1
JEE Advanced 2016 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

Among [Ni(CO)4], [NiCl4]2$$-$$, [Co(NH3)4)Cl2]Cl, Na3[CoF6], Na2O2 and CsO2, the total number of paramagnetic compound is

A
2
B
3
C
4
D
5
2
JEE Advanced 2016 Paper 1 Offline
MCQ (More than One Correct Answer)
+4
-2

The correct statements about of the following reaction sequence is (are)

Cumene (C9H12) $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{(ii)\,{H_3}{O^ + }}^{(i)\,{O_2}}} $$ P $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}^{CHC{l_3}/NaOH}} $$ Q (major) + R (minor)

Q $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{PhC{H_2}Br}^{NaOH}} $$ S

A
R is steam volatile.
B
Q gives dark violet coloration with 1% aqueous FeCl3 solution.
C
S gives yellow precipitate with 2, 4-dinitrophenylhydrazine.
D
S gives dark violet coloration with 1% aqueous FeCl3 solution.
3
JEE Advanced 2016 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1
Let $$S = \left\{ {x \in \left( { - \pi ,\pi } \right):x \ne 0, \pm {\pi \over 2}} \right\}.$$ The sum of all distinct solutions of the equation $$\sqrt 3 \,\sec x + \cos ec\,x + 2\left( {\tan x - \cot x} \right) = 0$$ in the set S is equal to
A
$$ - {{7\pi } \over 9}$$
B
$$ - {{2\pi } \over 9}$$
C
0
D
$${{5\pi } \over 9}$$
4
JEE Advanced 2016 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1
Let $$ - {\pi \over 6} < \theta < - {\pi \over {12}}.$$ Suppose $${\alpha _1}$$ and $${\beta_1}$$ are the roots of the equation $${x^2} - 2x\sec \theta + 1 = 0$$ and $${\alpha _2}$$ and $${\beta _2}$$ are the roots of the equation $${x^2} + 2x\,\tan \theta - 1 = 0.$$ $$If\,{\alpha _1} > {\beta _1}$$ and $${\alpha _2} > {\beta _2},$$ then $${\alpha _1} + {\beta _2}$$ equals
A
$$2\left( {\sec \theta - \tan \theta } \right)$$
B
$$2\,\sec \,\theta $$
C
$$ - 2\tan \theta $$
D
$$0$$
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