1
JEE Advanced 2019 Paper 2 Offline
Numerical
+3
-0
The decomposition reaction

$$2{N_2}{O_5}(g)\buildrel \Delta \over \longrightarrow 2{N_2}{O_4}(g) + {O_2}(g)$$

is started in a closed cylinder under isothermal isochoric condition at an initial pressure of 1 atm. After Y $$\times$$ 103 s, the pressure inside the cylinder is found to be 1.45 atm. If the rate constant of the reaction is 5 $$\times$$ 10-4s-1, assuming ideal gas behaviour, the value of Y is ...............
2
JEE Advanced 2019 Paper 1 Offline
Numerical
+3
-0
Consider the kinetic data given in the following table for the reaction A + B + C $$\to$$ Product.

The rate of the reaction for [A] = 0.15 mol dm-3, [B] = 0.25 mol dm-3 and [C] = 0.15 mol dm-3 is found to be Y $$\times$$ 10-5 mol dm-3s-1. The value of Y is .................
3
JEE Advanced 2018 Paper 2 Offline
Numerical
+3
-0
Consider the following reversible reaction, $$A\left( g \right) + B\left( g \right) \to AB\left( g \right).$$

The activation energy of the backward reaction exceeds that of the forward reaction by $$2RT$$ (in $$J\,mo{l^{ - 1}}$$). If the pre-exponential factor of the forward reaction is $$4$$ times that of the reverse reaction, the absolute value of $$\Delta {G^ \circ }$$ (in $$J\,mo{l^{ - 1}}$$ ) for the reaction at $$300$$ $$K$$ is ____________.

(Given; $$\ln \left( 2 \right) = 0.7,RT = 2500$$ $$J\,mo{l^{ - 1}}$$ at $$300$$ $$K$$ and $$G$$ is the Gibbs energy)
4
JEE Advanced 2015 Paper 2 Offline
Numerical
+4
-0
A closed vessel with rigid walls contains 1 mol of $${}_{92}^{238}U$$ and 1 mol of air at 298 K. Considering complete decay of $${}_{92}^{238}U$$ to $${}_{82}^{206}Pb$$, the ratio of the final pressure to the initial pressure of the system at 298 K is