Statement 1 : For every chemical reaction at equilibrium, standard Gibbs energy of reaction is zero.
and
Statement 2 : At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs energy.
$$ \begin{aligned} & \mathrm{Ag}^{+}+\mathrm{NH}_3 \quad\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)\right]^{+} \\ & k_1=3.5 \times 10^{-3} \\ & {\left[\mathrm{Ag}\left(\mathrm{NH}_3\right]^{+}+\mathrm{NH}_3 \quad\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}\right.} \end{aligned} $$
$k_2=1.7 \times 10^{-3}$, then the formation constant of $\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}$ is :
$$ \mathrm{N}_2+3 \mathrm{H}_2 \to 2 \mathrm{NH}_3 $$
Which is the correct statement if $\mathrm{N}_2$ is added at equilibrium condition?
JEE Advanced Subjects
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