1
JEE Advanced 2020 Paper 1 Offline
MCQ (More than One Correct Answer)
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The cubic unit cell structure of a compound containing cation M and anion X is shown below. When compared to the anion, the cation has smaller ionic radius. Choose the correct statement(s).

JEE Advanced 2020 Paper 1 Offline Chemistry - Solid State & Surface Chemistry Question 17 English
A
The empirical formula of the compound is MX.
B
The cation M and anion X have different coordination geometries.
C
The ratio of M$$-$$X bond length of the cubic unit cell edge length is 0.866.
D
The ratio of the ionic radii of cation M to anion X is 0.414.
2
JEE Advanced 2020 Paper 1 Offline
Numerical
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5.00 mL of 0.10 M oxalic acid solution taken in a conical flask is titrated against NaOH from a burette using phenolphthalein indicator. The volume of NaOH required for the appearance of permanent faint pink color is tabulated below for five experiments. What is the concentration, in molarity, of the NaOH solution?

Exp. No. Vol. of NaOH (mL)
1 12.5
2 10.5
3 9.0
4 9.0
5 9.0
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3
JEE Advanced 2020 Paper 1 Offline
Numerical
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Consider the reaction,

A $$\rightleftharpoons $$ B

at 1000 K. At time t', the temperature of the system was increased to 2000 K and the system was allowed to reach equilibrium. Throughout this experiment the partial pressure of A was maintained at 1 bar. Given, below is the plot of the partial pressure of B with time. What is the ratio of the standard Gibbs energy of the reaction at 1000 K to that at 2000 K?

JEE Advanced 2020 Paper 1 Offline Chemistry - Equilibrium Question 10 English
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4
JEE Advanced 2020 Paper 1 Offline
Numerical
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Consider a 70% efficient hydrogen-oxygen fuel cell working under standard conditions at 1 bar and 298 K. Its cell reaction is

$${H_2}(g) + {1 \over 2}{O_2}(g)\buildrel {} \over \longrightarrow {H_2}O(l)$$

The work derived from the cell on the consumption of 1.0 $$ \times $$ 10$$-$$3 mole of H2(g) is used to compress 1.00 mole of a monoatomic ideal gas in a thermally insulated container. What is the change in the temperature (in K) of the ideal gas?

The standard reduction potentials for the two half-cells are given below :

$${O_2}(g) + 4{H^ + }(aq) + 4{e^ - }\buildrel {} \over \longrightarrow 2{H_2}O(l),$$

$${E^o} = 1.23V$$

$$2{H^ + }(aq) + 2{e^ - }\buildrel {} \over \longrightarrow {H_2}(g),$$

$${E^o} = 0.00\,V$$

Use, $$F = 96500\,C\,mo{l^{ - 1}}$$, $$R = 8.314\,J\,mo{l^{ - 1}}\,{K^{ - 1}}$$.
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