[Cu{(N{H_3})_4}]^{2 + }}$$
C
$${[Ag{(N{H_3})_2}]^ + }$$ and $${[Cu{(N{H_3})_4}]^{2 + }}$$
D
$${[Ag{(N{H_3})_2}]^ + }$$ and $${[Ni{(N{H_3})_6}]^{2 + }}$$
4
IIT-JEE 2009 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

p-Amino-N, N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate(III) leads to a brown coloration due to the formation of Z.

The compound X is

A
NaNO$$_3$$
B
NaCl
C
Na$$_2$$SO$$_4$$
D
Na$$_2$$S
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