An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate (P) was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H2S in a dilute mineral acid medium. However, it gave a precipitate (R) with H2S in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with H2O2 in an aqueous NaOH medium.
The precipitate P contains
An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate (P) was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H2S in a dilute mineral acid medium. However, it gave a precipitate (R) with H2S in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with H2O2 in an aqueous NaOH medium.
The coloured solution S contains
When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves O and gives an intense blue solution.
When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves O and gives an intense blue solution.
The compound N is