The oxidation number of sulphur in S₈,S₂F₂,H₂S respectively, are

The normality of 0.3 M phosphorus acid (H₃PO₃) is

How many millilitres of 0.5 M H₂SO₄ are needed to dissolve 0.5 g of copper(II) carbonate?

A plant virus is found to consist of uniform cylindrical particles of 150 Å in diameter and 5000 Å long. The specific volume of the virus is 0.75 cm³/g. If the virus is considered to be a single particle, find its molar mass.

Ground state electronic configuration of nitrogen atom can be represented by

The electrons, identified by quantum numbers n and l, (i) n = 4, l = 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2 and (iv) n = 3, l = 1 can be placed in order of increasing energy, from the lowest to highest, as

Ionic radii of

The geometry of H₂S and its dipole moment are

The correct order of increasing C - O bond length of CO, $$CO_3^{2-}$$, CO₂ is

One mole of nitrogen gas at 0.8 atm takes 38 s to diffuse through a pinhole. whereas one mole of an unknown compound of xenon with flourine at 1.6 atm takes 57 s to diffuse through the same hole. Calculate the molecular formula of the compound.

When 3.06 g of solid NH₄HS is introduced into a two litre evacuated flask at 27^o C, 30% of the solid decomposes into gaseous ammonia and hydrogen sulphide. (i) K_c and K_p for the reaction at 27^o C (ii) What would happen to the equilibrium when more solid NH₄HS is introduced into the flask?

Give reasons of the following:
BeCl₂ can be easily hydrolysed.

Nitrobenzene is formed as the major product along with a minor product in the reaction of benzene with a hot mixture of nitric acid and sulphuric acid. The minor product consists of carbon : 42.86 %, hydrogen : 2.40%, nitrogen : 16.67% and oxygen : 38.07% (i) Calculate the empirical formula of the minor product. (ii) When 5.5 g of the minor product is dissolved in 45 g of benzene, the boiling point of the solution is 1.84 ^oC higher than that of pure benzene. Calculate the molar mass of the minor product and determine its molecular and structural formula. (Molal boiling point elevation constant of benzene is 2.53 K kg mol^-1)

A cell, Ag | Ag⁺ || Cu²⁺ | Cu, initially contains 1 M Ag⁺ and 1 M Cu²⁺ ions. Calculate the change in the cell potential after the passage of 9.65 A current for 1 h.

The rate constant for an isomerisation reaction, A $$\to$$ B is 4.5 $$\times$$ 10^-3 min^-1. If the initial concentration of A is 1 M, calculate the rate of the reaction after 1 h.

Let $$f(x)$$ be a continuous function given by $$$f\left( x \right) = \left\{ {\matrix{ {2x,} & {\left| x \right| \le 1} \cr {{x^2} + ax + b,} & {\left| x \right| > 1} \cr } } \right\}$$$

Find the area of the region in the third quadrant bounded by the curves $$x = - 2{y^2}$$ and $$y=f(x)$$ lying on the left of the line $$8x+1=0.$$

A solution of the differential equation
$${\left( {{{dy} \over {dx}}} \right)^2} - x{{dy} \over {dx}} + y = 0$$ is

Integrate $$\int\limits_0^\pi {{{{e^{\cos x}}} \over {{e^{\cos x}} + {e^{ - \cos x}}}}\,dx.} $$

The differential equation representing the family of curves
$${y^2} = 2c\left( {x + \sqrt c } \right),$$ where $$c$$ is a positive parameter, is of

For which of the following values of $$m$$, is the area of the region bounded by the curve $$y = x - {x^2}$$ and the line $$y=mx$$ equals $$9/2$$?

The probabilities that a student passes in Mathematics, Physics and Chemistry are $$m, p$$ and $$c,$$ respectively. Of these subjects, the student has a $$75%$$ chance of passing in at least one, a $$50$$% chance of passing in at least two, and a $$40$$% chance of passing in exactly two. Which of the following relations are true?

If the integers $$m$$ and $$n$$ are chosen at random from $$1$$ to $$100$$, then the probability that a number of the form $${7^m} + {7^n}$$ is divisible by $$5$$ equals

Let $$a=2i+j-2k$$ and $$b=i+j.$$ If $$c$$ is a vector such that $$a.$$ $$c = \left| c \right|,\left| {c - a} \right| = 2\sqrt 2 $$ and the angle between $$\left( {a \times b} \right)$$ and $$c$$ is $${30^ \circ },$$ then $$\left| {\left( {a \times b} \right) \times c} \right| = $$

Let $$a=2i+j+k, b=i+2j-k$$ and a unit vector $$c$$ be coplanar. If $$c$$ is perpendicular to $$a,$$ then $$c =$$

Eight players $${P_1},{P_2},.....{P_8}$$ play a knock-out tournament. It is known that whenever the players $${P_i}$$ and $${P_j}$$ play, the player $${P_i}$$ will win if $$i < j.$$ Assuming that the players are paired at random in each round, what is the probability that the player $${P_4}$$ reaches the final?

Let $$a$$ and $$b$$ two non-collinear unit vectors. If $$u = a - \left( {a\,.\,b} \right)\,b$$ and $$v = a \times b,$$ then $$\left| v \right|$$ is

Let $$u$$ and $$v$$ be units vectors. If $$w$$ is a vector such that $$w + \left( {w \times u} \right) = v,$$ then prove that $$\left| {\left( {u \times v} \right) \cdot w} \right| \le 1/2$$ and that the equality holds if and only if $$u$$ is perpendicular to $$v .$$

Integrate $$\int {{{{x^3} + 3x + 2} \over {{{\left( {{x^2} + 1} \right)}^2}\left( {x + 1} \right)}}dx.} $$

Let $${T_1}$$, $${T_2}$$ be two tangents drawn from (- 2, 0) onto the circle $$C:{x^2}\,\, + \,{y^2} = 1$$. Determine the circles touching C and having $${T_1}$$, $${T_2}$$ as their pair of tangents. Further, find the equations of all possible common tangents to these circles, when taken two at a time.

In a triangle $$PQR,\angle R = \pi /2$$. If $$\,\,\tan \left( {P/2} \right)$$ and $$\tan \left( {Q/2} \right)$$ are the roots of the equation $$a{x^2} + bx + c = 0\left( {a \ne 0} \right)$$ then.

$$If\,i = \sqrt { - 1} ,\,\,then\,\,4 + 5{\left( { - {1 \over 2} + {{i\sqrt 3 } \over 2}} \right)^{334}} + 3{\left( { - {1 \over 2} + {{i\sqrt 3 } \over 2}} \right)^{365}}$$ is equal to

For a positive integer $$\,n$$, let
$${f_n}\left( \theta \right) = \left( {\tan {\theta \over 2}} \right)\,\left( {1 + \sec \theta } \right)\,\left( {1 + \sec 2\theta } \right)\,\left( {1 + \sec 4\theta } \right).....\left( {1 + \sec {2^n}\theta } \right).$$ Then

If the roots of the equation $${x^2} - 2ax + {a^2} + a - 3 = 0$$ are real and less than 3, then

If in the expansion of $${\left( {1 + x} \right)^m}{\left( {1 - x} \right)^n},$$ the coefficients of $$x$$ and $${x^2}$$ are $$3$$ and $$-6$$ respectively, then $$m$$ is

Let $$n$$ be any positive integer. Prove that $$$\sum\limits_{k = 0}^m {{{\left( {\matrix{ {2n - k} \cr k \cr } } \right)} \over {\left( {\matrix{ {2n - k} \cr n \cr } } \right)}}.{{\left( {2n - 4k + 1} \right)} \over {\left( {2n - 2k + 1} \right)}}{2^{n - 2k}} = {{\left( {\matrix{ n \cr m \cr } } \right)} \over {\left( {\matrix{ {2n - 2m} \cr {n - m} \cr } } \right)}}{2^{n - 2m}}} $$$

for each non-be gatuve integer $$m \le n.$$ $$\,\left( {Here\left( {\matrix{ p \cr q \cr } } \right) = {}^p{C_q}} \right).$$

Lt $$PQR$$ be a right angled isosceles triangle, right angled at $$P(2, 1)$$. If the equation of the line $$QR$$ is $$2x + y = 3,$$ then the equation representing the pair of lines $$PQ$$ and $$PR$$ is

The harmonic mean of the roots of the equation $$\left( {5 + \sqrt 2 } \right){x^2} - \left( {4 + \sqrt 5 } \right)x + 8 + 2\sqrt 5 = 0$$ is

Let $${a_1},{a_2},......{a_{10}}$$ be in $$A,\,P,$$ and $${h_1},{h_2},......{h_{10}}$$ be in H.P. If $${a_1} = {h_1} = 2$$ and $${a_{10}} = {h_{10}} = 3,$$ then $${a_4}{h_7}$$ is

Let a, b, c, d be real numbers in G.P. If u, v, w, satisfy the system of equations
u + 2v + 3w = 6
4u + 5v + 6w = 12
6u + 9v = 4

then show that the roots of the equation $$\left( {{1 \over u} + {1 \over v} + {1 \over w}} \right){x^2}$$
$$ + [{(b - c)^2} + {(c - a)^2} + {(d - b)^2}]x + u + v + w = 0$$ and $$20{x^2} + 10{(a - d)^2}x - 9 = 0$$ are reciprocals of each other.

If $${x_1},\,{x_2},\,{x_3}$$ as well as $${y_1},\,{y_2},\,{y_3}$$, are in G.P. with the same common ratio, then the points $$\left( {{x_1},\,{y_1}} \right),\left( {{x_2},\,{y_2}} \right)$$ and $$\left( {{x_3},\,{y_3}} \right).$$

For a positive integer $$n$$, let
$$a\left( n \right) = 1 + {1 \over 2} + {1 \over 3} + {1 \over 4} + .....\,{1 \over {\left( {{2^n}} \right) - 1}}$$. Then

Let $${L_1}$$ be a straight line passing through the origin and $${L_2}$$ be the straight line $$x + y = 1$$. If the intercepts made by the circle $${x^2} + {y^2} - x + 3y = 0$$ on $${L_1}$$ and $${L_2}$$ are equal, then which of the following equations can represent $${L_1}$$?

For complex numbers z and w, prove that $${\left| z \right|^2}w - {\left| w \right|^2}z = z - w$$ if and only if $$ z = w\,or\,z\overline {\,w} = 1$$.

If two distinct chords, drawn from the point (p, q) on the circle $${x^2}\, + \,{y^2} = \,px\, + \,qy\,\,(\,where\,pq\, \ne \,0)$$ are bisected by the x - axis, then

On the ellipse $$4{x^2} + 9{y^2} = 1,$$ the points at which the tangents are parallel to the line $$8x = 9y$$ are

Consider the family of circles $${x^2} + {y^2} = {r^2},\,\,2 < r < 5$$. If in the first quadrant, the common taingent to a circle of this family and the ellipse $$4{x^2} + 25{y^2} = 100$$ meets the co-ordinate axes at $$A$$ and $$B$$, then find the equation of the locus of vthe mid-point of $$AB$$.

Let $$P$$ $$\left( {a\,\sec \,\theta ,\,\,b\,\tan \theta } \right)$$ and $$Q$$ $$\left( {a\,\sec \,\,\phi ,\,\,b\,\tan \,\phi } \right)$$, where $$\theta + \phi = \pi /2,$$, be two points on the hyperbola $${{{x^2}} \over {{a^2}}} - {{{y^2}} \over {{b^2}}} = 1$$.

If $$(h, k)$$ is the point of intersection of the normals at $$P$$ and $$Q$$, then $$k$$ is equal to

The curve described parametrically by $$x = {t^2} + t + 1,$$ $$y = {t^2} - t + 1 $$ represents

Find the co-ordinates of all the points $$P$$ on the ellipse $${{{x^2}} \over {{a^2}}} + {{{y^2}} \over {{b^2}}} = 1$$, for which the area of the triangle $$PON$$ is maximum, where $$O$$ denotes the origin and $$N$$, the foot of the perpendicular from $$O$$ to the tangent at $$P$$.

If $$x$$ $$=$$ $$9$$ is the chord of contact of the hyperbola $${x^2} - {y^2} = 9,$$ then the equation of the vcorresponding pair of tangents is

The function $$f\left( x \right) = \int\limits_{ - 1}^x {t\left( {{e^t} - 1} \right)\left( {t - 1} \right){{\left( {t - 2} \right)}^3}\,\,\,{{\left( {t - 3} \right)}^5}} $$ $$dt$$ has a local minimum at $$x=$$

The number of real solutions of
$${\tan ^{ - 1}}\,\,\sqrt {x\left( {x + 1} \right)} + {\sin ^{ - 1}}\,\,\sqrt {{x^2} + x + 1} = \pi /2$$ is

Let $$ABC$$ be a triangle having $$O$$ and $$I$$ as its circumcenter and in centre respectively. If $$R$$ and $$r$$ are the circumradius and the inradius, respectively, then prove that $${\left( {IO} \right)^2} = {R^2} - 2{\mathop{\rm Rr}\nolimits} $$. Further show that the triangle BIO is a right-angled triangle if and only if $$b$$ is arithmetic mean of $$a$$ and $$c$$.

The function $$f(x)=$$ $${\sin ^4}x + {\cos ^4}x$$ increases if

If for a real number $$y$$, $$\left[ y \right]$$ is the greatest integer less than or
equal to $$y$$, then the value of the integral $$\int\limits_{\pi /2}^{3\pi /2} {\left[ {2\sin x} \right]dx} $$ is

$$\int\limits_{\pi /4}^{3\pi /4} {{{dx} \over {1 + \cos x}}} $$ is equal to