1
JEE Advanced 2018 Paper 1 Offline
MCQ (More than One Correct Answer)
+4
-1
The compounds(s) which generate(s) $${N_2}$$ gas upon thermal decomposition below $${300^ \circ }C$$ is (are)
A
$$N{H_4}N{O_3}$$
B
$$\left( {N{H_4}} \right){}_2C{r_2}O{}_7$$
C
$$Ba{\left( {{N_3}} \right)_2}$$
D
$$M{g_3}{N_2}$$
2
JEE Advanced 2018 Paper 1 Offline
MCQ (More than One Correct Answer)
+4
-1
The correct statement(s) regarding the binary transition metal carbonyl compounds is(are) (Atomic numbers : $$Fe = 26,Ni = 28$$)
A
Total number of valence shell electrons at metal center in $$Fe{\left( {CO} \right)_5}\,\,$$ or $$Ni{\left( {CO} \right)_4}$$ is $$16$$
B
These are predominantly low spin in nature
C
Metal-carbon bond strengthens when the oxidation state of the metal is lowered.
D
The carbonyl $$C-O$$ bond weakens when the oxidation state of the metal is increased
3
JEE Advanced 2018 Paper 1 Offline
Numerical
+3
-0
Consider an ionic solid $$MX$$ with $$NaCl$$ structure. Construct a new structure $$(Z)$$ whose unit cell is constructed from the unit cell of $$MX$$ following the sequential instructions given below. Neglect the charge balance.
$$(i)\,\,\,\,\,$$ Remove all the anions $$(X)$$ except the central one

$$(ii)\,\,\,\,$$ Replace all the face centered cations $$(M)$$ by anions $$(X)$$

$$(iii)\,\,$$ Remove all the corner cations $$(M)$$

$$(iv)\,\,\,\,$$ Replace the central anion $$(X)$$ with cation $$(M)$$

The value of $$\,\,\left( {{{number\,\,of\,\,anions} \over {number\,\,of\,\,cations}}} \right)\,\,$$ in $$Z$$ is ___________.
Your input ____
4
JEE Advanced 2018 Paper 1 Offline
Numerical
+3
-0
Among the species given below, the total number of diamagnetic species is _____________.

$$H$$ atom, $$N{O_2}$$ monomer, $${O_2}^ - $$ (superoxide), dimeric sulphur in vapor phase, $$M{n_3}{O_4},\,\,$$ $${\left( {N{H_4}} \right)_2}\left[ {FeC{l_4}} \right],$$ $${\left( {N{H_4}} \right)_2}\left[ {NiC{l_4}} \right],\,$$ $$\,{K_2}Mn{O_4},\,$$$${K_2}Cr{O_4}$$
Your input ____
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