1
IIT-JEE 1997
Subjective
+3
-0
How many grams of silver could be plated out on a serving tray by electrolysis of a solution containing silver in +1 oxidation state for a period of 8.0 hours at a current of 8.46 amperes? What is the area of the tray if the thickness of the silver plating is 0.00254 cm? Density of silver is 10.5 g/cm3
2
IIT-JEE 1997
Subjective
+2
-0
Calculate the equilibrium constant for the reaction
Fe2+ + Ce4+ $$\leftrightharpoons$$ Fe3+ + Ce3+
(given $$E_{C{e^{4 + }}/C{e^{3 + }}}^o$$ = 1.44 V; $$E_{F{e^{3 + }}/F{e^{2 + }}}^o$$ = 0.68 V)
3
IIT-JEE 1996
Subjective
+3
-0
The standard reduction potential for Cu2+|Cu is +0.34 V. Calculate the reduction potential at pH = 14 for the above couple. Ksp of Cu(OH)2 is 1.0 $$\times$$ 10-19
4
IIT-JEE 1995
Subjective
+4
-0
An excess of liquid mercury is added to an acidified solution of 1.0 $$\times$$ 10-3 M Fe3+. It is found that 5% of Fe3+ remains at equilibrium at 25oC. Calculate $$E_{Hg_2^{2 + }|\,Hg}^o$$, assuming that only reaction that occurs is
2Hg + 2Fe3+ $$\to$$ $$Hg_2^{2+}$$ + 2Fe2+
(Given $$E_{F{e^{3 + }}|\,F{e^{2 + }}}^o$$ = 0.77 V)
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