In the following reaction, sequence in aqueous solution, the species X, Y and Z, respectively, are

$${S_2}O_3^{2 - }\buildrel {A{g^ + }} \over \longrightarrow \mathop X\limits_{Clear\,solution} \buildrel {A{g^ + }} \over \longrightarrow \mathop Y\limits_{White\,precipitate} \buildrel {With\,time} \over \longrightarrow \mathop Z\limits_{Black\,precipitate} $$

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, CH₃OH and CH₃(CH₂)₁₁ OSO$$_3^ - $$ Na⁺ at room temperature. The correct assignment of the sketches is

For "invert sugar", the correct statement(s) is(are)

(Given : specific rotations of (+)-sucrose, (+)-maltose, L-($$-$$)-glucose and L-(+)-fructose in aqueous solution are +66$$^\circ$$, +140$$^\circ$$, $$-$$52$$^\circ$$ and +92$$^\circ$$, respectively.)

Among the following reaction(s), which gives(give) tert-butyl benzene as the major product is(are)