IIT-JEE 1999

Paper was held on
Sun, Apr 11, 1999 9:00 AM

## Chemistry

The normality of 0.3 M phosphorus acid (H3PO3) is

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The oxidation number of sulphur in S8,S2F2,H2S
respectively, are

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How many millilitres of 0.5 M H2SO4 are needed to dissolve 0.5 g of copper(II) carbonate?

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A plant virus is found to consist of uniform cylindrical particles of 150 Å in diameter and 5000 Å long. The specific vo

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The electrons, identified by quantum numbers n and l, (i) n = 4, l = 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2 and (iv) n

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Ground state electronic configuration of nitrogen atom can be represented by

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Ionic radii of

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The correct order of increasing C - O bond length of CO, $$CO_3^{2-}$$, CO2 is

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The geometry of H2S and its dipole moment are

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One mole of nitrogen gas at 0.8 atm takes 38 s to diffuse through a pinhole. whereas one mole of an unknown compound of

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When 3.06 g of solid NH4HS is introduced into a two litre evacuated flask at 27o C, 30% of the solid decomposes into gas

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Give reasons of the following:
BeCl2 can be easily hydrolysed.

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Nitrobenzene is formed as the major product along with a minor product in the reaction of benzene with a hot mixture of

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A cell, Ag | Ag+ || Cu2+ | Cu, initially contains 1 M Ag+ and 1 M Cu2+ ions. Calculate the change in the cell potential

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The rate constant for an isomerisation reaction, A $$\to$$ B is 4.5 $$\times$$ 10-3 min-1. If the initial concentration

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## Mathematics

In a triangle $$PQR,\angle R = \pi /2$$. If $$\,\,\tan \left( {P/2} \right)$$ and $$\tan \left( {Q/2} \right)$$ are the

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$$If\,i = \sqrt { - 1} ,\,\,then\,\,4 + 5{\left( { - {1 \over 2} + {{i\sqrt 3 } \over 2}} \right)^{334}} + 3{\left( { -

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For a positive integer $$\,n$$, let
$${f_n}\left( \theta \right) = \left( {\tan {\theta \over 2}} \right)\,\left( {

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For complex numbers z and w, prove that $${\left| z \right|^2}w - {\left| w \right|^2}z = z - w$$ if and only if $$ z =

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If the roots of the equation $${x^2} - 2ax + {a^2} + a - 3 = 0$$ are real and less than 3, then

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If in the expansion of $${\left( {1 + x} \right)^m}{\left( {1 - x} \right)^n},$$ the coefficients of $$x$$ and $${x^2}$$

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Let $$n$$ be any positive integer. Prove that
$$$\sum\limits_{k = 0}^m {{{\left( {\matrix{
{2n - k} \cr
k \cr

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Let $${a_1},{a_2},......{a_{10}}$$ be in $$A,\,P,$$ and $${h_1},{h_2},......{h_{10}}$$ be in H.P. If $${a_1} = {h_1} = 2

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The harmonic mean of the roots of the equation $$\left( {5 + \sqrt 2 } \right){x^2} - \left( {4 + \sqrt 5 } \right)x + 8

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Let a, b, c, d be real numbers in G.P. If u, v, w, satisfy the system of equations
u + 2v + 3w = 6
4u + 5v + 6w = 12

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For a positive integer $$n$$, let
$$a\left( n \right) = 1 + {1 \over 2} + {1 \over 3} + {1 \over 4} + .....\,{1 \over {

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Lt $$PQR$$ be a right angled isosceles triangle, right angled at $$P(2, 1)$$. If the equation of the line $$QR$$ is $$2x

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If $${x_1},\,{x_2},\,{x_3}$$ as well as $${y_1},\,{y_2},\,{y_3}$$, are in G.P. with the same common ratio, then the poin

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Let $${L_1}$$ be a straight line passing through the origin and $${L_2}$$ be the straight line $$x + y = 1$$. If the int

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If two distinct chords, drawn from the point (p, q) on the circle $${x^2}\, + \,{y^2} = \,px\, + \,qy\,\,(\,where\,pq\,

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Let $${T_1}$$, $${T_2}$$ be two tangents drawn from (- 2, 0) onto the circle $$C:{x^2}\,\, + \,{y^2} = 1$$. Determine th

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Let $$P$$ $$\left( {a\,\sec \,\theta ,\,\,b\,\tan \theta } \right)$$ and $$Q$$ $$\left( {a\,\sec \,\,\phi ,\,\,b\,\tan

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The curve described parametrically by $$x = {t^2} + t + 1,$$ $$y = {t^2} - t + 1 $$ represents

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If $$x$$ $$=$$ $$9$$ is the chord of contact of the hyperbola $${x^2} - {y^2} = 9,$$ then the equation of the vcorrespon

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On the ellipse $$4{x^2} + 9{y^2} = 1,$$ the points at which the tangents are parallel to the line $$8x = 9y$$ are

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Find the co-ordinates of all the points $$P$$ on the ellipse $${{{x^2}} \over {{a^2}}} + {{{y^2}} \over {{b^2}}} = 1$$,

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Consider the family of circles $${x^2} + {y^2} = {r^2},\,\,2 < r < 5$$. If in the first quadrant, the common taing

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Let $$ABC$$ be a triangle having $$O$$ and $$I$$ as its circumcenter and in centre respectively. If $$R$$ and $$r$$ are

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The number of real solutions of
$${\tan ^{ - 1}}\,\,\sqrt {x\left( {x + 1} \right)} + {\sin ^{ - 1}}\,\,\sqrt {{x^2} +

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The function $$f(x)=$$ $${\sin ^4}x + {\cos ^4}x$$ increases if

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The function $$f\left( x \right) = \int\limits_{ - 1}^x {t\left( {{e^t} - 1} \right)\left( {t - 1} \right){{\left( {t -

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Integrate $$\int {{{{x^3} + 3x + 2} \over {{{\left( {{x^2} + 1} \right)}^2}\left( {x + 1} \right)}}dx.} $$

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If for a real number $$y$$, $$\left[ y \right]$$ is the greatest integer less than or
equal to $$y$$, then the value of

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$$\int\limits_{\pi /4}^{3\pi /4} {{{dx} \over {1 + \cos x}}} $$ is equal to

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For which of the following values of $$m$$, is the area of the region bounded by the curve $$y = x - {x^2}$$ and the lin

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Integrate $$\int\limits_0^\pi {{{{e^{\cos x}}} \over {{e^{\cos x}} + {e^{ - \cos x}}}}\,dx.} $$

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Let $$f(x)$$ be a continuous function given by
$$$f\left( x \right) = \left\{ {\matrix{
{2x,} & {\left| x \right

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A solution of the differential equation
$${\left( {{{dy} \over {dx}}} \right)^2} - x{{dy} \over {dx}} + y = 0$$ is

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The differential equation representing the family of curves
$${y^2} = 2c\left( {x + \sqrt c } \right),$$ where $$c$$ is

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If the integers $$m$$ and $$n$$ are chosen at random from $$1$$ to $$100$$, then the probability that a number of the fo

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The probabilities that a student passes in Mathematics, Physics and Chemistry are $$m, p$$ and $$c,$$ respectively. Of t

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Eight players $${P_1},{P_2},.....{P_8}$$ play a knock-out tournament. It is known that whenever the players $${P_i}$$ an

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Let $$a=2i+j-2k$$ and $$b=i+j.$$ If $$c$$ is a vector such that $$a.$$ $$c = \left| c \right|,\left| {c - a} \right| =

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Let $$a=2i+j+k, b=i+2j-k$$ and a unit vector $$c$$ be coplanar. If $$c$$ is perpendicular to $$a,$$ then $$c =$$

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Let $$a$$ and $$b$$ two non-collinear unit vectors. If $$u = a - \left( {a\,.\,b} \right)\,b$$ and $$v = a \times b,$$ t

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Let $$u$$ and $$v$$ be units vectors. If $$w$$ is a vector such that $$w + \left( {w \times u} \right) = v,$$ then prove

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