An acidified solution of 0.05 M Zn²⁺ is saturated with 0.1 M H₂S. What is the minimum molar concentration (M) of H⁺ required to prevent the precipitation of ZnS?

Use K_sp(ZnS) = 1.25 $$ \times $$ 10^$$-$$22 and overall dissociation constant of

H₂S, K_net = K₁K₂ = 1 $$ \times $$ 10^-21.

For a complex number z, let Re(z) denote that real part of z. Let S be the set of all complex numbers z satisfying $${z^4} - |z{|^4} = 4i{z^2}$$, where i = $$\sqrt { - 1} $$. Then the minimum possible value of |z₁ $$-$$ z₂|², where z₁, z₂$$ \in $$S with Re(z₁) > 0 and Re(z₂) < 0 is .........

The probability that a missile hits a target successfully is 0.75. In order to destroy the target completely, at least three successful hits are required. Then the minimum number of missiles that have to be fired so that the probability of completely destroying the target is NOT less than 0.95, is ............

Let O be the centre of the circle x² + y² = r², where $$r > {{\sqrt 5 } \over 2}$$. Suppose PQ is a chord of this circle and the equation of the line passing through P and Q is 2x + 4y = 5. If the centre of the circumcircle of the triangle OPQ lies on the line x + 2y = 4, then the value of r is .............